Preparation and characterization of sulfamic acid pyridinium chloride-functionalized Fe3O4 nanoparticles as a novel magnetic catalyst for synthesis of novel N-coumarin-2-furanones

Research on Chemical Intermediates - Tập 43 - Trang 7193-7209 - 2017
Sakineh Asghari1,2, Majid Mohammadnia1
1Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
2Nano and Biotechnology Research Group, University of Mazandaran, Babolsar, Iran

Tóm tắt

Sulfamic acid pyridinium chloride-functionalized Fe3O4 nanoparticles as a novel organic-inorganic hybrid heterogeneous catalyst was manufactured and characterized by FT-IR, XRD, TGA, SEM, TEM and VSM techniques. The catalytic activity of the nanomagnetic catalyst was investigated in the multicomponent reactions of arylaldehydes, 7-amino-4-methylcoumarin and dialkyl acetylenedicarboxylate that afford the novel N-coumarin-2-furanones. This green nanocatalytic procedure has good reversibility and provides clean production in a short reaction time. Preparation and characterization of sulfamic acid pyridinium chloride-functionalized Fe3O4 nanoparticles as a novel magnetic catalyst for synthesis of novel N-coumarin-2-furanone.

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