Preparation of high performance green alumina ceramic balls by roller production waste

Lianyun Zhong1,2,3, Bolin Wu2, Lianmeng Zhang1, Guifang Zhang2
1State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, China
2Key Lab of Nonferrous Materials and New Processing Technology (Guangxi University, Guilin University of Technology) of Ministry of Education, Guilin, China
3School of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning, China

Tóm tắt

To reuse roller waste as a raw material of high performance green ceramic balls, three kinds of white alumina ceramic balls whose wear resistance were 2–3 times of the best high alumina ceramic ball with 90% Al2O3 were prepared, and the Al2O3 content of the prepared balls was 75%. It is found that the effect of calcia and magnesia on the wear resistance of ceramic balls is contrast to the accepted one: the wear rate of the ceramic balls prepared in CaO-Al2O3-SiO2 system is the lowest and the wear rate of the ceramic balls prepared in MgO-Al2O3-SiO2 is the highest. The main crystal phase of the ceramic ball is mullite and corundum. The ceramic ball granular is uniform and fine with 4–5 μm average size. The pore diameter is about 2 μm. The wear way of the ceramic balls is mainly transcrystalline fracture.

Tài liệu tham khảo

M Sathiyalumar, F D Gnanam. Influence of Additives on Density, Microstructure and Mechanical Properties of Alumina[J]. J. Mat. Proc. Tech., 2003, 133:282–286 Eugene Medvedovski. Wear-resistant Engineering Ceramic[J]. Wear, 2001, 249: 821–828 Linqing Qin, Bolin Wu, Xinglong Duan, et al, Production and Application of Wear-resistant Alumina Ceramic Grinding Balls[J]. J. Wuhan Uni. Tech-Mat. Sci. Edi., 2001, 16(3): 12–15 Alumina of Hu. Balance In Turbulance Situation Show Uncommon[N]. Future Daily, 27 November, 2003 James P Bennett and Kyei-sing Kwong. Reusing Spent Refractory Materials[J]. Ceramic Industry, 1997, 11: 46–54 James P Bennett and M Abbot Maginns. Recycling/Disposal Issues of Refractories[J]. Ceram. Eng. Sci. Proc., 1995, 16(1): 127–141 Zhangming Lu. The Avenues to Improve the Properties of 95 wt% Alumina Ceramics and Sinter at Low Temperature[J]. Electronic Components & Materials, 1995,14(4): 13–17 Jingkun Guo. The Exploration on New Approach of Strengthening and Toughening of Ceramic Materials[J]. J. Inorg. Mat., 1998, 13(1): 23–26 Jiwen Liang. Mineralography[M]. Wuhan: Wunan Library Press, 1984: 1 258–1 259 Charlws E Semler. Overview of the U.S. Refractories Industry[J]. Ceramic Industry, 1994,142(2): 33–38