Pythium oligandrum-derived carbon/graphene oxide as sensitized substrate: large-scale preparation and enhancing photocatalytic hydrogen evolution

Qun Zheng1, Ting Mao1, Yanhao Fang1, Yongyan Niu1, Bin Ji1, Xiaofang Gong1, Peiya Wang1, Jiang Zhao1, Hui Yang1, Dan Luo2, Le Hu3, Ying Zhu1, Zhiye Wang1
1Key Laboratory of Microbial Resources Exploitation and Application of Gansu Province, Institute of Biology, Gansu Academy of Sciences, Lanzhou, China
2Department of Physics, Lanzhou City University, Lanzhou, China
3Department of Obstetrics and Gynecology, Key Laboratory of Gynecologic Oncology of Gansu Province, The First Hospital of Lanzhou University, Lanzhou, China

Tóm tắt

Pythium oligandrum-derived biomass-activated carbon/graphene oxide (POC/GO) nanohybrid material is prepared for the first time by direct carbonization using the two-dimensional graphene oxide (GO)-incorporated Pythium oligandrum (PO). Note that the implanted GO is adsorbed and wrapped by the generated PO, which may be a feasible method to separate GO from aqueous systems. The obtained POC/GO exhibits special textural and high conductivity properties due to rapid electron transfer through the two-dimensional GO incorporated into carbonaceous network. Based on the functional POC/GO as a sensitizing substrate, the eosin Y dye-sensitized POC/GO@Pt photocatalysts show high-efficiency H2 evolution activity, which is 1.3 and 2.1 times higher than GO@Pt and POC@Pt. As well as the apparent quantum efficiency of POC/GO@Pt can reach to 32.2% at 430 nm. The superior catalytic activities for H2 evolution are attributed to the inner heat-treated GO which provided fast electron transport channels, while the outer POC with rich defect sites provided adsorption sites for the reactant H2O and co-catalyst Pt. Research ideas and design methods in this paper might provide a new way for preparing other biomass-based carbon materials and solar-driven high active photocatalyst.

Tài liệu tham khảo

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