Performance and cost of materials for lithium-based rechargeable automotive batteries

Nature Energy - Tập 3 Số 4 - Trang 267-278
Richard Schmuch1, Ralf Wagner1, Gerhard Hörpel2, Tobias Placke1, Martin Winter3
1University of Münster, MEET Battery Research Center, Münster, Germany
2GBH Gesellschaft für Batterie Know-how mbH, Nottuln, Germany
3Helmholtz-Institute Münster, IEK-12, Forschungszentrum Jülich GmbH, Münster, Germany

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Westbrook, M. H. The Electric Car: Development & Future of Battery, Hybrid & Fuel-Cell Cars (Institution of Engineering and Technology, 2001).

Reddy, T. Linden’s Handbook of Batteries, 4th Edition (McGraw-Hill Education, New York, 2010).

Winter, M. & Besenhard, J. O. Wiederaufladbare Batterien. Teil 1: Akkumulatoren mit wäβriger Elektrolytlösung. Chemie Unserer Zeit 33, 252–266 (1999).

Scrosati, B., Garche, J. & Tillmetz, W. Advances in Battery Technologies for Electric Vehicles (Elsevier, 2015).

2017 Annual Merit Review, Vehicle Technologies Office (US Department of Energy, 2017); http://go.nature.com/2EFTGeh

Placke, T., Kloepsch, R., Dühnen, S. & Winter, M. Lithium-ion, lithium metal and alternative rechargeable battery technologies: the odyssey for high energy density. J. Solid State Electrochem. 21, 1939–1964 (2017). This article comprehensively reviews the history of battery technologies and offers perspectives of lithium-ion and post lithium ion batteries.

Meister, P. et al. Best practice: performance and cost evaluation of lithium ion battery active materials with special emphasis on energy efficiency. Chem. Mater. 28, 7203–7217 (2016).

Andre, D. et al. Future generations of cathode materials: an automotive industry perspective. J. Mater. Chem. A 3, 6709–6732 (2015). This Review describes the requirements for positive active materials (energy density, rate capability, capacity retention, cost and safety) for automotive LIBs from an OEM erspective.

Hagen, M. et al. Lithium–sulfur cells: the gap between the state-of-the-art and the requirements for high energy battery cells. Adv. Energy Mater. 5, 1401986 (2015).

Gröger, O., Gasteiger, H. A. & Suchsland, J.-P. Review—Electromobility: Batteries or fuel cells? J. Electrochem. Soc. 162, A2605–A2622 (2015).

Blomgren, G. E. The development and future of lithium ion batteries. J. Electrochem. Soc. 164, A5019–A5025 (2017).

Pillot, C. The Rechargeable Battery Market and Main Trends 2016–2025 (Avicenne Energy, 2017).

Winter, M. & Besenhard, J. O. in Handbook of Battery Materials 2nd edn (eds Daniel, C. & Besenhard, J. O.) 433–478 (Wiley VCH, Weinheim, 2011).

Korthauer, R. Handbuch Lithium–Ionen–Batterien (Springer Vieweg, Heidelberg, 2013).

Juri, G., Wilhelm, H. A. & L’Heureux, J. High-purity graphite powders for high performance. Cfi-Ceramic Forum Int. 84, E22–E25 (2007).

Liang, G. & MacNeil, D. D. in Lithium-Ion Batteries: Advanced Materials and Technologies Green Chemistry and Chemical Engineering (eds Yuan, X., Liu, H. & Zhang, J.) 327–394 (CRC Press, Boca Raton, 2011).

Dunn, J. B. et al. Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries (ANL/ESD-14/10 Rev.) (Argonne National Laboratory, 2015). This report gives a comprehensive overview of material flows in the production of anode and cathode materials for lithium ion batteries.

Chehreh Chelgani, S., Rudolph, M., Kratzsch, R., Sandmann, D. & Gutzmer, J. A review of graphite beneficiation techniques. Mineral Proc. Extractive Metallurgy Rev. 37, 58–68 (2016).

Lämmerer, W. & Flachberger, H. Wissenswertes zur Charakterisierung und Aufbereitung von Rohgrafiten. BHM Berg Hüttenmännische Monatshefte 162, 336–344 (2017).

Wiggers, H., Starke, R. & Roth, P. Silicon particle formation by pyrolysis of silane in a hot wall gasphase reactor. Chem. Engineering Technol. 24, 261–264 (2001).

Doh, C.-H. et al. A new SiO/C anode composition for lithium-ion battery. J. Power Sources 179, 367–370 (2008).

Chen, T., Wu, J., Zhang, Q. & Su, X. Recent advancement of SiOx based anodes for lithium-ion batteries. J. Power Sources 363, 126–144 (2017).

