Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates

Parikka, M. Global biomass fuel resources. Biomass Bioenergy 27, 613–620 (2004)

Ragauskas, A. J. et al. The path forward for biofuels and biomaterials. Science 311, 484–489 (2006)

Barlow, M. T., Smith, D. J. & Steward, D. G. Fuel composition. European patent EP0082689. (1983)

Román-Leshkov, Y., Chheda, J. N. & Dumesic, J. A. Phase modifiers promote efficient production of hydroxymethylfurfural from fructose. Science 312, 1933–1937 (2006)

Brown, D. W., Floyd, A. J., Kinsman, R. G. & Roshan-Ali, Y. Dehydration reactions of fructose in non-aqueous media. J. Chem. Technol. Biotechnol. 32, 920–924 (1982)

Kuster, B. M. F. 5-Hydroxymethylfurfural (HMF). A review focussing on its manufacture. Starch 42, 314–321 (1990)

Moreau, C., Belgacem, M. N. & Gandini, A. Recent catalytic advances in the chemistry of substituted furans from carbohydrates and in the ensuing polymers. Top. Catal. 27, 11–30 (2004)

Szmant, H. H. & Chundury, D. D. The preparation of 5-hydroxymethylfurfuraldehyde from high fructose corn syrup and other carbohydrates. J. Chem. Technol. Biotechnol. 31, 135–145 (1981)

van Dam, H. E., Kieboom, A. P. G. & van Bekkum, H. The conversion of fructose and glucose in acidic media: Formation of hydroxymethylfurfural. Starch 38, 95–101 (1986)

Eisen, E. O. & Joffe, J. Salt effects in liquid-liquid equilibria. J. Chem. Eng. Data 11, 480–484 (1966)

Tan, T. C. & Aravinth, S. Liquid-liquid equilibria of water/acetic acid/1-butanol system—effects of sodium (potassium) chloride and correlations. Fluid Phase Equil. 163, 243–257 (1999)

Neier, W., Webers, W., Ruckhaber, R., Osterburg, G. & Ostwald, W. Continuous production of sec-butanol. German patent DE3040997. (1982)

Jones, D. T. & Woods, D. R. Acetone-butanol fermentation revisited. Microbiol. Rev. 50, 484–524 (1986)

Ramey, E. D. Continuous two-stage dual path anaerobic fermentation of butanol and other organic solvents using two different strains of bacteria. US patent US5753474. (1998)

Manly, D. G. & Dunlop, A. P. Catalytic hydrogenation. I. Kinetics and catalyst composition in the preparation of 2-methylfuran. J. Org. Chem. 23, 1093–1095 (1958)

Rao, R. S., Baker, R. T. & Vannice, M. A. Furfural hydrogenation over carbon-supported copper. Catal. Lett. 60, 51–57 (1999)

Zheng, H.-Y. et al. Towards understanding the reaction pathway in vapour phase hydrogenation of furfural to 2-methylfuran. J. Mol. Catal. Chem. 246, 18–23 (2006)

Twigg, M. V. & Spencer, M. S. Deactivation of supported copper metal catalysts for hydrogenation reactions. Appl. Catal. A 212, 161–174 (2001)

Helms, C. R. & Sinfelt, J. H. Electron spectroscopy (ESCA) studies of ruthenium-copper catalysts. Surf. Sci. 72, 229–242 (1978)

Sinfelt, J. H. Supported bimetallic cluster catalysts. J. Catal. 29, 308–315 (1973)

Sinfelt, J. H., Lam, Y. L. & Cusumano, J. A. Nature of ruthenium-copper catalysts. J. Catal. 42, 227–237 (1976)

Broughton, D. B. & Gerhold, C. G. Continuous sorption process employing fixed beds of sorbent and moving inlets and outlets. US Patent US2985589. (1961)

Hashimoto, K., Adachi, S. & Shirai, Y. in Preparative and Production Scale Chromatography (eds Ganestos, G. & Barker, P. E.) 395–417 (CRC Publishing, New York, 1993)

Jones, J. H., Fenske, M. R. & Rusk, R. A. Vapor-phase oxidation as a process for raising octane number. Ind. Eng. Chem. Prod. Res. Dev. 10, 57–65 (1971)

Graboski, M. S. An Analysis of Alternatives for Unleaded Petrol Additives for South Africa (Technical Report, United Nations Environment Programme, Nairobi, Kenya, 2003); available at 〈 http://www.unep.org/PCFV/PDF/PubGraboskiReport.pdf 〉