Recent Progress of Carbon-Supported Single-Atom Catalysts for Energy Conversion and Storage

Matter - Tập 3 Số 5 - Trang 1442-1476 - 2020
Yongchao Yang1, Yuwei Yang1, Zengxia Pei1, Kuang‐Hsu Wu1, Chun Hui Tan1, Haozhu Wang1, Li Wei1, Asif Mahmood1, Cheng Yan1, Juncai Dong2, Shenlong Zhao1, Yuan Chen1
1School of Chemical and Biomolecular Engineering, The University of Sydney, Sydney, NSW, 2006, Australia
2Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

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Tài liệu tham khảo

King, 2017, Global clean energy in 2017, Science, 355, 111, 10.1126/science.aam7088

Copéret, 2003, Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry, Angew. Chem. Int. Ed., 42, 156, 10.1002/anie.200390072

Zhao, 2016, Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution, Nat. Energy, 1, 16184, 10.1038/nenergy.2016.184

Cheng, 2018, Atomically dispersed transition metals on carbon nanotubes with ultrahigh loading for selective electrochemical carbon dioxide reduction, Adv. Mater., 30, 1706287, 10.1002/adma.201706287

Yan, 2015, Single-atom Pd1/graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1, 3-butadiene, J. Am. Chem. Soc., 137, 10484, 10.1021/jacs.5b06485

Ji, 2020, Chemical synthesis of single atomic site catalysts, Chem. Rev., 10.1021/acs.chemrev.9b00818

Yang, 2019, A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts, Nat. Commun., 10, 4585, 10.1038/s41467-019-12510-0

Wang, 2019, Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt1 atoms, Nat. Commun., 10, 3808, 10.1038/s41467-019-11856-9

Jiang, 2018, Electrocatalysis over graphene-defect-coordinated transition-metal single-atom catalysts, Chem, 4, 194, 10.1016/j.chempr.2018.01.013

Liu, 2017, Catalysis by supported single metal atoms, ACS Catal., 7, 34, 10.1021/acscatal.6b01534

Liu, 2019, Atomically dispersed metal catalysts for the oxygen reduction reaction: synthesis, characterization, reaction mechanisms and electrochemical energy applications, Energy Environ. Sci., 12, 2890, 10.1039/C9EE01722D

Qiao, 2011, Single-atom catalysis of CO oxidation using Pt1/FeOx, Nat. Chem., 3, 634, 10.1038/nchem.1095

Joo, 2001, Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles, Nature, 412, 169, 10.1038/35084046

Paulus, 2002, Oxygen reduction on carbon-supported Pt-Ni and Pt-Co alloy catalysts, J. Phys. Chem. B, 106, 4181, 10.1021/jp013442l

Liu, 2004, Carbon-supported Pt and PtRu nanoparticles as catalysts for a direct methanol fuel cell, J. Phys. Chem. B, 108, 8234, 10.1021/jp049422b

Liu, 2005, Carbon-supported Pt nanoparticles as catalysts for proton exchange membrane fuel cells, J. Power Sources, 139, 73, 10.1016/j.jpowsour.2004.07.012

Han, 2019, Atomically dispersed binary Co-Ni sites in nitrogen-doped hollow carbon nanocubes for reversible oxygen reduction and evolution, Adv. Mater., 31, 1905622, 10.1002/adma.201905622

Yi, 2019, Cobalt single-atoms anchored on porphyrinic triazine-based frameworks as bifunctional electrocatalysts for oxygen reduction and hydrogen evolution reactions, J. Mater. Chem. A, 7, 1252, 10.1039/C8TA09490J

Tang, 2019, Single nickel atom supported on hybridized graphene-boron nitride nanosheet as a highly active bi-functional electrocatalyst for hydrogen and oxygen evolution reactions, J. Mater. Chem. A, 7, 26261, 10.1039/C9TA10500J

Zhao, 2020, Atomic site electrocatalysts for water splitting, oxygen reduction and selective oxidation, Chem. Soc. Rev., 49, 2215, 10.1039/C9CS00869A

