Processability of pure Zn and pure Fe by SLM for biodegradable metallic implant manufacturing

Emerald - Tập 23 Số 3 - Trang 514-523 - 2017
M. Eugenia Montani1, Ali Gökhan Demir1, Ehsan Mostaed1, Maurizio Vedani1, Barbara Previtali1
1Department of Mechanical Engineering, Poliecnico di Milano, Milan, Italy

Tóm tắt

Purpose This paper aims to investigate the processability by selective laser melting (SLM) of materials of potential interest for innovative biodegradable implants, pure Fe and pure Zn. The processability of these materials is evaluated with a more established counterpart in permanent implants, stainless steel. In particular, the processing conditions were studied to reduce porosity due to incomplete fusion of the powder. Design/methodology/approach In the first phase of the experiments, SLM of AISI 316L was studied through design of experiments method. The study was used to identify the significant parameters in the experimental range and estimate the fluence ranges for pure Fe and pure Zn using the lumped heat capacity model. In the second phase, SLM of pure Fe and pure Zn were studied using estimated fluence ranges. In the final phase, best conditions were characterized for mechanical properties. Findings The results showed that complete melting of AISI 316L and pure Fe could be readily achieved, whereas laser melting generated a foam-like porous structure in Zn samples. The mechanical properties of laser melt implant materials were compared to as-cast and rolled counterparts. Laser melted AISI 316L showed superior mechanical performance compared to as-cast and rolled material, whereas Fe showed mechanical performance similar to rolled mild steel. Despite 12 per cent apparent porosity, laser melted Zn exhibited superior mechanical properties compared to as-cast and wrought material because of reduced grain size. Originality/value The paper provides key processing knowledge on the SLM processability of new biodegradable metals, namely, pure Fe, which has been studied sparingly, and pure Zn, on which no previous work is available. The results prefigure the production of new biodegradable metallic implants with superior mechanical properties compared to their polymeric counterparts and with improved degradation rates compared to magnesium alloys, the reference material for biodegradable metals.

Từ khóa


Tài liệu tham khảo

2013, Fatigue behavior of porous biomaterials manufactured using selective laser melting, Materials Science and Engineering: C, 33, 4849, 10.1016/j.msec.2013.08.006

ASM International, 1990, Properties of pure metals, “properties and selection: nonferrous alloys and special-purpose materials’, ASM Handbook, 2

2014, Manufacture by selective laser melting and mechanical behavior of commercially pure titanium, Materials Science and Engineering: A, 593, 170, 10.1016/j.msea.2013.11.038

2013, Zinc exhibits ideal physiological corrosion behavior for bioabsorbable stents, Advanced Materials, 25, 2577, 10.1002/adma.201300226

2012, Effect of selective laser melting layout on the quality of stainless steel parts, Rapid Prototyping Journal, 18, 241, 10.1108/13552541211218216

2016, Processability of different IN738LC powder batches by selective laser melting, Journal of Materials Processing Technology, 229, 484, 10.1016/j.jmatprotec.2015.09.046

2012, Laser additive manufacturing of metallic components: materials, processes and mechanisms, International Materials Reviews, 57, 133, 10.1179/1743280411Y.0000000014

2010, Degradable metallic biomaterials: design and development of Fe-Mn alloys for stents, Journal of Biomedical Materials Research Part A, 93, 1

2010, Fe-Mn alloys for metallic biodegradable stents: degradation and cell viability studies, Acta Biomaterials, 6, 1852, 10.1016/j.actbio.2009.11.025

2014, Density of additively-manufactured, 316L SS parts using laser powder-bed fusion at powers up to 400 W, The International Journal of Advanced Manufacturing Technology, 74, 65

1999, Optimization of powder layer density in selective laser sintering, 255

2004, Selective laser melting of iron-based powder, Journal of Materials Processing Technology, 149, 616

2010, Densification behavior of gas and water atomized 316L stainless steel powder during selective laser melting, Applied Surface Science, 256, 4350, 10.1016/j.apsusc.2010.02.030

2008, Experimental studies on selective laser melting of metallic parts, Materwiss Werksttech, 39, 665, 10.1002/mawe.200800327

2010, Electroformed iron as new biomaterial for degradable stents: development process and structure-properties relationship, Acta Biomaterials, 6, 1726, 10.1016/j.actbio.2010.01.010

2016, Novel Zn-based alloys for biodegradable stent applications: design, development and in vitro degradation, Journal of the Mechanical Behavior of Biomedical Materials, 60, 581, 10.1016/j.jmbbm.2016.03.018

2012, Metal fabrication by additive manufacturing using laser and electron beam melting technologies, Journal of Materials Science & Technology, 28, 1, 10.1016/S1005-0302(12)60016-4

