Novel concept for the preparation of gas selective nanocomposite membranes

The European Physical Journal Special Topics - Tập 224 - Trang 1921-1933 - 2015
M. Drobek1, A. Ayral1, J. Motuzas1, C. Charmette1, C. Loubat2, E. Louradour3, D. Dhaler3, A. Julbe1
1Institut Européen des Membranes, ENSCM-UM2-CNRS UMR5635, Université de Montpellier, Montpellier Cedex 5, France
2Specific Polymers, ZAC Via Domitia, Castries, France
3Céramiques Techniques et Industrielles, Salindres, France

Tóm tắt

In this work we report on a novel concept for the preparation of gas selective composite membranes by a simple and robust synthesis protocol involving a controlled in-situpolycondensation of functional alkoxysilanes within the pores of a mesoporous ceramic matrix. This innovative approach targets the manufacture of thin nanocomposite membranes, allowing good compromise between permeability, selectivity and thermomechanical strength. Compared to simple infiltration, the synthesis protocol allows a controlled formation of gas separation membranes from size-adjusted functional alkoxysilanes by a chemical reaction within the mesopores of a ceramic support, without any formation of a thick and continuous layer on the support top-surface. Membrane permeability can thus be effectively controlled by the thickness and pore size of the mesoporous layer, and by the oligomers chain length. The as-prepared composite membranes are expected to possess a good mechanical and thermomechanical resistance and exhibit a thermally activated transport of He and H2 up to 150 °C, resulting in enhanced separation factors for specific gas mixtures e.g. FH2/CO ∼ 10; FH2/CO2 ∼ 3; FH2/CH4 ∼ 62.

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