Zhang, 2019, Tuning the coordination environment in single-atom catalysts to achieve highly efficient oxygen reduction reactions, J. Am. Chem. Soc., 141, 20118, 10.1021/jacs.9b09352

Jia, 2020, Atom-coordinated structure triggers selective H2O2 production, Chem, 6, 548, 10.1016/j.chempr.2020.02.011

Yang, 2020, Understanding the activity of Co-N4-xCx in atomic metal catalysts for oxygen reduction catalysis, Angew. Chem. Int. Ed., 132, 6178, 10.1002/ange.202000324

Wang, 2019, A sulfur-tethering synthesis strategy toward high-loading atomically dispersed noble metal catalysts, Sci. Adv., 5, eaax6322, 10.1126/sciadv.aax6322

Gong, 2019, Liberating N-CNTs confined highly dispersed Co-Nx sites for selective hydrogenation of quinolines, Adv. Mater., 31, 1906051, 10.1002/adma.201906051

Sui, 2017, A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: nanostructure, activity, mechanism and carbon support in PEM fuel cells, J. Mater. Chem. A, 5, 1808, 10.1039/C6TA08580F

Choi, 2016, Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst, Nat. Commun., 7, 10922, 10.1038/ncomms10922

Hossain, 2019, Rational design of graphene-supported single atom catalysts for hydrogen evolution reaction, Adv. Energy Mater., 9, 1803689, 10.1002/aenm.201803689

Lu, 2019, Atomic Ni anchored covalent triazine framework as high efficient electrocatalyst for carbon dioxide conversion, Adv. Funct. Mater., 29, 1806884, 10.1002/adfm.201806884

Wang, 2018, Synergistic effect of well-defined dual sites boosting the oxygen reduction reaction, Energy Environ. Sci., 11, 3375, 10.1039/C8EE02656D

Liu, 2016, Carbon-based metal-free catalysts, Nat. Rev. Mater., 1, 16064, 10.1038/natrevmats.2016.64

Ye, 2019, Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction, Energy Environ. Sci., 12, 1000, 10.1039/C8EE02888E

Han, 2018, A polymer encapsulation strategy to synthesize porous nitrogen-doped carbon-nanosphere-supported metal isolated-single-atomic-site catalysts, Adv. Mater., 30, 1706508, 10.1002/adma.201706508

Liu, 2019, Carbon-supported divacancy-anchored platinum single-atom electrocatalysts with superhigh Pt utilization for the oxygen reduction reaction, Angew. Chem. Int. Ed., 131, 1175, 10.1002/ange.201812423

Lai, 2019, The quasi-Pt-allotrope catalyst: hollow PtCo@ single-atom Pt1 on nitrogen-doped carbon toward superior oxygen reduction, Adv. Funct. Mater., 29, 1807340, 10.1002/adfm.201807340

Choi, 2015, Stability of Fe-N-C catalysts in acidic medium studied by operando spectroscopy, Angew. Chem. Int. Ed., 127, 12944, 10.1002/ange.201504903

Wang, 2019, Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation, Nat. Catal., 2, 578, 10.1038/s41929-019-0304-9

Liu, 2018, In situ trapped high-density single metal atoms within graphene: iron-containing hybrids as representatives for efficient oxygen reduction, Nano Res., 11, 2217, 10.1007/s12274-017-1840-8

Xi, 2018, Confined-interface-directed synthesis of Palladium single-atom catalysts on graphene/amorphous carbon, Appl. Catal. B, 225, 291, 10.1016/j.apcatb.2017.11.057

Sun, 2013, Single-atom catalysis using Pt/graphene achieved through atomic layer deposition, Sci. Rep., 3, 1775, 10.1038/srep01775

Zhang, 2019, Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction, Nat. Commun., 10, 4936, 10.1038/s41467-019-12887-y

Lu, 2016, Atomic layer deposition—sequential self-limiting surface reactions for advanced catalyst “bottom-up” synthesis, Surf. Sci. Rep., 71, 410, 10.1016/j.surfrep.2016.03.003

