Photoinduced water oxidation catalyzed by a double-helical dicobalt(<scp>ii</scp>) sexipyridine complex

Chemical Communications - Tập 50 Số 95 - Trang 14956-14959
Man Chen1,2,3,4,5, Siu‐Mui Ng2,3,6, Shek‐Man Yiu2,3,6, Kai‐Chung Lau2,3,6, Raymond Jianxiong Zeng1,7,4,5,8, Tai‐Chu Lau1,2,9,3,5
1Advanced Laboratory for Environmental Research & Technology (ALERT), USTC-CityU, Suzhou 215123, China
2City University of Hong Kong,
3Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, SAR, China
4Department of Chemistry, University of Science & Technology of China, Hefei 230026, China
5USTC-CityU
6Kowloon, China
7Department of Chemistry
8University of Science & Technology of China
9Department of Biology and Chemistry

Tóm tắt

A dicobalt(ii) sexipyridine complex functions as a molecular catalyst for visible light-induced water oxidation at pH 8–8.5 in the presence of Ru(bpy)32+ and S2O82−.

Từ khóa


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