One-pot synthesis of block copolymer dispersant by ICAR ATRP with ppm copper catalyst and the dispersibility on pigment

Feng, 2021, Role of aliphatic alcohol polyoxyethylene ether phosphate in 25 wt% tebuconazole suspension concentrate: dispersion and wetting, Colloid Surf. A, 628, 10.1016/j.colsurfa.2021.127350 Tian, 2020, Synthesis and hard water resistance mechanism of polycarboxylate dispersant for pesticide water dispersible granules, J. Disper. Sci. Technol., 41, 1892, 10.1080/01932691.2019.1638270 Yang, 2021, Dispersion performance of polycarboxylate terpolymers with different alkyl side-chain lengths in pesticide suspension concentrate, Int. J. Chem. Eng., 2021, 7188649, 10.1155/2021/7188649 Zhang, 2019, Synthesis of nonylphenol polyoxyethylene oligomer and application as an effective dispersant in pyraclostrobin suspension concentrate, Des. Monomers Polym., 22, 122, 10.1080/15685551.2019.1616374 Ettelaie, 2017, Novel food grade dispersants: review of recent progress, Curr. Opin. Colloid Interface Sci., 28, 46, 10.1016/j.cocis.2017.03.004 Farrokhpay, 2009, A review of polymeric dispersant stabilisation of titania pigment, Adv. Colloid Interf. Sci., 151, 24, 10.1016/j.cis.2009.07.004 Agbo, 2018, A review on the mechanism of pigment dispersion, J. Disper. Sci. Technol., 39, 874, 10.1080/01932691.2017.1406367 Pirrung, 2002, Wetting and dispersing agents, Chimia, 56, 170, 10.2533/000942902777680496 Reuter, 1999, The use of new blockcopolymeric dispersing agents for waterborne paints - theoretical and practical aspects, Prog. Org. Coat., 37, 161, 10.1016/S0300-9440(99)00072-7 Duivenvoorde, 2002, Use of poly(2-vinylpyridine)-b-poly(epsilon-caprolactone) copolymers as pigment stabilizers in powder coatings, J. Coat. Technol., 74, 49, 10.1007/BF02697967 Duivenvoorde, 2002, Diblock copolymer dispersants in polyester powder coatings, Prog. Org. Coat., 45, 127, 10.1016/S0300-9440(02)00046-2 Duivenvoorde, 2000, Novel block copolymers of 2-vinylpyridine and epsilon-caprolactone: synthesis and characterization, Macromol. Chem. Phys., 201, 656, 10.1002/(SICI)1521-3935(20000301)201:6<656::AID-MACP656>3.0.CO;2-Q Creutz, 2000, Effectiveness of block copolymers as stabilizers for aqueous titanium dioxide dispersions of a high solid content, Prog. Org. Coat., 40, 21, 10.1016/S0300-9440(00)00145-4 Creutz, 1998, Design of polymeric dispersants for waterborne coatings, J. Coat. Technol., 70, 41, 10.1007/BF02720518 Creutz, 1999, Effectiveness of poly(vinylpyridine) block copolymers as stabilizers of aqueous titanium dioxide dispersions of a high solid content, Langmuir, 15, 7145, 10.1021/la980951e Auschra, 2002, Design of new pigment dispersants by controlled radical polymerization, Prog. Org. Coat., 45, 83, 10.1016/S0300-9440(02)00048-6 Monteiro, 2014, Stabilization of nano-tio2 aqueous dispersions with poly(ethylene glycol)-b-poly(4-vinyl pyridine) block copolymer and their incorporation in photocatalytic acrylic varnishes, Prog. Org. Coat., 77, 1741, 10.1016/j.porgcoat.2014.05.030 Costa, 2017, Efficient dispersion of tio2 using tailor made poly(acrylic acid) - based block copolymers, and its incorporation in water based paint formulation, Prog. Org. Coat., 104, 34, 10.1016/j.porgcoat.2016.12.006 Kim, 2012, Synthesis of well-defined block copolymer dispersants with (2-dimethylamino)ethyl methacrylate and oligo(ethylene oxide)methyl ether methacrylate via atrp for dispersing copper phthalocyanine pigment, Polymer-Korea, 36, 104, 10.7317/pk.2012.36.1.104 Lokhande, 2016, Modified poly(butyl methacrylate-b-glycidyl methacrylate) dispersant for solvent-based paint by reverse atom transfer radical polymerization, Prog. Org. Coat., 90, 359, 10.1016/j.porgcoat.2015.06.025 C. Auschra A. Muehlebach E. Eckstein A. Muhlebach , Pigment Composition Used for Preparing Coating Compositions e.G. Prints, Images and Inks Comprises Block Copolymer and Dispersible Pigment Particles, in, Ciba Specialty Chem Holding Inc; Auschra C; Muhlebach a; Eckstein E; Ciba Specialty Chem Corp; Ciba Holding Inc., US6849679. North, 2021, Aqueous one-pot synthesis of well-defined zwitterionic diblock copolymers by raft polymerization: an efficient and environmentally-friendly route to a useful dispersant for aqueous pigments, Green Chem., 23, 1248, 10.1039/D0GC04271D North, 2017, Adsorption of small cationic nanoparticles onto large anionic particles from aqueous solution: a model system for understanding pigment dispersion and the problem of effective particle density, Langmuir, 33, 1275, 10.1021/acs.langmuir.6b04541 Saindane, 2015, Raft