Propylene oxide-assisted fast sol–gel synthesis of mesoporous and nano-structured LiFePO4/C cathode materials

Ionics - Tập 19 Số 3 - Trang 451-460 - 2013
Fuqing Wang1,2, Jian Chen2, Minghao Wu1,2, Baolian Yi2
1Graduate University of the Chinese Academy of Sciences, Beijing, China
2Laboratory of Advanced Rechargeable Batteries, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

Tóm tắt

Từ khóa


Tài liệu tham khảo

Huang H, Yin SC, Nazar LF (2001) Approaching theoretical capacity of LiFePO4 at room temperature at high rates. Electrochem Solid-State Lett 4:A170–A172

Doeff MM, Hu YQ, McLarnon F, Kostecki R (2003) Effect of surface carbon structure on the electrochemical performance of LiFePO4. Electrochem Solid-State Lett 6:A207–A209

Dominko R, Bele M, Gaberscek M, Remskar M, Hanzel D, Pejovnik S, Jamnik J (2005) Impact of the carbon coating thickness on the electrochemical performance of LiFePO4/C composites. J Electrochem Soc 152:A607–A610

Yi TF, Li XY, Liu H, Shu J, Zhu YR, Zhu RS (2012) Recent developments in the doping and surface modification of LiFePO4 as cathode material for power lithium ion battery. Ionics. doi: 10.1007/s11581-012-0695-y

Cao YL, Yu LH, Li T, Ai XP, Yang HX (2007) Synthesis and electrochemical characterization of carbon-coated nanocrystalline LiFePO4 prepared by polyacrylates–pyrolysis route. J Power Sources 172:913–918

Croce F, D’ Epifanio A, Hassoun J, Deptula A, Olczac T, Scrosati B (2002) A novel concept for the synthesis of an improved LiFePO4 lithium battery cathode. Electrochem Solid-State Lett 5:A47–A50

Huang YH, Goodenough JB (2008) High-rate LiFePO4 lithium rechargeable battery promoted by electrochemically active polymers. Chem Mater 20:7237–7241

Chung SY, Bloking JT, Chiang YM (2002) Electronically conductive phospho-olivines as lithium storage electrodes. Nat Mater 1:123–127

Wang DY, Li H, Shi SQ, Huang XJ, Chen LQ (2005) Improving the rate performance of LiFePO4 by Fe-site doping. Electrochim Acta 50:2955–2958

Wang ZL, Sun SR, Xia DG, Chu WS, Zhang S, Wu ZY (2008) Investigation of electronic conductivity and occupancy sites of Mo doped into LiFePO4 by ab initio calculation and X-ray absorption spectroscopy. J Phys Chem C 112:17450–17455

Heo JB, Lee SB, Cho SH, Kim J, Park SH, Lee YS (2009) Synthesis and electrochemical characterizations of dual doped Li1.05Fe0.997Cu0.003PO4. Mater Lett 63:581–583

Kang B, Ceder G (2009) Battery materials for ultrafast charging and discharging. Nature 458:190–193

Liu JL, Jiang RR, Wang XY, Huang T, Yu AS (2009) The defect chemistry of LiFePO4 prepared by hydrothermal method at different pH values. J Power Sources 194:536–540

Qin X, Wang XH, Xiang HM, Xie J, Li JJ, Zhou YC (2010) Mechanism for hydrothermal synthesis of LiFePO4 platelets as cathode material for lithium-ion batteries. J Phys Chem C 114:16806–16812

Ni JF, Morishita M, Kawabe Y, Watada M, Takeichi N, Sakai T (2010) Hydrothermal preparation of LiFePO4 nanocrystals mediated by organic acid. J Power Sources 195:2877–2882

Ferrari S, Lavall RL, Capsoni D, Quartarone E, Magistris A, Mustarelli P, Canton P (2010) Influence of particle size and crystal orientation on the electrochemical behavior of carbon-coated LiFePO4. J Phys Chem C 114:12598–12603

Bodoardo S, Gerbaldi C, Meligrana G, Tuel A, Enzo S, Penazzi N (2009) Optimisation of some parameters for the preparation of nanostructured LiFePO4/C cathode. Ionics 15:19–26

