Paraffin wax emulsions stabilized with polymers, surfactants, and nanoparticles

Theoretical Foundations of Chemical Engineering - Tập 51 - Trang 125-132 - 2017
M. Y. Koroleva1, O. S. Gorbachevski1, E. V. Yurtov1
1Mendeleev University of Chemical Technology of Russia, Moscow, Russia

Tóm tắt

Problems preparing paraffin wax emulsions stabilized by different types of emulsifiers have been discussed. The effect of the preparation conditions and stabilizers, such as polyethylene glycol and cetyl/oleyl alcohol ether (Eumulgin O10), polyvinyl alcohol, and SiO2@Al2O3 nanoparticles (20 nm in diameter) on the dispersion of paraffin wax emulsions has been demonstrated. It has been noted that, in order to obtain paraffin wax particles with an average diameter of 400–500 nm, the concentration of PVA, Eumulgin O10, and SiO2@Al2O3 nanoparticles must be equal to 0.5, 0.5, and 1.0 wt %, respectively.

Tài liệu tham khảo

Muller, R.H., Mader, K., and Gohla, S., Solid lipid nanoparticles (SLN) for controlled drug delivery—a review of the state of the art, Eur. J. Pharm. Biopharm., 2000, vol. 50, p. 161. McClements, D.J., Encapsulation, protection, and release of hydrophilic active components: potential and limitations of colloidal delivery systems, Adv. Colloid Interface Sci., 2015, vol. 219, p. 27. Doktorovova, S., Souto, E.B., and Silva, A.M., Nanotoxicology applied to solid lipid nanoparticles and nanostructured lipid carriers - a systematic review of in vitro data, Eur. J. Pharm. Biopharm., 2014, vol. 87, p. 1. Rostami, E., Kashanian, S., Azandaryani, A.H., Faramarzi, H., Ezzati, J., Dolatabadi, N., and Omidfar, K., Drug targeting using solid lipid nanoparticles, Chem. Phys. Lipids, 2014, vol. 181, p. 56. Ji, S. and Walz, J.Y., Depletion forces and flocculation with surfactants, polymers and particles—synergistic effects, Curr. Opin. Colloid Interface Sci., 2015, vol. 20, p. 39. Llamas, S., Guzman, E., Ortega, F., Baghdadli, N., Cazeneuve, C., Rubio, R.G., and Luengo, G.S., Adsorption of polyelectrolytes and polyelectrolytes–surfactant mixtures at surfaces: a physico-chemical approach to a cosmetic challenge, Adv. Colloid Interface Sci., 2015, vol. 222, p. 461. Bureiko, A., Trybala, A., Kovalchuk, N., and Starov, V., Current applications of foams formed from mixed surfactant–polymer solutions, Adv. Colloid Interface Sci., 2015, vol. 222, p. 670. Petkova, R., Tcholakova, S., and Denkov, N.D., Foaming and foam stability for mixed polymer–surfactant solutions: effect of surfactant type and polymer charge, Langmuir, 2012, vol. 28, p. 4996. Zhang, S., Zhou, Y., and Yang, C., Pickering emulsions stabilized by the complex of polystyrene particles and chitosan, Colloids Surf., A, 2015, vol. 482, p. 338. Morishita, C. and Kawaguchi, M., Rheological and interfacial properties of Pickering emulsions prepared by fumed silica suspensions pre-adsorbed poly(n-isopropylacrylamide), Colloids Surf., A, 2009, vol. 335, p. 138. Zhu, Y., Jiang, J., Liu, K., Cui, Z., and Binks, B.P., Switchable pickering emulsions stabilized by silica nanoparticles hydrophobized in situ with a conventional cationic surfactant, Langmuir, 2015, vol. 31, p. 3301. Giermanska-Kahn, J., Laine, V., Arditty, S., Schmitt, V., and Leal-Calderon, F., Particle-stabilized emulsions comprised of solid droplets, Langmuir, 2005, vol. 21, p. 4316. Sharma, T., Kumar, G.S., Chon, B.H., and Sangwai, J.S., Thermal stability of oil-in-water Pickering emulsion in the presence of nanoparticle, surfactant, and polymer, J. Ind. Eng. Chem., 2015, vol. 22, p. 324. Derevich, I.V., Ermolaev, V.S., Zolnikova, N.V., and Mordkovich, V.Z., Calculating the dynamic viscosity of paraffins using the Lee–Kesler equation, Theor. Found. Chem. Eng., 2010, vol. 44, p. 448. Volkov, R.S., Kuznetsov, G.V., and Strizhak, P.A., Experimental estimation of characteristic times of the existence of liquid drops in the form of a sphere and ellipse upon their movement in a gas environment under the conditions of moderate Weber numbers, Theor. Found. Chem. Eng., 2015, vol. 49, p. 457. Goff, H.D. and Jordan, W.K., Action of emulsifiers in promoting fat destabilization during the manufacture of ice cream, J. Dairy Sci., 1989, vol. 72, p. 18.