Preparation of polymer nanoparticles, and the effect of nanoconfinement on glass transition, structural relaxation and crystallization

Frontiers of Chemistry in China - Tập 6 - Trang 332-340 - 2012
Rong Chen1, Dinghai Huang1
1Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin, China

Tóm tắt

In this review the preparation methods of polymer nanoparticles from chemical microemulsion polymerization to physical methods such as spray-drying, freeze-drying, freeze-extracting, fast evaporation and spreading evaporation have been summarized. The influence of nanoconfinement on glass transition temperature (T g) variation from significant or slight decrease, no evident T g deviation, to even T g increase, as well as possible explanations of T g deviations were discussed. The influences of nanoconfinement or entanglement on the other properties such as structural relaxation, crystallization in polymer nanoparticle samples were also reviewed in this article.

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