Takeda, O. et al. Electrowinning of lithium from LiOH in molten chloride. J. Electrochem. Soc. 161, D820–D823 (2014).

Tran, T. & Luong, V. T. in Lithium Process Chemistry: Resources, Extraction, Batteries, and Recycling (eds Chagnes, A. & Swiatowska, J.) 81–124 (Elsevier, 2015).

Jónsson, E. Ö. & Larsson, F. Securing Lithium Foil Supply in a Future Imbalanced Market: A Strategy Suggestion for a Prospective Battery Cell Manufacturer (Chalmers University of Technology, 2016).

Wietelmann, U. Surface-passivated lithium metal and method for the production thereof. US patent 13,515,579 (2012).

Ciez, R. E. & Whitacre, J. F. The cost of lithium is unlikely to upend the price of Li-ion storage systems. J. Power Sources 320, 310–313 (2016).

Facada, M. A 21st century lithium rush. Industrial Minerals (4 December 2017).

Global Lithium Report (Macquarie Research, 2016).

Ryou, M.-H., Lee, Y. M., Lee, Y., Winter, M. & Bieker, P. Mechanical surface modification of lithium metal: towards improved Li metal anode performance by directed Li plating. Adv. Funct. Mater. 25, 825 (2014).

Becking, J. et al. Lithium-metal foil surface modification: an effective method to improve the cycling performance of lithium-metal batteries. Adv. Mater. Interfaces 4, 1700166 (2017).

Heine, J. et al. Coated lithium powder (CLiP) electrodes for lithium-metal batteries. Adv. Energy Mater. 4, 1300815–1300821 (2013).

Obrovac, M. N. & Chevrier, V. L. Alloy negative electrodes for Li-ion batteries. Chem. Rev. 114, 11444–11502 (2014). An in-depth overview of the fundamentals of alloy-based anode materials is reported and comprehensively discussed in view of their practical application in lithium ion full cells.

Nitta, N. & Yushin, G. High-capacity anode materials for lithium-ion batteries: choice of elements and structures for active particles. Particle Particle Syst. Characterization 31, 317–336 (2014).

Ryu, J., Hong, D., Lee, H.-W. & Park, S. Practical considerations of Si-based anodes for lithium-ion battery applications. Nano Res. 10, 3970–4002 (2017).

Holtstiege, F., Wilken, A., Winter, M. & Placke, T. Running out of lithium? A route to differentiate between capacity losses and active lithium losses in lithium-ion batteries. Phys. Chem. Chem. Phys. 19, 25905–25918 (2017).

Cheng, X.-B., Zhang, R., Zhao, C.-Z. & Zhang, Q. Toward safe lithium metal anode in rechargeable batteries: A review. Chem. Rev. 117, 10403–10473 (2017).

Tikekar, M. D., Choudhury, S., Tu, Z. & Archer, L. A. Design principles for electrolytes and interfaces for stable lithium-metal batteries. Nat. Energy 1, 16114 (2016).

Aravindan, V., Lee, Y.-S. & Madhavi, S. Best practices for mitigating irreversible capacity loss of negative electrodes in Li-ion batteries. Adv. Energy Mater. 7, 1602607–1602623 (2017).

Janek, J. & Zeier, W. G. A solid future for battery development. Nat. Energy 1, 16141–16144 (2016). This Perspective gives a critical view on the future developments, challenges and limitations of all-solid-state batteries.

Myung, S.-T. et al. Nickel-rich layered cathode materials for automotive lithium-ion batteries: achievements and perspectives. ACS Energy Lett. 2, 196–223 (2017).

Noh, H.-J., Youn, S., Yoon, C. S. & Sun, Y.-K. Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries. J. Power Sources 233, 121–130 (2013).

Sun, Y.-K., Myung, S.-T., Kim, M.-H., Prakash, J. & Amine, K. Synthesis and characterization of Li[(Ni0.8Co0.1Mn0.1)0.8(Ni0.5Mn0.5)0.2]O2 with the microscale core−shell structure as the positive electrode material for lithium batteries. J. Am. Chem. Soc. 127, 13411–13418 (2005).

Lim, B.-B., Myung, S.-T., Yoon, C. S. & Sun, Y.-K. Comparative study of Ni-rich layered cathodes for rechargeable lithium batteries: Li[Ni0.85Co0.11Al0.04]O2 and Li[Ni0.84Co0.06Mn0.09Al0.01]O2 with two-step full concentration gradients. ACS Energy Lett. 1, 283–289 (2016).

