Rational Ligand Design in Constructing Efficient Catalyst Systems for Suzuki–Miyaura Coupling

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In contrast in the related Pd complex with 9‐(2‐dicyclohexylphosphanylphenyl)phenanthrene a η2–π interaction with C9 and C10 is observed. The complex is effective for the reactions with bulky aryl bromides.[12b]

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