Oxygen vacancies-rich cobalt-doped NiMoO4 nanosheets for high energy density and stable aqueous Ni-Zn battery

Science China Materials - Tập 63 - Trang 1205-1215 - 2020
Yuenian Shen1, Ke Zhang2, Fang Yang2, Zhihao Li1, Zhe Cui1, Rujia Zou1, Qian Liu3, Junqing Hu4, Kaibing Xu1,5
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, China
2College of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai, China
3Department of Applied Physics, Donghua University, Shanghai, China
4College of Health Science and Environmental Engineering, Shenzhen Technology University, Shenzhen, China
5Research Center for Analysis and Measurement, Donghua University, Shanghai, China

Tóm tắt

The enhancement of energy density and cycling stability is in urgent need for the widespread applications of aqueous rechargeable Ni-Zn batteries. Herein, a facile strategy has been employed to construct hierarchical Co-doped Ni-MoO4 nanosheets as the cathode for high-performance Ni-Zn battery. Benefiting from the merits of substantially improved electrical conductivity and increased concentration of oxygen vacancies, the NiMoO4 with 15% cobalt doping (denoted as CNMO-15) displays the best capacity of 361.4 mA h g−1 at a current density of 3 A g−1 and excellent cycle stability. Moreover, the assembled CNMO-15//Zn battery delivers a satisfactory specific capacity of 270.9 mA h g-1 at 2 A g−1 and a remarkable energy density of 474.1 W h kg−1 at 3.5 kW kg−1, together with a maximum power density of 10.3 kW kg−1 achieved at 118.8 W h kg−1. Noticeably, there is no capacity decay with a 119.8% retention observed after 5000 cycles, demonstrating its outstanding long lifespan. This work might provide valuable inspirations for the fabrication of high performance Ni Zn batteries with superior energy density and impressive stability.

