Physicochemical Properties of Solutions of Amides in H2O and in D2O
Tóm tắt
Excess volume, partial molar volumes, viscosity, and ultrasound velocity in H2O and D2O solutions of formamide (FM), acetamide (AM), dimethylformamide (DMF), and dimethylacetamide (DMA) were studied at 20°C. The change in the excess volume of the various amide solutions on substitution of D2O for H2O varies both in magnitude and direction. On the other hand, the isotope effect on the ultrasound velocity behaves similarly in all cases. Its magnitude is greatest for pure water and then decreases monotonically with increasing amide concentration. Although the behavior of the concentration dependence of viscosity is similar to that for ultrasound velocity, the isotope effect on the viscosity behaves in a different way. For methyl-substitued amides, a maximum isotope effect is observed at amide mole fraction 0.2, but the isotope effect for FM and AM increases monotonically with increasing amide concentration. The differences in the behavior of amides in aqueous solution are discussed in terms of their interactions with water.
Tài liệu tham khảo
L. Boeje and A. Hvidt, J. Chem. Thermodyn. 3, 663 (1971).
A. Juszkiewicz, Z. Phys. Chem. Neue Folge 158, 87 (1988).
P. Rhodewald and M. Moeldner, J. Phys. Chem. 77, 373 (1973).
V. S. Goncharov, A. K. Lashchenko, and P. S. Yastremskij, Zh. Strukt. Khim. 17, 662 (1976).
I. V. Matiash, A. I. Torianyk, and V. V. Kiselnyk, Zh. Strukt. Khim. 8, 418 (1967).
P. J. Bernal and W. A. Van Hook, J. Chem. Thermodyn. 18, 955 (1986).
A. Sacco and E. Matteoli, J. Solution Chem. 26, 527 (1997).
K. Miyai, M. Nakamura, K. Tamura, and S. Murakami, J. Solution Chem. 26, 973 (1997).
R. J. Fort and W. R. Moore, Trans. Faraday Soc. 61, 2102 (1965).
Y. Uosaki, F. Iwama, and T. Moriyoshi, J. Chem. Thermodyn. 24, 797 (1992).
T. M. Aminabhavi and B. Gopalakrishna, J. Chem. Eng. Data 40, 856 (1995).
J. N. Spencer, J. Phys. Chem. 85, 1236 (1981).
F. Shahidi, P. G. Farrell, and J. T. Edward, J. Chem. Soc. Faraday Trans. I 73, 715 (1977).
C. de Visser, W. J. M. Heuvelsland, L. A. Dunn, and G. Somsen, J. Chem. Soc. Faraday Trans. I 74, 1159 (1978).
O. Kiyohara, G. Perron, and J. E. Desnoyers, Can. J. Chem. 53, 3263 (1975).
I. B. Rabinovich, Influence of Isotopy on the Physicochemical Properties of Liquids (Consultants Bureau, New York, 1970).
T. T. Herskovits and T. M. Kelly, J. Phys. Chem. 77, 381 (1973).
S. L. Oswal and N. B. Patel, J Chem. Eng. Data 40, 845 (1995).
D. Wolf and A. I. Kudish, J. Phys. Chem. 84, 921 (1980).
M. Holz, X. Mao, and D. Seiferling, J. Chem. Phys. 104, 669 (1996).