Phản ứng của muối kali của nguyên tố nhóm 14 đã thay thế với 1-(Chloromethyl)silatrane: Thay thế hay Sắp xếp lại?

Russian Journal of General Chemistry - Tập 91 - Trang 2385-2390 - 2022
K. V. Zaitsev1, Yu. F. Oprunenko1
1Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Russia

Tóm tắt

Các phản ứng của 1-(chloromethyl)silatrane với các anion của nguyên tố nhóm 14 hữu cơ [(Me3Si)3E]‒ (E = Si, Ge) được tạo ra tại chỗ cho ra các sản phẩm thay thế tương ứng (Me3Si)3ECH2Si(OCH2CH2)3N, trong khi không có sản phẩm nào của quá trình tái cấu trúc mở rộng vòng được phát hiện. Cấu trúc của các hợp chất được phân lập đã được xác định bằng phổ NMR nhiều hạch.

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