Nickel Flower/Conducting Polymer Composite for Effective Ethanol Electrooxidation in Alkaline Medium

S. Kanwal, M.T. Mehran, M. Hassan, M. Anwar, S.R. Naqvi, A.H. Khoja, An integrated future approach for the energy security of Pakistan: Replacement of fossil fuels with syngas for better environment and socio-economic development. Renew. Sustain. Energy Rev. 156, 111978 (2022)

A. Bhide, C.R. Monroy, Energy poverty: A special focus on energy poverty in India and renewable energy technologies. Renew. Sustain. Energy Rev. 15, 1057–1066 (2011)

N. Johnstone, I. Haščič, D. Popp, Renewable energy policies and technological innovation: evidence based on patent counts. Environ. Resour. Econ. 45, 133–155 (2010)

N.S. Al-Kadhi, M.A. Hefnawy, S. S. Nafee, F.S. Alamro, R.A. Pashameah, H.A. Ahmed, S.S. Medany, Zinc nanocomposite supported chitosan for nitrite sensing and hydrogen evolution applications. Polymers (Basel). 15, (2023). https://doi.org/10.3390/polym15102357

M. Höök, X. Tang, Depletion of fossil fuels and anthropogenic climate change—A review. Energy Policy 52, 797–809 (2013)

M. Ni, D.Y.C. Leung, M.K.H. Leung, A review on reforming bio-ethanol for hydrogen production. Int. J. Hydrogen Energy 32, 3238–3247 (2007)

R.M. Dell, D.A.J. Rand, Energy storage—a key technology for global energy sustainability. J. Power. Sources 100, 2–17 (2001)

S.R. Bull, Renewable energy today and tomorrow. Proc. IEEE 89, 1216–1226 (2001)

D.B. Richardson, Electric vehicles and the electric grid: A review of modeling approaches, Impacts, and renewable energy integration. Renew. Sustain. Energy Rev. 19, 247–254 (2013)

A.E. Farrell, R.J. Plevin, B.T. Turner, A.D. Jones, M. O’hare, D.M. Kammen, Ethanol can contribute to energy and environmental goals. Science (80-. ) 311, 506–508 (2006)

S.C.S. Lai, M.T.M. Koper, Ethanol electro-oxidation on platinum in alkaline media. Phys. Chem. Chem. Phys. 11, 10446–10456 (2009)

S.T. Nguyen, H.M. Law, H.T. Nguyen, N. Kristian, S. Wang, S.H. Chan, X. Wang, Enhancement effect of Ag for Pd/C towards the ethanol electro-oxidation in alkaline media. Appl. Catal. B Environ. 91, 507–515 (2009)

S. Baruah, A. Kumar, N.R. Peela, The promotional effect of Ag in activated carbon supported Pt-Ag nanoalloy electrocatalyst towards alkaline ethanol oxidation reaction: A kinetic study. J. Electroanal. Chem. 953, 118015 (2024)

N. Tanwar, H. Narjinari, H. Sharma, S. Dhole, R.V. Jasra, A. Kumar, Electrocatalytic oxidation of methanol and ethanol with 3d-metal based anodic electrocatalysts in alkaline media using carbon based electrode assembly. Inorg. Chem. (2024)

H.M. Song, D.H. Anjum, R. Sougrat, M.N. Hedhili, N.M. Khashab, Hollow Au@ Pd and Au@ Pt core–shell nanoparticles as electrocatalysts for ethanol oxidation reactions. J. Mater. Chem. 22, 25003–25010 (2012)

Z.-P. Wu, D.T. Caracciolo, Y. Maswadeh, J. Wen, Z. Kong, S. Shan, J.A. Vargas, S. Yan, E. Hopkins, K. Park, Alloying–realloying enabled high durability for Pt–Pd-3d-transition metal nanoparticle fuel cell catalysts. Nat. Commun. 12, 859 (2021)

