Phase relations in the Cu-O-Al2O3-SiO2 system at 1150 °C and 1300 °C in air

Niko Hellstén1, Pekka Taskinen1
1Aalto University, School of Chemical Engineering, Department of Chemical and Metallurgical Engineering, Metallurgical Thermodynamics and Modelling Research Group, Vuorimiehentie 2K, PO Box 16200, FI-00076 Aalto, Finland

Tài liệu tham khảo

Kosenko, 2001, Equilibrium phase relationships in the system Cu-O under high oxygen pressure, J. Phase Equilib., 22, 12, 10.1007/s11669-001-0050-x Matusita, 1983, Thermal expansion of substituted copper aluminosilicate glasses, J. Am. Ceram. Soc., 66, 33, 10.1111/j.1151-2916.1983.tb09963.x Roy, 2013, Electrical and dielectric properties of sol–gel derived mullite doped with transition metals, Mater. Chem. Phys., 138, 375, 10.1016/j.matchemphys.2012.11.070 Cardona, 2011, The physical chemistry of copper smelting slags and copper losses at the Paipote smelter part 2 – characterisation of industrial slags, Can. Metall. Q, 50, 330, 10.1179/000844311X13112418194806 Hellstén, 2016, High-temperature phase equilibria of Cu–O–Al2O3 system in air, Can. Metall. Q., 55, 226, 10.1080/00084433.2016.1151601 Xia, 2016, Equilibrium study of the Cu–O–SiO2 system at various oxygen partial pressures, J. Chem. Thermodyn., 98, 126, 10.1016/j.jct.2016.03.023 Aksay, 1975, Stable and metastable equilibria in the system SiO2-Al2O3, J. Am. Ceram. Soc., 58, 507, 10.1111/j.1151-2916.1975.tb18770.x Hidayat, 2012, Phase equilibria studies of Cu-O-Si systems in equilibrium with air and metallic copper and Cu-Me-O-Si systems (Me = Ca, Mg, Al, and Fe) in equilibrium with metallic copper, Metall. Mater. Trans. B, 43, 1290, 10.1007/s11663-012-9735-2 Chen, 2013, Phase equilibrium studies of "Cu2O"-SiO2-Al2O3 system in equilibrium with metallic copper, J. Am. Ceram. Soc., 96, 3631, 10.1111/jace.12573 Lambert, 1986, New copper ((II)) — rare earth ((III)) compounds I. ternary systems CuO-M2O3-TO2, Powder Diffr., 1, 45, 10.1017/S088571560001157X Xiao, 2008, Isothermal section of a Cu2O-Al2O3-SiO2 pseudo-ternary system at 1150°C in air, J. Am. Ceram. Soc., 91, 252, 10.1111/j.1551-2916.2007.02097.x T. Oishi, T. Ohba, K. Ono, A thermodynamic study of the alumina-saturated copper oxide (Cu2O)-silicon dioxide melts in equilibrium with liquid copper, in: Proceedings of the First International Symposium on Molten Salt Chemistry and Technology, Kyoto, Japan, pp. 213–216, 1983. Jak, 2008, Phase equilibria determination in complex slag systems, Trans. Inst. Min. Metall. C, 117, 1 Davies, 2002, MTDATA - thermodynamics and phase equilibrium software from the national physical laboratory, Calphad, 26, 229, 10.1016/S0364-5916(02)00036-6 I. Vaajamo, J. Gisby, P. Taskinen, An Extensive Slag Database: Lead-ing the way, in: Proceedings of the 12th World Copper Conference, Santiago, Chile, pp. 621–634, 2013. Gisby, 2017, MTDATA and the prediction of phase equilibria in oxide systems: 30 years of industrial collaboration, Metall. Mater. Trans. B, 48, 91, 10.1007/s11663-016-0811-x Hellstén, 2016, High-temperature phase equilibria of Cu–O–MgO system in air, Thermochim. Acta, 623, 107, 10.1016/j.tca.2015.10.019 J. L. Pouchou, F. Pichoir, Basic expression of "PAP" computation for quantitative EPMA, in: Proceedings of the 11th International Congress on X-ray Optics and Microanalysis (IXCOM), London, Ontario, Canada, 1986, pp. 249-253. Nash, 1992, Analysis of oxygen with electron microprobe: applications to hydrated glass and minerals, Am. Mineral., 77, 453 Rigby, 2009, Electron probe, S. Afr. J. Geol., 111, 239, 10.2113/gssajg.111.2-3.239 Zhao, 2009 Zhao, 1983, The theorem of corresponding relation between neighboring phase regions and