Tài liệu tham khảo

Huang J, Wang Z, Hou M, et al. Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery. Nat Commun, 2018, 9: 2906 Pan H, Shao Y, Yan P, et al. Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat Energy, 2016, 1: 16039 Simon P, Gogotsi Y, Dunn B. Where do batteries end and super-capacitors begin? Science, 2014, 343: 1210–1211 Li YJ, Cui L, Da PF, et al. Multiscale structural engineering of Ni-doped CoO nanosheets for zinc-air batteries with high power density. Adv Mater, 2018, 30: 1804653 He J, Chen Y, Manthiram A. Metal sulfide-decorated carbon sponge as a highly efficient electrocatalyst and absorbant for polysulfide in high-loading Li2S batteries. Adv Energy Mater, 2019, 9: 1900584 Naveed A, Yang H, Shao Y, et al. A highly reversible Zn anode with intrinsically safe organic electrolyte for long-cycle-life batteries. Adv Mater, 2019, 31: 1900668 Li X, Guan C, Hu Y, et al. Nanoflakes of Ni-Co LDH and Bi2O3 assembled in 3D carbon fiber network for high-performance aqueous rechargeable Ni/Bi battery. ACS Appl Mater Interfaces, 2017, 9: 26008–26015 Sarkar D, Shukla A, Sarma DD. Substrate integrated nickel-iron ultrabattery with extraordinarily enhanced performances. ACS Energy Lett, 2016, 1: 82–88 Lei D, Lee DC, Magasinski A, et al. Performance enhancement and side reactions in rechargeable nickel-iron batteries with nanostructured electrodes. ACS Appl Mater Interfaces, 2016, 8: 2088–2096 Zhao X, Ma L, Shen X. Co-based anode materials for alkaline rechargeable Ni/Co batteries: a review. J Mater Chem, 2012, 22: 277–285 Gao XP, Yao SM, Yan TY, et al. Alkaline rechargeable Ni/Co batteries: cobalt hydroxides as negative electrode materials. Energy Environ Sci, 2009, 2: 502–505 Zeng Y, Lin Z, Meng Y, et al. Flexible ultrafast aqueous rechargeable Ni//Bi battery based on highly durable single-crystalline bismuth nanostructured anode. Adv Mater, 2016, 28: 9188–9195 Hao Z, Xu L, Liu Q, et al. On-chip Ni-Zn microbattery based on hierarchical ordered porous Ni@Ni(OH)2 microelectrode with ultrafast ion and electron transport kinetics. Adv Funct Mater, 2019, 29: 1808470 Liu J, Guan C, Zhou C, et al. A flexible quasi-solid-state nickel-zinc battery with high energy and power densities based on 3D electrode design. Adv Mater, 2016, 28: 8732–8739 Meng L, Lin D, Wang J, et al. Electrochemically activated nickelcarbon composite as ultrastable cathodes for rechargeable nickel-zinc batteries. ACS Appl Mater Interfaces, 2019, 11: 14854–14861 Huang M, Li M, Niu C, et al. Recent advances in rational electrode designs for high-performance alkaline rechargeable batteries. Adv Funct Mater, 2019, 29: 1807847 Wang R, Han Y, Wang Z, et al. Nickel@nickel oxide core-shell electrode with significantly boosted reactivity for ultrahigh-energy and stable aqueous Ni-Zn battery. Adv Funct Mater, 2018, 28: 1802157 Lee DU, Fu J, Park MG, et al. Self-assembled NiO/Ni(OH)2 nanoflakes as active material for high-power and high-energy hybrid rechargeable battery. Nano Lett, 2016, 16: 1794–1802 Shang W, Yu W, Tan P, et al. Achieving high energy density and efficiency through integration: progress in hybrid zinc batteries. J Mater Chem A, 2019, 7: 15564–15574 Tan P, Chen B, Xu H, et al. Nanoporous NiO/Ni(OH)2 plates incorporated with carbon nanotubes as active materials of rechargeable hybrid zinc batteries for improved energy efficiency and high-rate capability. J Electrochem Soc, 2018, 165: A2119–A2126 Zeng Y, Lai Z, Han Y, et al. Oxygen-vacancy and surface modulation of ultrathin nickel cobaltite nanosheets as a high-energy cathode for advanced Zn-ion batteries. Adv Mater, 2018, 30: 1802396 Wang X, Li M, Wang Y, et al. A Zn-NiO rechargeable battery with long lifespan and high energy density. J Mater Chem A, 2015, 3: 8280–8283 Jian Y, Wang D, Huang M, et al. Facile synthesis of Ni(OH)2/carbon nanofiber composites for improving NiZn battery cycling life. ACS Sustain Chem Eng, 2017, 5: 6827–6834 Xu C, Liao J, Yang C, et al. An ultrafast, high capacity and superior longevity Ni/Zn battery constructed on nickel nanowire array film. Nano Energy, 2016, 30: 900–908 Gong M, Li Y, Zhang H, et al. Ultrafast high-capacity NiZn battery with NiAlCo-layered double hydroxide. Energy Environ Sci, 2014, 7: 2025–2032 Chen C, Yan D, Luo X, et al. Construction of core-shell Ni-MoO4@Ni-Co-S nanorods as advanced electrodes for high-performance asymmetric supercapacitors. ACS Appl Mater Interfaces, 2018, 20: 4662–4671 Qing C, Yang C, Chen M, et al. Design of oxygen-deficient NiMoO4 nanoflake and nanorod arrays with enhanced supercapacitive performance. Chem Eng J, 2018, 354: 182–190 Liu Z, Zhan C, Peng L, et al. A CoMoO4−Co2Mo3O8 hetero-structure with valence-rich