X. Cui, W. Li, P. Ryabchuk, K. Junge, M. Beller, Bridging homogeneous and heterogeneous catalysis by heterogeneous single-metal-site catalysts. Nat. Catal. 1, 385–397 (2018)

J. Guo, C. Lin, C. Jiang, P. Zhang, Review on noble metal-based catalysts for formaldehyde oxidation at room temperature. Appl. Surf. Sci. 475, 237–255 (2019)

S. Sen Gupta, J. Datta, A comparative study on ethanol oxidation behavior at Pt and PtRh electrodeposits. J. Electroanal. Chem. 594, 65–72 (2006)

I.E. Wachs, R.J. Madix, The oxidation of ethanol on Cu (110) and Ag (110) catalysts. Appl. Surf. Sci. 1, 303–328 (1978)

Z. Zhang, L. Xin, K. Sun, W. Li, Pd–Ni electrocatalysts for efficient ethanol oxidation reaction in alkaline electrolyte. Int. J. Hydrogen Energy 36, 12686–12697 (2011)

M.A. Hefnawy, S.A. Fadlallah, R.M. El-Sherif, S.S. Medany, Synergistic effect of Cu-doped NiO for enhancing urea electrooxidation: Comparative electrochemical and DFT studies. J. Alloys Compd. 896, 162857 (2022). https://doi.org/10.1016/j.jallcom.2021.162857

F.S. Alamro, M.A. Hefnawy, S.S. Nafee, N.S. Al-Kadhi, R.A. Pashameah, H.A. Ahmed, S.S. Medany, Chitosan supports boosting NiCo2O4 for catalyzed urea electrochemical removal application. Polymers (Basel). 15, (2023). https://doi.org/10.3390/polym15143058

M.A. Hefnawy, A. Nafady, S.K. Mohamed, S.S. Medany, Facile green synthesis of Ag/carbon nanotubes composite for efficient water splitting applications. Synth. Met. 294, 117310 (2023). https://doi.org/10.1016/j.synthmet.2023.117310

J. Wu, Q. Liang, X. Yu, Q. Lü, L. Ma, X. Qin, G. Chen, B. Li, Deep eutectic solvents for boosting electrochemical energy storage and conversion: a review and perspective. Adv. Funct. Mater. 31, 2011102 (2021)

Y. Guo, J. Hu, L. Wan, Nanostructured materials for electrochemical energy conversion and storage devices. Adv. Mater. 20, 2878–2887 (2008)

M.A. Shenashen, D. Hassen, S.A. El-Safty, M.M. Selim, N. Akhtar, A. Chatterjee, A. Elmarakbi, Mesoscopic fabric sheet racks and blocks as catalysts with efficiently exposed surfaces for methanol and ethanol electrooxidation. Adv. Mater. Interfaces 3, 1600743 (2016)

N.S. Al-Kadhi, M.A. Hefnawy, F.S. Alamro, R.A. Pashameah, H.A. Ahmed, S.S. Medany, Polyaniline-supported nickel oxide flower for efficient nitrite electrochemical detection in water. Polymers (Basel). 15, (2023). https://doi.org/10.3390/polym15071804

M.A. Hefnawy, S.S. Medany, R.M. El-Sherif, S.A. Fadlallah, NiO-MnOx/Polyaniline/Graphite electrodes for urea Electrocatalysis: Synergetic effect between polymorphs of MnOx and NiO. ChemistrySelect 7, e202103735 (2022). https://doi.org/10.1002/slct.202103735

M.A. Hefnawy, S.S. Medany, R.M. El-Sherif, N. El-Bagoury, S.A. Fadlallah, High-performance IN738 superalloy derived from turbine blade waste for efficient ethanol, ethylene glycol, and urea electrooxidation. J. Appl. Electrochem. (2023). https://doi.org/10.1007/s10800-023-01862-7

N.F. Atta, R.M.A. El-Sherif, H.K. Hassan, M.A. Hefnawy, A. Galal, Conducting polymer-mixed oxide composite electrocatalyst for enhanced urea oxidation. J. Electrochem. Soc. 165, J3310–J3317 (2018). https://doi.org/10.1149/2.0421815jes

