Reaction of β-iminoalcohols with sulfur dioxide. Synthesis of (±)-(2-hydroxyalkylamino)phenyl(isopropyl)-methanesulfonic acids

Russian Journal of General Chemistry - Tập 80 - Trang 761-764 - 2010
P. I. Gryaznov1, O. N. Kataeva1, O. E. Naumova1, R. Z. Musin1, V. A. Al’fonsov1
1Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

Tóm tắt

Reactions of 2-(N-isopropylidene)amino-2-methylpropanol, 2-(N-benzylidene)-, and 2-(N-isopropylidene) aminoethanols with sulfur dioxide in aqueous ethanol medium produce (±)-(2-hydroxyalkylamino)-phenyl(isopropyl)methanesulfonic acids. Structure of (±)-(2-hydroxyethylamino)phenylmethanesulfonic acid was determined by X-ray diffraction method.

Tài liệu tham khảo

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