Prussian blue assembled on graphene oxide for enhanced capacitive deionization and water disinfection
Science China Materials - Trang 1-10 - 2023
Tóm tắt
Capacitive deionization (CDI) with water disinfection materials is an energy-efficient technology for the simultaneous desalination and bio-decontamination of brackish water. However, desalination capacity is always limited by the mechanism of ion electrosorption within the electrical double layer. Recently, the water disinfection ability of CDI has been demonstrated through the functionalization of electrode materials with antimicrobial compounds. To achieve highly efficient and low-cost capacitive deionization and disinfection (CDID) performance, we propose a facile strategy for the fabrication of a graphene oxide/polyaniline/Prussian blue (GO/PANI/PB) nanocomposite. This nanocomposite exhibits a high Brunauer–Emmett–Teller surface area (148.08 m2 g−1), mesopore volume (34.02 cm3 g−1), and pore volume (0.66 cm3 g−1), making it suitable as a Faradaic electrode in the CDI and CDID systems. The obtained GO/PANI/PB electrode exhibits a high desalination capacity of 91.6 mg g−1 and superior desalination ratio of 3.05 mg g−1 min−1 at 1 A g−1. Furthermore, the GO/PANI/PB electrode has a bacterial (Escherichia coli) removal and inactivation efficiency of 94.0% ± 3.1% without the use of other disinfectants. This is ∼7 times higher than the antibacterial efficiency of active carbon electrodes under the same CDI conditions. The proposed strategy is the first to exploit simultaneous deionization and disinfection without using disinfectants, offering the potential of using PB-based Faradaic electrodes for eco-friendly and high-efficiency water desalination and disinfection in future CDID technology.
Tài liệu tham khảo
Metzger M, Besli MM, Kuppan S, et al. Techno-economic analysis of capacitive and intercalative water deionization. Energy Environ Sci, 2020, 13: 1544–1560
Liu Z, Shang X, Li H, et al. A brief review on high-performance capacitive deionization enabled by intercalation electrodes. Glob Challenges, 2021, 5: 2000054
Wang H, Chen B, Liu DJ, et al. Nanoarchitectonics of metal-organic frameworks for capacitive deionization via controlled pyrolyzed approaches. Small, 2022, 18: 2102477
Zhang P, Fritz PA, Schroën K, et al. Zwitterionic polymer modified porous carbon for high-performance and antifouling capacitive desalination. ACS Appl Mater Interfaces, 2018, 10: 33564–33573
Zang X, Xue Y, Ni W, et al. Enhanced electrosorption ability of carbon nanocages as an advanced electrode material for capacitive deionization. ACS Appl Mater Interfaces, 2020, 12: 2180–2190
Yu F, Yang Z, Cheng Y, et al. A comprehensive review on flow-electrode capacitive deionization: Design, active material and environmental application. Separ Purif Tech, 2022, 281: 119870
Li B, Cao Q, Liu Y, et al. Polyaniline-decorated porous carbons with engineered meso/macrochannels for high performance capacitive deionization. J Mater Chem A, 2022, 10: 24905–24914
Luo Q, Yang Y, Wang K, et al. Hierarchical porous carbon nanofibers for highly efficient solar-driven water purification. Sci China Mater, 2023, 66: 3310–3318
Hu P, Tan B, Long M. Advanced nanoarchitectures of carbon aerogels for multifunctional environmental applications. Nanotechnol Rev, 2016, 5
Qian H, Yang J, Hu B, et al. Partially reduced CeO2/C@CNT with high oxygen vacancy boosting phosphate adsorption as CDI anode. Separ Purif Tech, 2023, 306: 122557
Li Y, Chen N, Li Z, et al. Reborn three-dimensional graphene with ultrahigh volumetric desalination capacity. Adv Mater, 2021, 33: 2105853
Jung Y, Yang Y, Kim T, et al. Enhanced electrochemical stability of a zwitterionic-polymer-functionalized electrode for capacitive deionization. ACS Appl Mater Interfaces, 2018, 10: 6207–6217
Lee J, Kim S, Kim C, et al. Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques. Energy Environ Sci, 2014, 7: 3683–3689
Zhang X, Toledo-Carrillo EA, Yu D, et al. Effect of surface charge on the fabrication of hierarchical Mn-based Prussian blue analogue for capacitive desalination. ACS Appl Mater Interfaces, 2022, 14: 40371–40381
Cool NI, James R, Schofield P, et al. Tunnel-structured ζ-V2O5 as a redox-active insertion host for hybrid capacitive deionization. ACS Appl Mater Interfaces, 2023, 15: 1554–1562
Zhang C, Wang D, Wang Z, et al. Boosting capacitive deionization performance of commercial carbon fibers cloth via structural regulation based on catalytic-etching effect. Energy Environ Mater, 2023, 6: e12276
Wei D, Cao Y, Yan L, et al. Enhanced pseudo-capacitance process in nanoarchitectural layered double hydroxide nanoarrays hollow nanocages for improved capacitive deionization performance. ACS Appl Mater Interfaces, 2023, 15: 24427–24436
Wan P, Xie H, Zhang N, et al. Stepwise hollow Prussian blue nanoframes/carbon nanotubes composite film as ultrahigh rate sodium ion cathode. Adv Funct Mater, 2020, 30: 2002624