H. Gamal, A.M. Elshahawy, S.S. Medany, M.A. Hefnawy, M.S. Shalaby, Recent advances of vanadium oxides and their derivatives in supercapacitor applications: A comprehensive review. J. Energy Storage. 76, 109788 (2024). https://doi.org/10.1016/j.est.2023.109788

Z. Yan, X. Yu, A. Han, P. Xu, P. Du, Noble-metal-free Ni (OH) 2-modified CdS/reduced graphene oxide nanocomposite with enhanced photocatalytic activity for hydrogen production under visible light irradiation. J. Phys. Chem. C 118, 22896–22903 (2014)

P. Tan, B. Chen, H. Xu, W. Cai, M. Liu, Z. Shao, M. Ni, Nanoporous NiO/Ni (OH) 2 plates incorporated with carbon nanotubes as active materials of rechargeable hybrid zinc batteries for improved energy efficiency and high-rate capability. J. Electrochem. Soc. 165, A2119 (2018)

C. Wen, X. Zheng, X. Li, M. Yuan, H. Li, G. Sun, Rational design of 3D hierarchical MXene@ AlF3/Ni (OH) 2 nanohybrid for high-performance lithium-sulfur batteries. Chem. Eng. J. 409, 128102 (2021)

M.A. Mahadik, P.S. Shinde, H.H. Lee, M. Cho, J.S. Jang, Highly efficient and stable 3D Ni (OH) 2/CdS/ZnIn2S4/TiO2 heterojunction under solar light: effect of an improved TiO2/FTO interface and cocatalyst. Sol. Energy Mater. Sol. Cells 159, 475–487 (2017)

R. Shen, W. Liu, D. Ren, J. Xie, X. Li, Co1. 4Ni0. 6P cocatalysts modified metallic carbon black/g-C3N4 nanosheet Schottky heterojunctions for active and durable photocatalytic H2 production. Appl. Surf. Sci. 466, 393–400 (2019)

H. Zhang, B. Xu, Z. Xiao, H. Mei, L. Zhang, Y. Han, D. Sun, Optimizing crystallinity and porosity of hierarchical Ni (OH) 2 through conformal transformation of metal–organic framework template for supercapacitor applications. CrystEngComm 20, 4313–4320 (2018)

L. Marchetti, F. Miserque, S. Perrin, M. Pijolat, XPS study of Ni-base alloys oxide films formed in primary conditions of pressurized water reactor. Surf. Interface Anal. 47, 632–642 (2015)

Y. Li, Q. Li, S. Zhao, C. Chen, J. Zhou, K. Tao, L. Han, Conductive 2D metal-organic frameworks decorated on layered double hydroxides nanoflower surface for high-performance supercapacitor. ChemistrySelect 3, 13596–13602 (2018)

C. Zhao, Y. Zhou, T. Shi, D. Guo, H. Yin, C. Song, L. Qin, Z. Wang, H. Shao, K. Yu, Employing synergetic effect of ZnSe quantum dots and layered Ni (OH) 2 to boost the performance of lithium–sulfur cathodes. Nanotechnology 32, 505406 (2021)

C. Han, Q. Liu, D.G. Ivey, Kinetics of Sn electrodeposition from Sn (II)–citrate solutions. Electrochim. Acta 53, 8332–8340 (2008)

W. Zhang, R. Cheng, Z. Wang, Y. Ma, S. Ran, Y. Lv, L. Ma, A composite-hydroxide-activation strategy for the preparation of N/S dual-doped porous carbon materials as advanced supercapacitor electrodes. J. Mater. Sci. Mater. Electron. 31, 22498–22511 (2020)

N. Karthik, T. Tian, T.N.J.I. Edison, R. Atchudan, Y.R. Lee, S. Kim, D. Xiong, Pulsed laser rusted stainless steel: a robust electrode material applied for energy storage and generation applications, Sustain. Energy Fuels 4, 1242–1253 (2020)

