Percolation in carbon black filled epoxy resin

Macromolecular Symposia - Tập 104 Số 1 - Trang 261-268 - 1996
Ruediger Schueler1, J. Petermann2, Karl Schulte1, Hans‐Peter Wentzel3
1Technical University Hamburg‐Harburg, Polymer / Composites Section, Denickestr. 15, D‐21071 Hamburg, Germany;
2University of Dortmund, Emil‐Figge‐Str. 66, D‐44221 Dortmund, Germany;
3Daimler‐Benz Aerospace Airbus, D‐28183 Bremen, Germany

Tóm tắt

AbstractThe conditions to form a conductive network in carbon black filled epoxy resin were examined. It was found that the formation is controlled by particle‐particle interaction which can be influenced by shear forces or by the ionic concentration of the resin. Therefore the network morphology and thus the percolation threshold depends strongly upon the processing route. On best conditions the percolation threshold was reduced to 0.06 vol.‐%. That a continuous network can form with such a low volume fraction can be explained by the fractal dimension of agglomerates the network is made of.

Từ khóa


Tài liệu tham khảo

Jachym B. J., 1982, Carbon Black‐Polymer Composites

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