Các Hạt Nano Kim Loại Quý và Kim Loại Cơ Bản Gắn Trên Các Oxit Kim Loại Mesoporous: Chất Xúc Tác Hiệu Quả Trong Phản Ứng Hydro Hóa Chọn Lọc Axit Levulinic Thành γ-Valerolactone

Catalysis Letters - Tập 149 - Trang 2807-2822 - 2019
Matumuene Joe Ndolomingo1, Reinout Meijboom1
1Department of Chemistry, University of Johannesburg, Auckland Park, South Africa

Tóm tắt

Nghiên cứu về phản ứng hydro hóa chọn lọc axit levulinic (LA) thành γ-valerolactone (GVL) trong hệ thống nước và không dung môi sử dụng các oxit kim loại TiO2, NiO và MnO2 gắn trên các hạt nano kim loại quý và kim loại cơ bản đã được tiến hành. Kết quả BET cho thấy tất cả các vật liệu tổng hợp đều là mesoporous với các isotherm loại IV và hiện tượng hồi tiếp loại I. Các đỉnh p-XRD quan sát được ở vùng góc thấp xác nhận sự hình thành thành công của các vật liệu có cấu trúc meso, trong khi các mẫu nhiễu xạ góc rộng cho thấy cấu trúc tinh thể của các hạt nano tinh khiết được duy trì khi có sự lắng đọng của kim loại. Kết quả TPR cho thấy các hạt xúc tác nano đã được hỗ trợ có chứa Ru, Pd, Cu và Cr kim loại ở dạng kim loại và kích thước hạt trung bình thu được từ HRTEM dao động từ 2 đến 6 nm. Các hạt nano đã tổng hợp cho thấy hiệu quả cao trong việc chuyển đổi LA thành GVL. Hiệu suất tốt nhất với mức chuyển đổi hoàn toàn LA và độ chọn lọc GVL > 95% được đạt được từ các hạt nano dựa trên TiO2 và MnO2 khi nước được sử dụng làm dung môi. Thứ tự hoạt tính của các hạt nano kim loại hỗ trợ được xác định như sau: Pd ≈ Ru > Cu > Cr. Với hoạt tính TOF lên đến 277273 h−1/mol, các hạt nano dựa trên đồng có chi phí thấp có thể là một lựa chọn thay thế cho các chất xúc tác kim loại quý có chi phí cao.

Từ khóa

#Axit Levulinic #γ-Valerolactone #Hydro hóa #Hạt nano #Oxit kim loại #Chất xúc tác

Tài liệu tham khảo

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