Whittingham, M. S. Ultimate limits to intercalation reactions for lithium batteries. Chem. Rev. 114, 11414–11443 (2014).This Article discusses various alternative cathode chemistries beyond layered oxides with emphasis on lithium metal phosphates, as well as the ultimate limits of intercalation chemistry with regard to their maximum energy content (Wh kg –1 and Wh l –1 ).

Thackeray, M. M., Wolverton, C. & Isaacs, E. D. Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ. Sci. 5, 7854–7863 (2012).

Qiu, B. et al. Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries. Nat. Commun. 7, 12108 (2016).

Schipper, F. et al. Study of cathode materials for lithium-ion batteries: recent progress and new challenges. Inorganics 5, 32 (2017).

Bettge, M. et al. Voltage fade of layered oxides: its measurement and impact on energy density. J. Electrochem. Soc. 160, A2046–A2055 (2013).

Saubanere, M., McCalla, E., Tarascon, J.-M. & Doublet, M.-L. The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries. Energy Environ. Sci. 9, 984–991 (2015).

Ahmed, S., Nelson, P. A., Gallagher, K. G., Susarla, N. & Dees, D. W. Cost and energy demand of producing nickel manganese cobalt cathode material for lithium ion batteries. J. Power Sources 342, 733–740 (2017).

Jugović, D. & Uskoković, D. A review of recent developments in the synthesis procedures of lithium iron phosphate powders. J. Power Sources 190, 538–544 (2009).

Yakovleva, M. From Raw Material to Next Generation Advanced Batteries (FMC Corporation, 2017).

Chen, Z. H., Qin, Y., Amine, K. & Sun, Y. K. Role of surface coating on cathode materials for lithium-ion batteries. J. Mater. Chem. 20, 7606–7612 (2010).

Ewald, B., Krkljus, I. & Lampert, J. K. Method for Producing Electrode Materials. Patent WO2013171059 A1 (2013).

Thackeray, M. Lithium-ion batteries: An unexpected conductor. Nat. Mater. 1, 81–82 (2002).

Commodity and Metal Prices (Infomine, 2017); http://go.nature.com/2EFNJdh

Nelson, P., Gallagher, K., Bloom, I. & Dees, D. Modeling the Performance and Cost of Lithium-Ion Batteries for Electric-Drive Vehicles ANL-11/32 (Chemical Sciences and Engineering Division of Argonne National Laboratory, 2011).

Simon, B., Ziemann, S. & Weil, M. Potential metal requirement of active materials in lithium-ion battery cells of electric vehicles and its impact on reserves: Focus on Europe. Resour. Conservation Recycling 104, 300–310 (2015).

Mineral Commodity Summaries 2017 (US Department of the Interior, US Geological Survey, 2017).

Study on the Review of the List of Critical Raw Materials: Non-Critical Raw Materials Factsheets (European Commission, 2017); http://doi.org/ckn7

Xu, K. Electrolytes and interphases in Li-ion batteries and beyond. Chem. Rev. 114, 11503–11618 (2014). This Review provides a still up-to-date summary of liquid electrolytes used in past and current lithium-based batteries including the basic electrolyte and electrode/electrolyte interface theory, for both beginners and experts.

Schmitz, R. W. et al. Investigations on novel electrolytes, solvents and SEI additives for use in lithium-ion batteries: Systematic electrochemical characterization and detailed analysis by spectroscopic methods. Prog. Solid State Chem. 42, 65–84 (2014).

Zhang, S. S. A review on electrolyte additives for lithium-ion batteries. J. Power Sources 162, 1379–1394 (2006).

Xu, K. Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem. Rev. 104, 4303–4417 (2004).

Pacheco, M. A. & Marshall, C. L. Review of dimethyl carbonate (DMC) manufacture and its characteristics as a fuel additive. Energy Fuels 11, 2–29 (1997).

Raines, D. A. & Ainsworth, O. C. Ethylene carbonate process. US patent 4233,221 (1979).

Garcia-Herrero, I. et al. Environmental assessment of dimethyl carbonate production: Comparison of a novel electrosynthesis route utilizing CO2 with a commercial oxidative carbonylation process. ACS Sustain. Chem. Engineer 4, 2088–2097 (2016).

Naitou, T. et al. Method of manufacturing diethyl carbonate. US patent 20,150,291,504 A1 (2015).

Inaba, M. et al. Process for producing unsymmetrical chain carbonic acid ester. US patent 5,760,273 A (1998).

Na, D. C., Woo, B. W., Park, S. H. & Lee, J. H. Manufacturing method for lithium hexafluoro phosphate. US patent 6,387,340 B1 (2002).

Lu, H. L. Present Technology and Market Development Trends of Electrolyte and Separator for LIB (Second International Forum on Electrolyte & Separator for Advanced Batteries, 2015).