Hsu KF, Tsay SY, Hwang BJ (2004) Synthesis and characterization of nano-sized LiFePO4 cathode materials prepared by a citric acid-based sol–gel route. J Mater Chem 14:2690–2695

Xu ZH, Xu L, Lai QY, Ji XY (2007) A PEG assisted sol–gel synthesis of LiFePO4 as cathodic material for lithium ion cells. Mater Res Bull 42:883–891

Liu YY, Cao CB, Li J (2010) Enhanced electrochemical performance of carbon nanospheres–LiFePO4 composite by PEG based sol–gel synthesis. Electrochim Acta 55:3921–3926

Dominko R, Bele M, Gaberscek M, Remskar M, Hanzel D, Goupil JM, Pejovnik S, Jamnik J (2006) Porous olivine composites synthesized by sol–gel technique. J Power Sources 153:274–280

Kim JK, Choi JW, Chauhan GS, Ahn JH, Hwang GC, Choi JB, Ahn HJ (2008) Enhancement of electrochemical performance of lithium iron phosphate by controlled sol–gel synthesis. Electrochim Acta 53:8258–8264

Göktepe H, Şahan H, Kılıç F, Patat Ş (2010) Improved of cathode performance of LiFePO4/C composite using different carboxylic acids as carbon sources for lithium-ion batteries. Ionics 16:203–208

Sundarayya Y, Kumara Swamy KC, Sunandana CS (2007) Oxalate based non-aqueous sol–gel synthesis of phase pure sub-micron LiFePO4. Mater Res Bull 42:1942–1948

Hu Y, Doeff MM, Kostecki R, Fiñones R (2004) Electrochemical performance of sol–gel synthesized LiFePO4 in lithium batteries. J Electrochem Soc 151:A1279–A1285

Xu J, Chen G, Xie CD, Li X, Zhou YH (2008) Synthesis and electrochemical performance of LiFePO4/C prepared by a new method. Solid State Commun 147:443–446

Ni JF, Zhou HH, Chen JT, Zhang XX (2005) LiFePO4 doped with ions prepared by co-precipitation method. Mater Lett 59:2361–2365

Lee MH, Kim JY, Song HK (2010) A hollow sphere secondary structure of LiFePO4 nanoparticles. Chem Commun 46:6795–6797

Yu F, Zhang JJ, Yang YF, Song GZ (2009) Preparation and characterization of mesoporous LiFePO4/C microsphere by spray drying assisted template method. J Power Sources 189:794–797

Gómez LS, de Meatza I, Martín MI, Bengoechea M, Cantero I, Rabanal ME (2010) Morphological, structural and electrochemical properties of lithium iron phosphates synthesized by spray pyrolysis. Electrochim Acta 55:2805–2809

Liu J, Conry TE, Song XY, Doeff MM, Richardson TJ (2011) Nanoporous spherical LiFePO4 for high performance cathodes. Energy Environ Sci 4:885–888

Gash AE, Tillotson TM, Satcher JH Jr, Poco JF, Hrubesh LW, Simpson RL (2001) Use of epoxides in the sol–gel synthesis of porous iron(III) oxide monoliths from Fe(III) salts. Chem Mater 13:999–1007

Baumann TF, Kucheyev SO, Gash AE, Satcher JH Jr (2005) Facile synthesis of a crystalline, high-surface-area SnO2 aerogel. Adv Mater 17:1546–1548

Camponeschi E, Walker J, Garmestani H, Tannenbaum R (2008) Surfactant effects on the particle size of iron(III) oxides formed by sol–gel synthesis. J Non-Cryst Solids 354:4063–4069

Gao YP, Sisk CN, Hope-Weeks LJ (2007) A sol–gel route to synthesize monolithic zinc oxide aerogels. Chem Mater 19:6007–6011

Zhao LH, Clapsaddle BJ, Satcher JH Jr, Schaefer DW, Shea KJ (2005) Integrated chemical systems: the simultaneous formation of hybrid nanocomposites of iron oxide and organo silsesquioxanes. Chem Mater 17:1358–1366

Cui HT, Zayat M, Levy D (2005) Sol–gel synthesis of nanoscaled spinels using propylene oxide as a gelation agent. J Sol-Gel Sci Technol 35:175–181