Yin, 2018, Engineering the coordination environment of single-atom platinum anchored on graphdiyne for optimizing electrocatalytic hydrogen evolution, Angew. Chem. Int. Ed., 57, 9382, 10.1002/anie.201804817

Qin, 2018, Single-site gold catalysts on hierarchical N-doped porous noble carbon for enhanced electrochemical reduction of nitrogen, Small Methods, 2, 1800202, 10.1002/smtd.201800202

Podyacheva, 2018, Highly stable single-atom catalyst with ionic Pd active sites supported on N-doped carbon nanotubes for formic acid decomposition, ChemSusChem, 11, 3724, 10.1002/cssc.201801679

Zhang, 2019, The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring, Nat. Commun., 10, 1657, 10.1038/s41467-019-09596-x

Zhang, 2018, Graphene defects trap atomic Ni species for hydrogen and oxygen evolution reactions, Chem, 4, 285, 10.1016/j.chempr.2017.12.005

Li, 2018, Photochemical solid-phase synthesis of platinum single atoms on nitrogen-doped carbon with high loading as bifunctional catalysts for hydrogen evolution and oxygen reduction reactions, ACS Catal., 8, 8450, 10.1021/acscatal.8b02288

Fei, 2018, Microwave-assisted rapid synthesis of graphene-supported single atomic metals, Adv. Mater., 30, 1802146, 10.1002/adma.201802146

Deng, 2015, A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature, Sci. Adv., 1, e1500462, 10.1126/sciadv.1500462

Cui, 2018, Room-temperature methane conversion by graphene-confined single iron atoms, Chem, 4, 1902, 10.1016/j.chempr.2018.05.006

Zhao, 2018, One-pot pyrolysis method to fabricate carbon nanotube supported Ni single-atom catalysts with ultrahigh loading, ACS Appl. Energy Mater., 1, 5286

Cheng, 2019, Iron single atoms on graphene as nonprecious metal catalysts for high-temperature polymer electrolyte membrane fuel cells, Adv. Sci., 6, 1802066, 10.1002/advs.201802066

Zhao, 2019, Carbon-based metal-free catalysts for key reactions involved in energy conversion and storage, Adv. Mater., 31, 1801526, 10.1002/adma.201801526

Yin, 2016, Single cobalt atoms with precise N-coordination as superior oxygen reduction reaction catalysts, Angew. Chem. Int. Ed., 55, 10800, 10.1002/anie.201604802

Jiao, 2018, From metal-organic frameworks to single-atom Fe implanted N-doped porous carbons: efficient oxygen reduction in both alkaline and acidic media, Angew. Chem. Int. Ed., 57, 8525, 10.1002/anie.201803262

Yang, 2019, Metal-organic-framework-derived hollow N-doped porous carbon with ultrahigh concentrations of single Zn atoms for efficient carbon dioxide conversion, Angew. Chem. Int. Ed., 58, 3511, 10.1002/anie.201813494

Chen, 2018, Single tungsten atoms supported on MOF-derived N-doped carbon for robust electrochemical hydrogen evolution, Adv. Mater., 30, 1800396, 10.1002/adma.201800396

Ni, 2019, Pore size effect of graphynes supports on CO2 electrocatalytic activity of Cu single atoms, Phys. Chem. Chem. Phys., 22, 1181, 10.1039/C9CP05624F

Zhu, 2017, Atomically dispersed Fe/N-doped hierarchical carbon architectures derived from a metal-organic framework composite for extremely efficient electrocatalysis, ACS Energy Lett, 2, 504, 10.1021/acsenergylett.6b00686

Feng, 2019, Mesoporous nitrogen-doped carbon-nanosphere-supported isolated single-atom Pd catalyst for highly efficient semihydrogenation of acetylene, Adv. Mater., 31, 1901024, 10.1002/adma.201901024

Yang, 2018, In situ thermal atomization to convert supported nickel nanoparticles into surface-bound nickel single-atom catalysts, Angew. Chem. Int. Ed., 57, 14095, 10.1002/anie.201808049

Qu, 2018, Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms, Nat. Catal., 1, 781, 10.1038/s41929-018-0146-x