molybdenum for a high-performance hydrogen evolution reaction in alkaline solution. J Mater Chem A, 2019, 7: 16761–16769 Zhang Z, Zhang H, Zhang X, et al. Facile synthesis of hierarchical CoMoO4@NiMoO4 core-shell nanosheet arrays on nickel foam as an advanced electrode for asymmetric supercapacitors. J Mater Chem A, 2016, 4: 18578–18584 Cheng D, Yang Y, Xie J, et al. Hierarchical NiCo2O4@NiMoO4 core-shell hybrid nanowire/nanosheet arrays for high-performance pseudocapacitors. J Mater Chem A, 2015, 3: 14348–14357 Zhang P, Zhou J, Chen W, et al. Constructing highly-efficient electron transport channels in the 3D electrode materials for highrate supercapacitors: the case of NiCo2O4@NiMoO4 hierarchical nanostructures. Chem Eng J, 2017, 307: 687–695 Yang J, Liu W, Niu H, et al. Ultrahigh energy density battery-type asymmetric supercapacitors: NiMoO4 nanorod-decorated graphene and graphene/Fe2O3 quantum dots. Nano Res, 2018, 11: 4744–4758 Sharma GP, Pala RGS, Sivakumar S. Ultrasmall NiMoO4 robust nanoclusters-active carbon composite for high performance extrinsic pseudocapacitor. Electrochim Acta, 2019, 318: 607–616 Lei X, Ge S, Tan Y, et al. Bimetallic phosphosulfide Zn-Ni-P-S nanosheets as binder-free electrodes for aqueous asymmetric supercapacitors with impressive performance. J Mater Chem A, 2019, 7: 24908–24918 Huang J, Wei J, Xiao Y, et al. When Al-doped cobalt sulfide nanosheets meet nickel nanotube arrays: a highly efficient and stable cathode for asymmetric supercapacitors. ACS Nano, 2018, 12: 3030–3041 Ling T, Zhang T, Ge B, et al. Well-dispersed nickel- and zinc-tailored electronic structure of a transition metal oxide for highly active alkaline hydrogen evolution reaction. Adv Mater, 2019, 31: 1807771 Wang R, Lu Y, Zhou L, et al. Oxygen-deficient tungsten oxide nanorods with high crystallinity: promising stable anode for asymmetric supercapacitors. Electrochim Acta, 2018, 283: 639–645 Chiu KL, Lin LY. Applied potential-dependent performance of the nickel cobalt oxysulfide nanotube/nickel molybdenum oxide nanosheet core-shell structure in energy storage and oxygen evolution. J Mater Chem A, 2019, 7: 4626–4639 Lin J, Yao L, Li Z, et al. Hybrid hollow spheres of carbon@ CoxNi1−xMoO4 as advanced electrodes for high-performance asymmetric supercapacitors. Nanoscale, 2019, 11: 3281–3291 Xu K, Ma S, Shen Y, et al. CuCo2O4 nanowire arrays wrapped in metal oxide nanosheets as hierarchical multicomponent electrodes for supercapacitors. Chem Eng J, 2019, 369: 363–369 Ruan Y, Lv L, Li Z, et al. Ni nanoparticles@Ni-Mo nitride nanorod arrays: a novel 3D-network hierarchical structure for high areal capacitance hybrid supercapacitors. Nanoscale, 2017, 9: 18032–18041 Lu Z, Wu X, Lei X, et al. Hierarchical nanoarray materials for advanced nickel-zinc batteries. Inorg Chem Front, 2015, 2: 184–187 Shi W, Mao J, Xu X, et al. An ultra-dense NiS2/reduced graphene oxide composite cathode for high-volumetric/gravimetric energy density nickel-zinc batteries. J Mater Chem A, 2019, 7: 15654–15661 Zhou L, Zhang X, Zheng D, et al. Ni3S2@PANI core-shell nanosheets as a durable and high-energy binder-free cathode for aqueous rechargeable nickel-zinc batteries. J Mater Chem A, 2019, 7: 10629–10635 Huang M, Xu Z, Hou C, et al. Intermediate phase α-β-Ni1−xCox-(OH)2/carbon nanofiber hybrid material for high-performance nickel-zinc battery. Electrochim Acta, 2019, 298: 127–133 Lu Y, Wang J, Zeng S, et al. An ultrathin defect-rich Co3O4 nanosheet cathode for high-energy and durable aqueous zinc ion batteries. J Mater Chem A, 2019, 7: 21678–21683 Zhang H, Liu Q, Wang J, et al. Boosting the Zn-ion storage capability of birnessite manganese oxide nanoflorets by La3+ intercalation. J Mater Chem A, 2019, 7: 22079–22083 Hu P, Wang T, Zhao J, et al. Ultrafast alkaline Ni/Zn battery based on Ni-foam-supported Ni3S2 nanosheets. ACS Appl Mater Interfaces, 2015, 7: 26396–26399 Zhang H, Zhang X, Li H, et al. Flexible rechargeable Ni//Zn battery based on self-supported NiCo2O4 nanosheets with high power density and good cycling stability. Green Energy Environ, 2018, 3: 56–62 Meng A, Yuan X, Shen T, et al. One-step synthesis of flower-like Bi2O3/Bi2Se3 nanoarchitectures and NiCoSe2/Ni0.85Se nanoparticles with appealing rate capability for the construction of high-energy and long-cycle-life asymmetric aqueous batteries. J Mater Chem A, 2019, 7: 17613–17625 Chao D, Zhu CR, Song M, et al. A high-rate and stable quasi-solid-state zinc-ion battery with novel 2D layered zinc orthovanadate array. Adv Mater, 2018, 30: 1803181
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Science China Materials

Tập 63

1205-1215

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