Cui HT, Jia YY, Ren WZ, Wang WH (2010) Facile and ultra large scale synthesis of nearly monodispersed CoFe2O4 nanoparticles by a low temperature sol–gel route. J Sol-Gel Sci Technol 55:36–40

Tokudome Y, Fujita K, Nakanishi K, Miura K, Hirao K (2007) Synthesis of monolithic Al2O3 with well-defined macropores and mesostructured skeletons via the sol–gel process accompanied by phase separation. Chem Mater 19:3393–3398

Chervin CN, Clapsaddle BJ, Chiu HW, Gash AE, Satcher JH Jr, Kauzlarich SM (2006) Role of cyclic ether and solvent in a non-alkoxide sol–gel synthesis of yttria-stabilized zirconia nanoparticles. Chem Mater 18:4865–4874

Tokudome Y, Miyasaka A, Nakanishi K, Hanada T (2011) Synthesis of hierarchical macro/mesoporous dicalcium phosphate monolith via epoxide-mediated sol–gel reaction from ionic precursors. J Sol-Gel Sci Technol 57:269–278

Hasegawa G, Ishihara Y, Kanamori K, Miyazaki K, Yamada Y, Nakanishi K, Abe T (2011) Facile preparation of monolithic LiFePO4/carbon composites with well-defined macropores for a lithium-ion battery. Chem Mater 23:5208–5216

Xu YB, Lu YJ, Yan L, Yang ZY, Yang RD (2006) Synthesis and effect of forming Fe2P phase on the physics and electrochemical properties of LiFePO4/C materials. J Power Sources 160:570–576

Herle PS, Ellis B, Coombs N, Nazar LF (2004) Nano-network electronic conduction in iron and nickel olivine phosphates. Nat Mater 3:147–152

Islam MS, Driscoll DJ, Fisher CAJ, Slater PR (2005) Atomic-scale investigation of defects, dopants, and lithium transport in the LiFePO4 olivine-type battery material. Chem Mater 17:5085–5092

Song MS, Kim DY, Kang YM, Kim Y-II, Lee JY, Kwon HS (2008) Amphoteric effects of Fe2P on electrochemical performance of lithium iron phosphate–carbon composite synthesized by ball-milling and microwave heating. J Power Sources 180:546–552

Arnold G, Garche J, Hemmer R, Ströbele S, Vogler C, Wohlfahrt-Mehrens M (2003) Fine-particle lithium iron phosphate LiFePO4 synthesized by a new low-cost aqueous precipitation technique. J Power Sources 119–121:247–251

Dominko R, Bele M, Goupil J-M, Gaberscek M, Hanzel D, Arcon I, Jamnik J (2007) Wired porous cathode materials: a novel concept for synthesis of LiFePO4. Chem Mater 19:2960–2969

Kalaiselvi N, Manthiram A (2010) One-pot, glycine-assisted combustion synthesis and characterization of nanoporous LiFePO4/C composite cathodes for lithium-ion batteries. J Power Sources 195:2894–2899

Yamada A, Koizumi H, Sonoyama N, Kanno R (2005) Phase change in Li x FePO4. Electrochem Solid-State Lett 8:A409–A413

Gibot P, Casas-cabanas M, Laffont L, Levasseur S, Carlach P, Hamelet S, Tarascon J-M, Masquelier C (2008) Room-temperature single-phase Li insertion/extraction in nanoscale Li x FePO4. Nat Mater 7:741–747

Meethong N, Huang H-YS, Carter WC, Chiang Y-M (2007) Size-dependent lithium miscibility gap in nanoscale Li1−x FePO4. Electrochem Solid-State Lett 10:A134–A138

Kobayashi G, Nishimura S-I, Park M-S, Kanno R, Yashima M, Ida T, Yamada A (2009) Isolation of solid solution phases in size-controlled Li x FePO4 at room temperature. Adv Funct Mater 19:395–403

Dokko K, Mohamedi M, Fujita Y, Itoh T, Nishizawa M, Umeda M, Uchida I (2001) Kinetic characterization of single particles of LiCoO2 by AC impedance and potential step methods. J Electrochem Soc 148:A422–A426