New bimetallic Mo2C–WC/Al2O3 membrane catalysts in the dry reforming of methane

Kinetics and Catalysis - Tập 58 - Trang 73-80 - 2017
V. R. Kislov1, V. V. Skudin1, A. Adamu1
1Mendeleev University of Chemical Technology, Moscow, Russia

Tóm tắt

Bimetallic membrane catalysts based on the Mo2C–WC binary carbides were obtained. Their structural characteristics and catalytic properties in a reaction of dry reforming of methane were compared with those of monocarbide catalysts. The advantage of the use of the mixed carbide catalysts was established.

Tài liệu tham khảo

Van der Oosterkamp, P., Vagner, E., and Ros. D., Ross. Khim. Zh., 2000, vol. 44, p. 34. Bukharkina, T.V., Gavrilova, N.N., and Skudin, V.V., Catal. Ind., 2015, vol. 7, no. 4, p. 253. Westerman., Th. and Melin, Th., Chem. Eng. Process. Process Intensif., 2009, vol. 48, no. 1, p. 17. Membrane Reactors for Energy: Applications and Basic Chemical Production, Basile, A., Di Paola, L., Hai, F., and Piemonte, V., Eds., Cambridge, UK: Woodhead, 2015. Darujati, A.R.S. https://www.research.wsulibs.wsu.edu: 8443/xmlui/handle/2376/342. Zhang Shaohua, Zhang Anjie, Zhang Yali, Au Chaktong, and Shi Chuan, 8th Int. Conf. on Environmental Catalysis, 2014, Asheville, USA. http://www.icec2014. us/pdf/GC-O-22.pdf. Brungs, A.J., York, A.P.E., Claridge, J.B., Márquez-Alvarez, C., and Green, M.L.H., Catal. Lett., 2000, vol. 70, p. 117. Shao Huifang. Kugler Edwin, L., Ma Wenping, and Dadyburjor Dady, B., Ind. Eng. Chem. Res., 2005, vol. 44, no. 14, p. 4914. Zhang, A., Zhu, A., Chen, B., Zhang, S., Au, C., and Shi, C., Catal. Commun., 2011, vol. 12, p. 803. Skudin, V.V., Shamkina, N.A., and Shul’min, D.A., Khim. Prom–st. Segodnya, 2011, no. 9, p. 6. Claridge, J.B., York, A.P.E., Brungs, A.J., Marquez-Alvarez, C., and Sloan, J., J. Catal., 1998, vol. 180, p. 85. Kryzhanovskii, A.S., Cand. Sci. (Chem.) Dissertation, Moscow: Dmitry Mendeleev Univ. of Chemical Technology of Russia, 2013. Hunt, S.T., Nimmanwudipong, T., and Roman-Leshkov, Y., Angew. Chem., Int. Ed. Engl., 2014, vol. 53, p. 1. Ge, X., Wang, H., Liu, Z., Fisher, A., and Wang, X., Adv. Funct. Mater., 2015, vol. 25, p. 1520. Claridge, J.B., York, A.P.E., Brungs, A.J., and Marquez-Alvarez, C., J. Catal., 1998, vol. 180, p. 85. Du, X., France, L.J., Kuznetsov, V.L., Xiao, T., Edwards, P.P., and Al Megren, H., Appl. Petrochem. Res., 2014, no. 4, p. 137.