Fan, 2016, Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis, Nat. Commun., 7, 10667, 10.1038/ncomms10667

Zhang, 2018, Coordination of atomic Co-Pt coupling species at carbon defects as active sites for oxygen reduction reaction, J. Am. Chem. Soc., 140, 10757, 10.1021/jacs.8b04647

Yan, 2019, Probing the active sites of carbon-encapsulated cobalt nanoparticles for oxygen reduction, Small Methods, 3, 1800439, 10.1002/smtd.201800439

Zhao, 2014, Carbonized nanoscale metal-organic frameworks as high performance electrocatalyst for oxygen reduction reaction, ACS Nano, 8, 12660, 10.1021/nn505582e

Wan, 2020, Molecular design of single-atom catalysts for oxygen reduction reaction, Adv. Energy Mater., 10, 1903815, 10.1002/aenm.201903815

Li, 2019, Carbon nanotube-linked hollow carbon nanospheres doped with iron and nitrogen as single-atom catalysts for oxygen reduction reaction in acidic solutions, J. Mater. Chem. A, 7, 14478, 10.1039/C9TA00508K

Chen, 2019, Atomic Fe dispersed on N-doped carbon hollow nanospheres for high-efficiency electrocatalytic oxygen reduction, Adv. Mater., 31, 1806312, 10.1002/adma.201806312

Deng, 2019, g-C3N4 promoted MOF derived hollow carbon nanopolyhedra doped with high density/fraction of single Fe atoms as an ultra-high performance non-precious catalyst towards acidic ORR and PEM fuel cells, J. Mater. Chem. A, 7, 5020, 10.1039/C8TA11785C

Li, 2019, Secondary-atom-assisted synthesis of single iron atoms anchored on N-doped carbon nanowires for oxygen reduction reaction, ACS Catal., 9, 5929, 10.1021/acscatal.9b00869

Staszak-Jirkovský, 2016, Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction, Nat. Mater., 15, 197, 10.1038/nmat4481

Liu, 2019, Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution, Nat. Energy, 4, 512, 10.1038/s41560-019-0402-6

Lu, 2019, Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media, Nat. Commun., 10, 631, 10.1038/s41467-019-08419-3

Zhang, 2018, Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction, Nat. Catal., 1, 985, 10.1038/s41929-018-0195-1

Zhang, 2018, Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction, Sci. Adv., 4, eaao6657, 10.1126/sciadv.aao6657

Lu, 2015, Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution, Nat. Commun., 6, 6567, 10.1038/ncomms7567

Mahmood, 2018, Electrocatalysts for hydrogen evolution in alkaline electrolytes: mechanisms, challenges, and prospective solutions, Adv. Sci., 5, 1700464, 10.1002/advs.201700464

Mahmood, 2017, An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction, Nat. Nanotechnol., 12, 441, 10.1038/nnano.2016.304

Danilovic, 2013, Electrocatalysis of the HER in acid and alkaline media, J. Serb. Chem. Soc., 78, 2007, 10.2298/JSC131118136D

Durst, 2014, New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism, Energy Environ. Sci., 7, 2255, 10.1039/C4EE00440J

Huang, 2019, Strategies to break the scaling relation toward enhanced oxygen electrocatalysis, Matter, 1, 1494, 10.1016/j.matt.2019.09.011

Zhang, 2019, Unveiling the activity origin of electrocatalytic oxygen evolution over isolated Ni atoms supported on a N-doped carbon matrix, Adv. Mater., 31, 1904548, 10.1002/adma.201904548

Chen, 2018, Enhanced oxygen evolution reaction for single atomic Co catalyst via support modification: a density functional theory design predication, Inorg. Chem., 57, 13020, 10.1021/acs.inorgchem.8b02294

Yang, 2018, Atomically dispersed Ni (I) as the active site for electrochemical CO2 reduction, Nat. Energy, 3, 140, 10.1038/s41560-017-0078-8

Gong, 2019, Catalytic mechanisms and design principles for single-atom catalysts in highly efficient CO2 conversion, Adv. Energy Mater., 9, 1902625, 10.1002/aenm.201902625