Kasnatscheew, J. et al. Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies. Phys. Chem. Chem. Phys. 19, 16078–16086 (2017).

Lebedeva, N. P. & Boon-Brett, L. Considerations on the chemical toxicity of contemporary Li-ion battery electrolytes and their components. J. Electrochem. Soc. 163, A821–A830 (2016).

Nowak, S. & Winter, M. Review—chemical analysis for a better understanding of aging and degradation mechanisms of non-aqueous electrolytes for lithium ion batteries: method development, application and lessons learned. J. Electrochem. Soc. 162, A2500–A2508 (2015).

Lee, H., Yanilmaz, M., Toprakci, O., Fu, K. & Zhang, X. A review of recent developments in membrane separators for rechargeable lithium-ion batteries. Energy Environ. Sci. 7, 3857–3886 (2014). This Article gives an in-depth overview of the recent developments, characteristics and production processes of membrane separators for lithium ion batteries, in addition to covering the field of solid electrolytes.

Arora, P. & Zhang, Z. M. Battery separators. Chem. Rev. 104, 4419–4462 (2004).

Bachman, J. C. et al. Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem. Rev. 116, 140–162 (2016).

Motavalli, J. Technology: a solid future. Nature 526, S96–S97 (2015).

Rodrigues, M.-T. F. et al. A materials perspective on Li-ion batteries at extreme temperatures. Nat. Energy 2, 17108 (2017).

Manthiram, A., Yu, X. & Wang, S. Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev. Mater. 2, 16103 (2017).

Anderman, M. xEV Expansion, Key Technology, and Market Development (Total Battery Consulting, 2017).

Cekic-Laskovic, I. et al. Synergistic effect of blended components in nonaqueous electrolytes for lithium ion batteries. Topics Current Chem. 375, 37 (2017).

Gambe, Y., Sun, Y. & Honma, I. Development of bipolar all-solid-state lithium battery based on quasi-solid-state electrolyte containing tetraglyme-LiTFSA equimolar complex. Sci. Rep. 5, 8869 (2015).

Kim, C. R., Tajitsu, N. & Nussey, S. Toyota set to sell long-range, fast-charging electric cars in 2022: paper. Reuters (25 July 2017).

Manthiram, A., Fu, Y., Chung, S.-H., Zu, C. & Su, Y.-S. Rechargeable lithium–sulfur batteries. Chem. Rev. 114, 11751–11787 (2014).

Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J. M. Li–O2 and Li–S batteries with high energy storage. Nat. Mater. 11, 19–29 (2012).

Judez, X. et al. Review—Solid electrolytes for safe and high energy density lithium–sulfur batteries: promises and challenges. J. Electrochem. Soc. 165, A6008–A6016 (2018).

Freunberger, S. A. True performance metrics in beyond-intercalation batteries. Nat. Energy 2, 17091 (2017). This Comment highlights the importance of reporting complete experimental data sets and objectifies the comparison between intercalation and post-intercalation chemistries.

Gallagher, K. G. et al. Quantifying the promise of lithium-air batteries for electric vehicles. Energy Environ. Sci. 7, 1555–1563 (2014).

Nykvist, B. & Nilsson, M. Rapidly falling costs of battery packs for electric vehicles. Nat. Clim. Change 5, 329–332 (2015).

Sauer, D. U. Don’t wait for the next battery-cell generation. ATZelektronik Worldwide 11, 72–72 (2016).

Copper (Eco3e, 2016); http://go.nature.com/2Ffymcu

Helbig, C., Bradshaw, A. M., Wietschel, L., Thorenz, A. & Tuma, A. Supply risks associated with lithium-ion battery materials. J. Cleaner Prod. 172, 274–286 (2018).

Reuter, B. Assessment of sustainability issues for the selection of materials and technologies during product design: a case study of lithium-ion batteries for electric vehicles. Int. J. Interactive Design Manufactur 10, 217–227 (2016).

Berg, E. J., Villevieille, C., Streich, D., Trabesinger, S. & Novák, P. Rechargeable batteries: grasping for the limits of chemistry. J. Electrochem. Soc. 162, A2468–A2475 (2015).

Patry, G., Romagny, A., Martinet, S. & Froelich, D. Cost modeling of lithium-ion battery cells for automotive applications. Energy Sci. Engineer 3, 71–82 (2014).

Nelson, P., Gallagher, K. & Bloom, I. BatPaC (Battery Performance and Cost) Software (Argonne National Lab, accessed 10 August 2017); http://go.nature.com/2C8tw25. This Article offers an in-depth, spreadsheet-based, regularly updated calculation tool to estimate cost and energy density of various battery designs following a bottom-up approach.