Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming

Walter de Gruyter GmbH - Tập 14 Số 1 - Trang 363-376 - 2016

Vladіslav Sadykov^1,2, Mikhail Simonov^1,2, Natalia Mezentseva^1,2, Svetlana Pavlova², Yulia E. Fedorova², A. Bobin^1,2, Yulia Bespalko², А. В. Ищенко^1,2, Tamara Krieger^1,2, Tatiana S. Glazneva^1,2, Т. В. Ларина^1,2, Svetlana V. Cherepanova², В. В. Каичев², Аndrey А. Saraev², Yu. A. Chesalov², А. Н. Шмаков^1,2, Anne‐Cécile Roger³, Andrzej Adamski⁴

¹1Boreskov Institute of catalysis, Novosibirsk, 630090, Russia

²2Novosibirsk State University, Novosibirsk, 630090, Russia

³3University of Strasbourg, Strasbourg, F-67087, France

⁴4Jagiellonian University, Krakow, Poland

Tóm tắt

AbstractMixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.

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