Li, 2019, Supported noble-metal single atoms for heterogeneous catalysis, Adv. Mater., 31, 1902031, 10.1002/adma.201902031

Huang, 2019, Disclosing CO2 activation mechanism by hydroxyl-induced crystalline structure transformation in electrocatalytic process, Matter, 1, 1656, 10.1016/j.matt.2019.07.003

Gao, 2016, Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel, Nature, 529, 68, 10.1038/nature16455

Kumar, 2013, Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction, Nat. Commun., 4, 2819, 10.1038/ncomms3819

Ju, 2017, Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2, Nat. Commun., 8, 944, 10.1038/s41467-017-01035-z

Pan, 2018, Design of single-atom Co-N5 catalytic site: a robust electrocatalyst for CO2 reduction with nearly 100% CO selectivity and remarkable stability, J. Am. Chem. Soc., 140, 4218, 10.1021/jacs.8b00814

Yang, 2018, Highly efficient CO2 electroreduction on ZnN4-based single-atom catalyst, Angew. Chem. Int. Ed., 57, 12303, 10.1002/anie.201805871

Yang, 2019, Scalable production of efficient single-atom copper decorated carbon membranes for CO2 electroreduction to methanol, J. Am. Chem. Soc., 141, 12717, 10.1021/jacs.9b04907

Zheng, 2019, Large-scale and highly selective CO2 electrocatalytic reduction on nickel single-atom catalyst, Joule, 3, 265, 10.1016/j.joule.2018.10.015

Zhu, 2013, Monodisperse Au nanoparticles for selective electrocatalytic reduction of CO2 to CO, J. Am. Chem. Soc., 135, 16833, 10.1021/ja409445p

Yoon, 2016, Tuning of silver catalyst mesostructure promotes selective carbon dioxide conversion into fuels, Angew. Chem. Int. Ed., 55, 15282, 10.1002/anie.201607942

Zhang, 2019, Graphene supported single-atom FeN5 catalytic site for efficient electrochemical CO2 reduction, Angew. Chem. Int. Ed., 131, 15013, 10.1002/ange.201906079

Wu, 2015, Incorporation of nitrogen defects for efficient reduction of CO2 via two-electron pathway on three-dimensional graphene foam, Nano Lett., 16, 466, 10.1021/acs.nanolett.5b04123

Wu, 2015, Achieving highly efficient, selective, and stable CO2 reduction on nitrogen-doped carbon nanotubes, ACS Nano, 9, 5364, 10.1021/acsnano.5b01079

Mou, 2019, Highly efficient electroreduction of CO2 on nickel single-atom catalysts: atom trapping and nitrogen anchoring, Small, 15, 1903668, 10.1002/smll.201903668

Lu, 2019, Facile synthesis of single-nickel-atomic dispersed N-doped carbon framework for efficient electrochemical CO2 reduction, Appl. Catal. B, 241, 113, 10.1016/j.apcatb.2018.09.025

Cheng, 2019, Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2, Appl. Catal. B, 243, 294, 10.1016/j.apcatb.2018.10.046

Jeong, 2019, Achieving highly efficient CO2 to CO electroreduction exceeding 300 mA cm-2 with single-atom nickel electrocatalysts, J. Mater. Chem. A, 7, 10651, 10.1039/C9TA02405K

Li, 2017, Exclusive Ni-N4 sites realize near-unity CO selectivity for electrochemical CO2 reduction, J. Am. Chem. Soc., 139, 14889, 10.1021/jacs.7b09074

Foster, 2018, Catalysts for nitrogen reduction to ammonia, Nat. Catal., 1, 490, 10.1038/s41929-018-0092-7

Leigh, 2004, Haber-Bosch and other industrial processes, 33

Liu, 2019, Homogeneous, heterogeneous, and biological catalysts for electrochemical N2 reduction toward NH3 under ambient conditions, ACS Catal., 9, 5245, 10.1021/acscatal.9b00994