copolymerization of amphiphilic poly (ethyl acrylate-b-acrylic acid) as wetting and dispersing agents for water borne coating, Prog. Org. Coat., 79, 106, 10.1016/j.porgcoat.2014.07.016 Spinelli, 1996, Group transfer polymerization and its use in water based pigment dispersants and emulsion stabilizers, Prog. Org. Coat., 27, 255, 10.1016/0300-9440(95)00541-2 Wu, 1991, An experimental-study on the effect of adsorbing and nonadsorbing block sizes on diblock copolymer adsorption, Polym. J., 23, 709, 10.1295/polymj.23.709 Matyjaszewski, 2012, Atom transfer radical polymerization (atrp): current status and future perspectives, Macromolecules, 45, 4015, 10.1021/ma3001719 Boyer, 2016, Copper-mediated living radical polymerization (atom transfer radical polymerization and copper(0) mediated polymerization): from fundamentals to bioapplications, Chem. Rev., 116, 1803, 10.1021/acs.chemrev.5b00396 di Lena, 2010, Transition metal catalysts for controlled radical polymerization, Prog. Polym. Sci., 35, 959, 10.1016/j.progpolymsci.2010.05.001 Pintauer, 2008, Atom transfer radical addition and polymerization reactions catalyzed by ppm amounts of copper complexes, Chem. Soc. Rev., 37, 1087, 10.1039/b714578k Siegwart, 2012, Atrp in the design of functional materials for biomedical applications, Prog. Polym. Sci., 37, 18, 10.1016/j.progpolymsci.2011.08.001 Tsarevsky, 2007, Electron transfer reactions relevant to atom transfer radical polymerization, J. Organomet. Chem., 692, 3212, 10.1016/j.jorganchem.2007.01.051 Tsarevsky, 2007, "Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials, Chem. Rev., 107, 2270, 10.1021/cr050947p Wang, 1995, Controlled living radical polymerization - atom-transfer radical polymerization in the presence of transition-metal complexes, J. Am. Chem. Soc., 117, 5614, 10.1021/ja00125a035 Matyjaszewski, 2001, Atom transfer radical polymerization, Chem. Rev., 101, 2921, 10.1021/cr940534g Konkolewicz, 2012, Icar atrp with ppm cu catalyst in water, Macromolecules, 45, 4461, 10.1021/ma300887r Simakova, 2012, Aqueous arget atrp, Macromolecules, 45, 6371, 10.1021/ma301303b Konkolewicz, 2014, Aqueous rdrp in the presence of cu-0: the exceptional activity of cu-i confirms the sara atrp mechanism, Macromolecules, 47, 560, 10.1021/ma4022983 Magenau, 2011, Electrochemically mediated atom transfer radical polymerization, Science, 332, 81, 10.1126/science.1202357 Park, 2015, Simplified electrochemically mediated atom transfer radical polymerization using a sacrificial anode, Angew. Chem. Int. Edit., 54, 2388, 10.1002/anie.201410598 Mosnacek, 2012, Photochemically mediated atom transfer radical polymerization of methyl methacrylate using ppm amounts of catalyst, Macromolecules, 45, 5859, 10.1021/ma300773t Pan, 2016, Mechanism of photoinduced metal-free atom transfer radical polymerization: experimental and computational studies, J. Am. Chem. Soc., 138, 2411, 10.1021/jacs.5b13455 Pan, 2015, Photoinduced atom transfer radical polymerization with ppm-level cu catalyst by visible light in aqueous media, J. Am. Chem. Soc., 137, 15430, 10.1021/jacs.5b11599 Britovsek, 2005, Non-heme lron(ii) complexes containing tripodal tetradentate nitrogen ligands and their application in alkane oxidation catalysis, Inorg. Chem., 44, 8125, 10.1021/ic0509229 Wang, 2019, In situ crosslinking of nanoparticles in polymerization-induced self-assembly via arget atrp of glycidyl methacrylate, Macromol. Rapid Commun., 40, 10.1002/marc.201800332 Silber, 2002, New concepts for the synthesis of wetting and dispersing additives for water-based systems, Prog. Org. Coat., 45, 259, 10.1016/S0300-9440(02)00064-4 Tsarevsky, 2011, Atom transfer radical polymerization of functional monomers employing cu-based catalysts at low concentration: polymerization of glycidyl methacrylate, J. Polym. Sci. Pol. Chem., 49, 918, 10.1002/pola.24503 Wang, 2017, Polymerization-induced self-assembly of acrylonitrile via icar atrp, Polymer, 129, 57, 10.1016/j.polymer.2017.09.029 Shi, 2019, Development of icar atrp-based polymerization-induced self-assembly and its application in the preparation of organic-inorganic nanoparticles, Macromol. Rapid Commun., 40, 10.1002/marc.201900547 Wang, 2017, Synthesis, characterization and the paramagnetic properties of bottle-brush copolymers with shielding tempo radicals, Polym. Chem., 8, 7044, 10.1039/C7PY01683B Gadwal, 2015, Homopolymer bifunctionalization through sequential thiol-epoxy and esterification reactions: an optimization, quantification, and structural elucidation study, Polym. Chem., 6, 1393, 10.1039/C4PY01453G