Hu M, Dai J, Chen L, et al. Selectivity for intercalated ions in MXene toward a high-performance capacitive electrode. Sci China Mater, 2022, 66: 974–981
Wang X, Wang X, Nian H, et al. Hierarchical MXene/polypyrrole-decorated carbon nanofibers for asymmetrical capacitive deionization. ACS Appl Mater Interfaces, 2022, 14: 53150–53164
Yu F, Yang Z, Zhang X, et al. V2CTx-MXene partially derived hybrid VS2/V2CTx electrode for capacitive deionization with exceptional rate and capacity. J Mater Chem A, 2022, 10: 23531–23541
Gao F, Li X, Shi W, et al. Highly selective recovery of phosphorus from wastewater via capacitive deionization enabled by ferrocene-polyaniline-functionalized carbon nanotube electrodes. ACS Appl Mater Interfaces, 2022, 14: 31962–31972
Shi W, Ma J, Gao F, et al. Metal-organic framework with a redox-active bridge enables electrochemically highly selective removal of arsenic from water. Environ Sci Technol, 2023, 57: 6342–6352
Qie H, Liu M, Fu X, et al. Interfacial charge-modulated multifunctional MoS2/Ti3C2Tx penetrating electrode for high-efficiency freshwater production. ACS Nano, 2022, 16: 18898–18909
Wang L, Yuan Z, Zhang Y, et al. Sandwich layered double hydroxides with graphene oxide for enhanced water desalination. Sci China Mater, 2021, 65: 803–810
Wang L, Zhang P, Chen K, et al. Synthetic subnanochannels in porous aromatic frameworks accelerate selective water permeation in membrane desalination. Sci China Mater, 2022, 65: 1920–1928
Wang Y, El-Deen AG, Li P, et al. High-performance capacitive deionization disinfection of water with graphene oxide-graft-quaternized chitosan nanohybrid electrode coating. ACS Nano, 2015, 9: acsnano.5b03763
El-Deen AG, Boom RM, Kim HY, et al. Flexible 3D nanoporous graphene for desalination and bio-decontamination of brackish water via asymmetric capacitive deionization. ACS Appl Mater Interfaces, 2016, 8: 25313–25325
Wang J, Wang G, Wu T, et al. Quaternary ammonium compound functionalized activated carbon electrode for capacitive deionization disinfection. ACS Sustain Chem Eng, 2018, 6: 17204–17210
Liu N, Ren P, Saleem A, et al. Simultaneous efficient decontamination of bacteria and heavy metals via capacitive deionization using polydopamine/polyhexamethylene guanidine co-deposited activated carbon electrodes. ACS Appl Mater Interfaces, 2021, 13: 61669–61680
Yin X, Li H, Yuan R, et al. General formation of Prussian blue analogue microtubes for high-performance Na-ion hybrid supercapacitors. Sci China Mater, 2020, 63: 739–747
Ye S, Yang X, Huang Z, et al. The activity origin of FeCo Prussian blue analogue for ambient electrochemical hydrogenation of nitrate to ammonia in neutral electrolyte. Sci China Mater, 2023, 66: 3573–3581
Shapira B, Avraham E, Aurbach D. Side reactions in capacitive deionization (CDI) processes: The role of oxygen reduction. Electrochim Acta, 2016, 220: 285–295
Zhao H, Jiao T, Zhang L, et al. Preparation and adsorption capacity evaluation of graphene oxide-chitosan composite hydrogels. Sci China Mater, 2015, 58: 811–818
Guan K, Liu Q, Zhou G, et al. Cation-diffusion controlled formation of thin graphene oxide composite membranes for efficient ethanol dehydration. Sci China Mater, 2019, 62: 925–935
Zheng K, Li K, Chang TH, et al. Synergistic antimicrobial capability of magnetically oriented graphene oxide conjugated with gold nanoclusters. Adv Funct Mater, 2019, 29: 1904603
Shi W, Liu X, Deng T, et al. Enabling superior sodium capture for efficient water desalination by a tubular polyaniline decorated with prussian blue nanocrystals. Adv Mater, 2020, 32: 1907404
Cao S, Chen T, Zheng S, et al. High-performance capacitive deionization and killing microorganism in surface-water by ZIF-9 derived carbon composites. Small Methods, 2021, 5: 2101070
Hatami M, Hosseini SM, Ghorbanpour M, et al. Physiological and antioxidative responses to GO/PANI nanocomposite in intact and demucilaged seeds and young seedlings of Salvia mirzayanii. Chemosphere, 2019, 233: 920–935
Du W, Xiao J, Geng H, et al. Rational-design of polyaniline cathode using proton doping strategy by graphene oxide for enhanced aqueous zinc-ion batteries. J Power Sources, 2020, 450: 227716
Gaikwad MS, Balomajumder C. Simultaneous electrosorptive removal of chromium(VI) and fluoride ions by capacitive deionization (CDI): Multicomponent isotherm modeling and kinetic study. Separ Purif Tech, 2017, 186: 272–281
Agartan L, Hayes-Oberst B, Byles BW, et al. Influence of operating conditions and cathode parameters on desalination performance of hybrid CDI systems. Desalination, 2019, 452: 1–8
Panda S, Rout TK, Prusty AD, et al. Electron transfer directed antibacterial properties of graphene oxide on metals. Adv Mater, 2018, 30: 1702149
Li B, Luo Y, Zheng Y, et al. Two-dimensional antibacterial materials. Prog Mater Sci, 2022, 130: 100976
Shi T, Hou X, Guo S, et al. Nanohole-boosted electron transport between nanomaterials and bacteria as a concept for nano-bio interactions. Nat Commun, 2021, 12: 493