Ling, 2018, Single molybdenum atom anchored on N-doped carbon as a promising electrocatalyst for nitrogen reduction into ammonia at ambient conditions, J. Phys. Chem. C, 122, 16842, 10.1021/acs.jpcc.8b05257

Tao, 2019, Nitrogen fixation by Ru single-atom electrocatalytic reduction, Chem, 5, 204, 10.1016/j.chempr.2018.10.007

Wang, 2019, Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential, Nat. Commun., 10, 341, 10.1038/s41467-018-08120-x

Han, 2019, Atomically dispersed molybdenum catalysts for efficient ambient nitrogen fixation, Angew. Chem. Int. Ed., 58, 2321, 10.1002/anie.201811728

Geng, 2018, Achieving a record-high yield rate of 120.9 for N2 electrochemical reduction over Ru single-atom catalysts, Adv. Mater., 30, 1803498, 10.1002/adma.201803498

Luo, 2019, Efficient electrocatalytic N2 fixation with MXene under ambient conditions, Joule, 3, 279, 10.1016/j.joule.2018.09.011

Cheng, 2018, Molybdenum carbide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions, Adv. Mater., 30, 1803694, 10.1002/adma.201803694

Yu, 2018, Boron-doped graphene for electrocatalytic N2 reduction, Joule, 2, 1610, 10.1016/j.joule.2018.06.007

Qiu, 2018, High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst, Nat. Commun., 9, 3485, 10.1038/s41467-018-05758-5

Andersen, 2019, A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements, Nature, 570, 504, 10.1038/s41586-019-1260-x

Zhao, 2019, Ammonia detection methods in photocatalytic and electrocatalytic experiments: how to improve the reliability of NH3 production rates?, Adv. Sci., 6, 1802109, 10.1002/advs.201802109

Suryanto, 2019, Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia, Nat. Catal., 2, 290, 10.1038/s41929-019-0252-4

Wang, 2015, Carbon-supported Pt-based alloy electrocatalysts for the oxygen reduction reaction in polymer electrolyte membrane fuel cells: particle size, shape, and composition manipulation and their impact to activity, Chem. Rev., 115, 3433, 10.1021/cr500519c

Deng, 2014, Highly active and durable non-precious-metal catalysts encapsulated in carbon nanotubes for hydrogen evolution reaction, Energy Environ. Sci., 7, 1919, 10.1039/C4EE00370E

Lee, 2012, Synthesis and activities of rutile IrO2 and RuO2 nanoparticles for oxygen evolution in acid and alkaline solutions, J. Phys. Chem. Lett., 3, 399, 10.1021/jz2016507

Stoerzinger, 2014, Orientation-dependent oxygen evolution activities of rutile IrO2 and RuO2, J. Phys. Chem. Lett., 5, 1636, 10.1021/jz500610u

Amiinu, 2017, Multifunctional Mo-N/C@MoS2 electrocatalysts for HER, OER, ORR, and Zn-air batteries, Adv. Funct. Mater., 27, 1702300, 10.1002/adfm.201702300

Zeng, 2018, Single-atom to single-atom grafting of Pt1 onto Fe-N4 Center: Pt1@Fe-N-C multifunctional electrocatalyst with significantly enhanced properties, Adv. Energy Mater., 8, 1701345, 10.1002/aenm.201701345

Liu, 2015, Metal (Ni, Co)-metal oxides/graphene nanocomposites as multifunctional electrocatalysts, Adv. Funct. Mater., 25, 5799, 10.1002/adfm.201502217

Fei, 2018, General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities, Nat. Catal., 1, 63, 10.1038/s41929-017-0008-y

Fei, 2015, Atomic cobalt on nitrogen-doped graphene for hydrogen generation, Nat. Commun., 6, 8668, 10.1038/ncomms9668

Zhao, 2017, Ionic exchange of metal–organic frameworks to access single nickel sites for efficient electroreduction of CO2, J. Am. Chem. Soc., 139, 8078, 10.1021/jacs.7b02736

Pan, 2018, A bimetallic Zn/Fe polyphthalocyanine-derived single-atom Fe-N4 catalytic site: a superior trifunctional catalyst for overall water splitting and Zn-Air batteries, Angew. Chem. Int. Ed., 57, 8614, 10.1002/anie.201804349