2007, Biodegradable polymers as biomaterials, Progress in Polymer Science, 32, 762

2011, Fabrication of magnesium using selective laser melting technique, Rapid Prototyping Journal, 17, 479, 10.1108/13552541111184206

2011, Microstructure and mechanical properties of selective laser melted magnesium, Applied Surface Science, 257, 7447, 10.1016/j.apsusc.2011.03.004

2008, Steel castings properties, casting, ASM Handbook

2015, On the role of melt flow into the surface structure and porosity development during selective laser melting, Acta Mater, 96, 72, 10.1016/j.actamat.2015.06.004

2016, In Vitro cytotoxicity, adhesion, and proliferation of human vascular cells exposed to zinc, ACS Biomaterials Science & Engineering, 2, 634, 10.1021/acsbiomaterials.6b00035

2012, Effects of processing parameters on microstructure and mechanical property of selective laser melted Ti6Al4V, Materials Design, 35, 120, 10.1016/j.matdes.2011.09.051

2014, Microstructure and tensile properties of iron parts fabricated by selective laser melting, Optics & Laser Technology, 56, 451

2014, Vacuum heat treatment of iron parts produced by selective laser melting: Microstructure, residual stress and tensile behavior, Materials Design, 54, 727, 10.1016/j.matdes.2013.08.085

2014, Research on rapid manufacturing of CoCrMo alloy femoral component based on selective laser melting, The International Journal of Advanced Manufacturing Technology, 75, 445

2009, Comparison of density of stainless steel 316L parts produced with selective laser melting using different powder grades, 342

2009, The development of a scanning strategy for the manufacture of porous biomaterials by selective laser melting, Journal of Materials Science: Materials in Medicine, 20, 1839

2010, Laser Material Processing, 4th ed.

2007, Selective laser melting of biocompatible metals for rapid manufacturing of medical parts, Rapid Prototyping Journal, 13, 196, 10.1108/13552540710776142

2011, Mechanical and corrosion properties of newly developed biodegradable Zn-based alloys for bone fixation, Acta Biomaterials, 7, 3515, 10.1016/j.actbio.2011.05.008

1990, Wrought Stainless Steels, properties and selection: irons, steels, and high-performance alloys, ASM Handbook

2011, Microstructure, cytotoxicity and corrosion of powder-metallurgical iron alloys for biodegradable bone replacement materials, Materials Science and Engineering: B, 176, 1789, 10.1016/j.mseb.2011.04.017

2014, Effect of energy input on formability, microstructure and mechanical properties of selective laser melted AZ91D magnesium alloy, Materials Science and Engineering: A, 611, 212, 10.1016/j.msea.2014.05.092

2008, Degradable biomaterials based on magnesium corrosion, Current Opinion in Solid State and Materials Science, 12, 63

2012, In vitro biocompatibility of Co-Cr alloy fabricated by selective laser melting or traditional casting techniques, Materials Letters, 88, 101, 10.1016/j.matlet.2012.08.032

2013, Surface properties and corrosion behavior of Co-Cr alloy fabricated with selective laser melting technique, Cell Biochem. Biophys, 67, 983, 10.1007/s12013-013-9593-9

2010, Selective laser melting technology: from the single laser melted track stability to 3D parts of complex shape, Phys Procedia, 5, 551, 10.1016/j.phpro.2010.08.083

2011, Microstructural investigation of selective laser melting 316L stainless steel parts exposed to laser re-melting, Procedia Engineering, 19, 389, 10.1016/j.proeng.2011.11.130

2014, Microstructure, corrosion, and mechanical properties of compression-molded zinc-nanodiamond composites, Journal of Materials Science, 49, 3629, 10.1007/s10853-014-8066-x

2012, Effects of processing parameters on properties of selective laser melting Mg–9%Al powder mixture, Materials Design, 34, 753

2014, Effects of scan line spacing on pore characteristics and mechanical properties of porous Ti6Al4V implants fabricated by selective laser melting, Materials Design, 63, 185, 10.1016/j.matdes.2014.05.021

2014, Biodegradable metals, Materials Science and Engineering: R: Reports, 77, 1, 10.1016/j.mser.2014.01.001

2009, Biocompatibility of pure iron: in vitro assessment of degradation kinetics and cytotoxicity on endothelial cells, Materials Science and Engineering: C, 29, 1589, 10.1016/j.msec.2008.12.019

ASTM E112-96, 2004, Standard Test Methods for Determining Average Grain Size

ASTM E9-09, 2009, Test Methods of Compression Testing of Metallic Materials at Room Temperature, Annual Book of ASTM Standards