New Limonoids from the Seeds of a Krishna Mangrove, Xylocarpus granatum

Wiley - Tập 10 Số 4 - Trang 612-620 - 2013
Hongliang Chen1,2, Jing Zhang1,3,4,5,2, Min‐Yi Li6,5, Tirumani Satyanandamurty7, Jun Wu3,4,6,5,2
1College of Chinese Medicinal Materials, Jilin Agricultural University, Changchun 130118, P. R. China, (phone: +86-431-84533087-8011
2fax: +86-431-84533086)
3Jing Zhang, College of Chinese Medicinal Materials, Jilin Agricultural University, Changchun 130118, P. R. China, (phone: +86-431-84533087-8011
4Jun Wu, Key Laboratory of Marine Bio-resources Sustainable Utilization, South China Sea Institute of Oceanology, Chinese Academy of Sciences, 164 West Xingang Road, Guangzhou 510301, P. R. China, (phone: +86-20-84458442
5fax: +86-20-84451672)
6Key Laboratory of Marine Bio-resources Sustainable Utilization, South China Sea Institute of Oceanology, Chinese Academy of Sciences, 164 West Xingang Road, Guangzhou 510301, P. R. China, (phone: +86-20-84458442
7Government Degree College at Amadala valasa, Srikakulam District, Andhra Pradesh 532185, India

Tóm tắt

AbstractTwo new mexicanolides, named granatumins H and I (1 and 2, resp.), and two phragmalins, named granatumins J and K (3 and 4, resp.), were isolated from the seeds of an Indian mangrove, Xylocarpus moluccensis, collected from the swamps of Krishna estuary, Andhra Pradesh. The structures of these limonoids were established on the basis of spectroscopic data. Granatumin J (3) is a highly oxidized phragmalin with five AcO groups, whereas granatumin K (4) is the first phragmalin found in nature with conjugated C(8)C(30) and C(14)C(15) bonds.

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