Chen, 2013, Carbon nanomaterials for high-performance supercapacitors, Mater. Today, 16, 272, 10.1016/j.mattod.2013.07.002

Zhang, 2009, Carbon-based materials as supercapacitor electrodes, Chem. Soc. Rev., 38, 2520, 10.1039/b813846j

Jiao, 2017, Mixed-metallic MOF based electrode materials for high performance hybrid supercapacitors, J. Mater. Chem. A, 5, 1094, 10.1039/C6TA09805C

Niu, 2013, Highly stretchable, integrated supercapacitors based on single-walled carbon nanotube films with continuous reticulate architecture, Adv. Mater., 25, 1058, 10.1002/adma.201204003

Yu, 2019, Hierarchical nickel/phosphorus/nitrogen/carbon composites templated by one metal–organic framework as highly efficient supercapacitor electrode materials, J. Mater. Chem. A, 7, 2875, 10.1039/C8TA11568K

Lu, 2019, A high performance solid-state asymmetric supercapacitor based on Anderson-type polyoxometalate-doped graphene aerogel, Res. Chem. Intermed., 45, 3237, 10.1007/s11164-019-03789-1

Chai, 2019, Polyoxometalate-based metal-organic frameworks for boosting electrochemical capacitor performance, Chem. Eng. J., 373, 587, 10.1016/j.cej.2019.05.084

Shan, 2017, Single atom (K/Na) doped graphitic carbon Nitride@MnO2 as an efficient electrode Material for supercapacitor, Mater. Lett., 202, 103, 10.1016/j.matlet.2017.05.061

Guo, 2020, Recent advances in rechargeable magnesium-based batteries for high-efficiency energy storage, Adv. Energy Mater., 10, 1903591, 10.1002/aenm.201903591

Chen, 2019, Co-Fe mixed metal phosphide nanocubes with highly interconnected-pore architecture as an efficient polysulfide mediator for lithium-sulfur batteries, ACS Nano, 13, 4731, 10.1021/acsnano.9b01079

Fang, 2019, Nanostructured electrode materials for advanced sodium-ion batteries, Matter, 1, 90, 10.1016/j.matt.2019.05.007

Su, 2018, Toward high performance lithium–sulfur batteries based on Li2S cathodes and beyond: status, challenges, and perspectives, Adv. Funct. Mater., 28, 1800154, 10.1002/adfm.201800154

Xu, 2018, Promoting lithium polysulfide/sulfide redox kinetics by the catalyzing of zinc sulfide for high performance lithium-sulfur battery, Nano Energy, 51, 73, 10.1016/j.nanoen.2018.06.046

Yu, 2019, Sodium-sulfur batteries with a polymer-coated NASICON-type sodium-ion solid electrolyte, Matter, 1, 439, 10.1016/j.matt.2019.03.008

Wang, 2019, Materials design for rechargeable metal-air batteries, Matter, 1, 565, 10.1016/j.matt.2019.05.008

Zhang, 2018, Atomic cobalt as an efficient electrocatalyst in sulfur cathodes for superior room-temperature sodium-sulfur batteries, Nat. Commun., 9, 4082, 10.1038/s41467-018-06144-x

Wang, 2019, Single-atom catalyst boosts electrochemical conversion reactions in batteries, Energy Storage Mater., 18, 246, 10.1016/j.ensm.2018.09.006

Zhang, 2019, Single nickel atoms on nitrogen-doped graphene enabling enhanced kinetics of lithium-sulfur batteries, Adv. Mater., 31, 1903955, 10.1002/adma.201903955

Xie, 2019, Implanting atomic cobalt within mesoporous carbon toward highly stable lithium-sulfur batteries, Adv. Mater., 31, 1903813, 10.1002/adma.201903813

Du, 2019, Cobalt in nitrogen-doped graphene as single-atom catalyst for high-sulfur content lithium–sulfur batteries, J. Am. Chem. Soc., 141, 3977, 10.1021/jacs.8b12973