New complexes of 3,4-dimethoxyphenylacetic acid with selected transition metal ions: Spectral, thermal, and magnetic properties

Russian Journal of General Chemistry - Tập 87 - Trang 2045-2055 - 2017
W. Ferenc1, D. Osypiuk1, B. Cristóvão1, J. Sarzyński2, H. Głuchowska1
1Faculty of Chemistry, Maria Curie-Skłodowska University, Lublin, Poland
2Institute of Physics, Maria Curie-Skłodowska University, Lublin, Poland

Tóm tắt

3,4-Dimethoxyphenylacetates of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) of general formula M(C10H11O4)2·nH2O, where n = 1, 2 or 4 depending on M(II) ions, are obtained. The complexes crystallize in monoclinic or triclinic systems. The carboxylate groups act as bidentate chelating or bridging ligands. On heating in the air (293–1173 K) they decompose in three steps finally forming oxides of the corresponding metals(II) or their mixtures. Magnetic moments of compounds were determined in the ranges of 76–303 and 4–300 K.

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