Photoluminescent phenylated polyfluorenes synthesized in an organic solvent and supercritical carbon dioxide

Pleiades Publishing Ltd - Tập 54 - Trang 106-114 - 2012
M. L. Keshtov1, E. I. Mal’tsev2, A. M. Lopatin1, L. N. Nikitin1, D. V. Marochkin3, V. P. Perevalov3, P. V. Petrovskii1, A. R. Khokhlov1
1Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
2Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia
3Mendeleev University of Chemical Technology, Moscow, Russia

Tóm tắt

A number of new phenylated polyfluorenes with blue emission are synthesized via the Diels-Alder reaction in chloronaphthalene and supercritical carbon dioxide. It is shown that these polymers are thermally stable. A comparative analysis of their properties shows that a “green” solvent is a suitable alternative to organic solvents for obtaining phenyl-substituted polyfluorenes via the Diels-Alder reaction.

Tài liệu tham khảo

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