F.B. Li, X.Z. Li, M.F. Hou, Photocatalytic degradation of 2-mercaptobenzothiazole in aqueous La3+–TiO2 suspension for odor control. Appl. Catal. B Environ. 48, 185–194 (2004)

L. Hou, Q. Liang, F. Wang, Mechanisms that control the adsorption–desorption behavior of phosphate on magnetite nanoparticles: the role of particle size and surface chemistry characteristics. RSC Adv. 10, 2378–2388 (2020). https://doi.org/10.1039/C9RA08517C

N. Joshi, L.F. da Silva, F.M. Shimizu, V.R. Mastelaro, J.-C. M’Peko, L. Lin, O.N. Oliveira, UV-assisted chemiresistors made with gold-modified ZnO nanorods to detect ozone gas at room temperature. Microchim. Acta 186, 418 (2019). https://doi.org/10.1007/s00604-019-3532-4

O.C. Altıncı, B.K. Körbahti, Graphene oxide-polyaniline conducting composite film deposited on platinum-iridium electrode by electrochemical polymerization of aniline: Synthesis and environmental electrochemistry application. Appl. Surf. Sci. Adv. 7, 100212 (2022). https://doi.org/10.1016/j.apsadv.2022.100212

C. Han, J. Zhu, K. Fu, D. Deng, W. Luo, L. Mai, A high-capacity polyaniline-intercalated layered vanadium oxide for aqueous ammonium-ion batteries. Chem. Commun. (2022)

H. Gholami, A. Shakeri, V. Saadattalab, Investigation of physical and mechanical properties of polyaniline/MMT nanocomposites. Curr. Chem. Lett. 6, 151–158 (2017)

M.A. Gabris, S. Rezania, M. Rafieizonooz, E. Khankhaje, S. Devanesan, M.S. AlSalhi, M.J. Aljaafreh, A. Shadravan, Chitosan magnetic graphene grafted polyaniline doped with cobalt oxide for removal of Arsenic(V) from water. Environ. Res. 207, 112209 (2022). https://doi.org/10.1016/j.envres.2021.112209

S.S. Medany, M.A. Hefnawy, Nickel–cobalt oxide decorated Chitosan electrocatalyst for ethylene glycol oxidation. Surf. Interfaces. 103077 (2023). https://doi.org/10.1016/j.surfin.2023.103077

H.N. Dinh, P. Vanýsek, V.I. Birss, The effect of film thickness and growth method on polyaniline film properties. J. Electrochem. Soc. 146, 3324–3334 (1999)

A.S. Eliwa, M.A. Hefnawy, S.S. Medany, R.G. Deghadi, W.M. Hosny, G.G. Mohamed, Ultrasonic-assisted synthesis of nickel metal-organic framework for efficient urea removal and water splitting applications. Synth. Met. 294, 117309 (2023). https://doi.org/10.1016/j.synthmet.2023.117309

M.A. Hefnawy, S.A. Fadlallah, R.M. El-Sherif, S.S. Medany, Competition between enzymatic and non-enzymatic electrochemical determination of cholesterol. J. Electroanal. Chem. 930, 117169 (2023). https://doi.org/10.1016/j.jelechem.2023.117169

M.A. Hefnawy, S.A. Fadlallah, R.M. El-Sherif, S.S. Medany, Systematic DFT studies of CO-Tolerance and CO oxidation on Cu-doped Ni surfaces. J. Mol. Graph. Model. 118, 108343 (2023). https://doi.org/10.1016/j.jmgm.2022.108343

M.A. Hefnawy, S.S. Medany, R.M. El-Sherif, S.A. Fadlallah, Green synthesis of NiO/Fe3O4@chitosan composite catalyst based on graphite for urea electro-oxidation. Mater. Chem. Phys. 290, 126603 (2022). https://doi.org/10.1016/j.matchemphys.2022.126603