Sản xuất hydrochar rắn từ tảo biển thải bằng phương pháp cacbon hóa thủy nhiệt: tác động của các biến quá trình

Sepideh Soroush1,2, Frederik Ronsse2, An Verberckmoes3, Francis Verpoort1,4, Jihae Park5, Di Wu1,2,6, Philippe M. Heynderickx1,2
1Center for Environmental and Energy Research (CEER) - Engineering of Materials via Catalysis and Characterization, Ghent University Global Campus, Incheon, South Korea
2Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Ghent, Belgium
3Department of Materials, Textiles and Chemical Engineering, Faculty of Engineering and Architecture, Ghent University, Gent, Belgium
4Department of Organometallics, Catalysis and Ordered Materials, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Center for Chemical and Material Engineering, Wuhan University of Technology, Wuhan, People’s Republic of China
5Lab of Plant Growth Analysis, Ghent University Global Campus, Incheon, South Korea
6Department of Civil and Environmental Engineering, Chinese National Engineering Research Center for Control & Treatment of Heavy Metal Pollution (Hong Kong Branch) and Water Technology Center, The Hong Kong University of Science and Technology, Hong Kong, China

Tóm tắt

Nghiên cứu này cung cấp một so sánh về hydrochar từ cacbon hóa thủy nhiệt (HTC), bắt đầu từ hai loài tảo biển thải khác nhau, cụ thể là tảo xanh Ulva pertusa và tảo nâu Sargassum horneri. Tác động của nhiệt độ phản ứng (180 ~ 250 ℃), thời gian lưu giữ sinh khối (1 ~ 6 h), và tỷ lệ khối lượng nước (1 ~ 10) lên năng suất HTC (38 ~ 57%) đã được nghiên cứu. Diện tích bề mặt (5 ~ 52 m2 g−1), hiệu quả loại bỏ methylene blue (71 ~ 99%), khả năng hấp phụ methylene blue (11 ~ 88%), và thành phần hydrochar đã được đánh giá. Thời gian lưu giữ tăng và nhiệt độ HTC dẫn đến sự gia tăng diện tích bề mặt lên tới mức tối đa là 51 m2 g−1, trong khi năng suất trong hydrochar HTC giảm khoảng 35% cho cả hai loại. Hình vẽ van Krevelen đã được mở rộng để so sánh sự biến đổi trong thành phần nguyên tố của hydrochar thu được từ tảo biển thải. Kết quả của các thí nghiệm hấp phụ methylene blue được mô tả tốt nhất bởi mô hình Langmuir với giá trị khả năng hấp phụ tối đa là 112 ± 7.63 mg g−1 cho hydrochar dựa trên Sargassum, được sản xuất ở nhiệt độ 180 ℃, với tỷ lệ nước/sinh khối là 5 và thời gian lưu giữ 4 h.

Từ khóa

#cacbon hóa thủy nhiệt #hydrochar #tảo biển thải #hấp phụ #methylene blue

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