their boundaries in phase diagrams ((I)), Calphad, 7, 185, 10.1016/0364-5916(83)90002-0 Chang, 2010, Two-Phase Equilibrium I: Theory, 103 H. Rannikko, A thermodynamic assessment of the Cu-O-CaO-SiO2 system (1995). von Wartenberg, 1932, Schmelzdiagramme höchstfeuerfester oxyde: IV, aluminiumoxyd, Z. Anorg. Allgem. Chem., 207, 1, 10.1002/zaac.19322070102 Schmalzried, 1960, Measurement of the free enthalpy of reaction in the formation of spinel phases from the single oxides by aid of solid galvanic couples, Z. Phys. Chem., 25, 178, 10.1524/zpch.1960.25.3_4.178 Rigby, 1961, Examination of basic brick from copper anode furnaces, J. Am. Ceram. Soc., 44, 201, 10.1111/j.1151-2916.1961.tb15360.x Misra, 1963, The system copper oxide - alumina, J. Am. Ceram. Soc., 46, 509, 10.1111/j.1151-2916.1963.tb13788.x Gadalla, 1963, Equilibrium relationships in the system CuO-Cu2O-Al2O3, Br. Ceram. Trans. J., 63, 39 Navrotsky, 1968, Thermodynamics of formation of simple spinels, J. Inorg. Nucl. Chem., 30, 479, 10.1016/0022-1902(68)80475-0 Zalazinskii, 1969, Thermodynamic analysis of the reduction, dissociation, and formation from the elements and oxides of copper(I) aluminate (CuAlO2), chromate(III) (CuCrO2), and ferrate(III) (CuFeO2), Russ. J. Inorg. Chem., 14, 326 O. Kubaschewski, Thermodynamic properties of double oxides, High Temp.- High Pressures, 4 (1972), pp. 1-12. Jacob, 1975, Thermodynamics of CuAlO2 and CuAl2O4 and phase equilibria in the system Cu2O-CuO-Al2O3, J. Am. Ceram. Soc., 58, 192, 10.1111/j.1151-2916.1975.tb11441.x Jacob, 1975, Oxygen potential of the systems iron + iron chromite (FeCr2O4) + chromium(III) oxide and iron + iron vanadite (FeV2O4) + vanadium(III) oxide in the temperature range 750-1600 deg, Metall. Trans. B, 6B, 215, 10.1007/BF02913562 Kubaschewski, 1993 M.A. Zinovik, Thermodynamics of oxides with a spinel structure, Ukr. Khim. Zh. (Russ.Ed.), 62 (1996) 83-88. Meyer, 1999, Microemulsion mediated sol-gel synthesis of nano-scaled MAl2O4 (M=Co, Ni, Cu) spinels from single-source heterobimetallic alkoxide precursors, J. Mater. Chem., 9, 1755, 10.1039/a900014c Berezhnoi, 1952, The system Cu2O-SiO2 and the existence of anhydrous copper silicates, Dokl. Akad. Nauk SSSR, 83, 399 Gadalla, 1963, Equilibrium relations in the system CuO-Cu2O-SiO2, Trans. Br. Ceram. Soc., 62, 45 Ust'yantsev, 1966, X-ray diffraction study of the CuO-SiO2 and Cu2O-SiO2 systems, Zh. Neorg. Khim., 11, 1177 Kuxmann, 1968, Die mischungslücke im system kupfer-sauerstoff und ihre beeinflussung durch die oxide CaO, SiO2, Al2O3, MgO • Al2O3 and ZrO2, Erzmetall., 21, 199 C. Landolt, Equilibrium studies in the system copper--silicon--oxygen (1969). Peddada, 1993, The activity of CuO0. 5 along the air isobars in the systems copper-oxygen-silica and copper-oxygen-calcia at 1300°C, Metall. Trans. B., 24B, 59, 10.1007/BF02657872 Dinsdale, 1991, SGTE data for pure elements, Calphad., 15, 317, 10.1016/0364-5916(91)90030-N Sommer, 1982, Association model for the description of the thermodynamic functions of liquid alloys. I: basic concepts, Z. Metallkd., 73, 72 Barry, 1993, Predictive thermochemistry and phase equilibria of slags, JOM, 45, 32, 10.1007/BF03223284 Matusita, 1979, Low expansion copper aluminosilicate glasses, J. Non Cryst. Solids, 30, 285, 10.1016/0022-3093(79)90167-4 Wheaton, 2007, Evaluation of phase separation in glasses with the use of atomic force microscopy, J. Non Cryst. Solids, 353, 4767, 10.1016/j.jnoncrysol.2007.06.073 Shelby, 2005 Schneider, 2015, Mullite: crystal structure and related properties, J. Am. Ceram. Soc., 98, 2948, 10.1111/jace.13817 Low, 1989, The origins of mullite formation, J. Mater. Sci., 24, 926, 10.1007/BF01148780