Polymorphism in the family of Ln6−xMoO12−δ(Ln = La, Gd–Lu; x = 0, 0.5) oxygen ion- and proton-conducting materials

Journal of Materials Chemistry A - Tập 5 Số 16 - Trang 7618-7630
A.V. Shlyakhtina1,2,3,4, Stanislav N. Savvin5,6,7,8,9, Н. В. Лысков10,11,2,3, И. В. Колбанев1,2,3,4, O.K. Karyagina12,13,2,3, S. A. Chernyak14,15,1,2, Л. Г. Щербакова1,2,3,4, P. Núñez5,6,7,8,9
1Moscow
2Russia
3Russian Academy of Sciences
4Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia
5Department of Inorganic Chemistry, Institute of Materials and Nanotechnology, University of La Laguna, Tenerife, La Laguna, Spain
6Institute of Materials and Nanotechnology
7La Laguna
8Spain
9University of La Laguna
10Chernogolovka 142432
11Institute of Problems of Chemical Physics, Russian Academy of Sciences, Academician Semenov ave. 1, Chernogolovka 142432, Moscow Region, Russia
12Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow 119991, Russia
13Moscow 119991
14Department of Chemistry
15Lomonosov Moscow State University

Tóm tắt

Arrhenius plots of the total conductivity in (1 and 3) dry and (2 and 4) wet air of two Yb6MoO12polymorphs: (1 and 2) bixbyite (Ia3̄(206)) Yb6MoO12and (3 and 4) rhombohedral (R3̄) Yb6MoO12; Yb6MoO12rhombohedral (R3̄) → Yb6MoO12bixbyite (Ia3̄(206)) atT∼ 1600 °C.

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Journal of Materials Chemistry A

Tập 5 Số 16

7618-7630

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