Quantum Chemical Simulation of Polycondensation Processes of Vanadium Oxide Structures on Silica Surface

Russian Journal of General Chemistry - Tập 92 - Trang 2870-2876 - 2023
E. O. Drozdov1, D. V. Buzina1, A. A. Malkov1, A. A. Malygin1
1St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia

Tóm tắt

For the V–O–V bonds between closely spaced vanadium hydroxide groups, synthesized by the molecular layering during sequential treatment of the silica surface with VOCl3 and H2O vapors, a scheme of binding based on experimental data was proposed, and patterns of formation were predicted by quantum chemistry methods.

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