Vật liệu composite ba thành phần NiCo2O4@NiMnCo-LDH thay thế Fe có cấu trúc nano làm vật liệu điện cực cho siêu tụ điện hiệu suất cao

Ayla Sajid1, Javearia Tariq1, Faiq Ahmad1, Mutawara Mahmood Baig1, Iftikhar Hussain Gul1, Uzma Habib2
1Electronic and Magnetic Materials Laboratory, Department of Materials Engineering, School of Chemical and Materials Engineering (SCME), National University of Sciences and Technology (NUST), Islamabad, Pakistan
2Computational Science and Engineering Laboratory, School of Interdisciplinary Engineering and Sciences (SINES), National University of Sciences and Technology (NUST), Islamabad, Pakistan

Tóm tắt

Một thách thức thiết yếu đối với các vật liệu điện cực kiểu giả tụ điện là khả năng lưu trữ điện tích không đủ với điện trở nội tại cao và sự không ổn định của cấu trúc. Với sự gia tăng theo cấp số nhân trong nhu cầu về một môi trường không ô nhiễm, các hợp chất kim loại ba thành phần đang được khám phá rất nhiều như một giải pháp hấp dẫn cho những vấn đề này. Tại đây, chúng tôi đã giải quyết các vấn đề được liệt kê ở trên bằng cách tổng hợp các lớp hydroxide kép NiMnCo (NiMnCo-LDH) mới và không sử dụng chất kết dính, dưới dạng các tấm nano trên nanorod NiCo2O4 thay thế Fe (FexNi1−xCo2O4) được hỗ trợ bởi bọt nickel thông qua phương pháp thủy nhiệt đơn giản, tiếp theo là tráng hóa học. Cấu trúc nanorod NiCo2O4 thay thế Fe định hình cao và phân bố tốt kết hợp với các tấm nano NiMnCo-LDH cung cấp động lực học truyền tải điện tích cực nhanh, tăng khả năng lưu trữ điện tích và độ ổn định cấu trúc cao. Điện cực composite này cung cấp dung lượng riêng cao 281 mAh/g tại tốc độ quét 5 mV/s (265 mAh/g tại 1 A/g) với khả năng giữ điện dung 92% sau 5000 chu kỳ ở 2 A/g. Tác động của Fe trong NiCo2O4 được xác nhận thêm bằng cách thực hiện các phép tính lý thuyết mật độ chức năng (DFT) để có được những hiểu biết về điện dẫn thông qua mật độ trạng thái (DOS) và cấu trúc vùng. Cuối cùng, một siêu tụ điện đối xứng dựa trên FexNi1−xCo2O4@NiMnCo-LDH đã được lắp ráp, mang lại mật độ năng lượng ấn tượng là 105 Wh/kg và mật độ công suất 1112 W/kg, chứng minh FexNi1−xCo2O4@NiMnCo-LDH là vật liệu điện cực dùng cho các ứng dụng lưu trữ năng lượng.

Từ khóa

#vật liệu điện cực #siêu tụ điện #hydroxide kép #NiMnCo #NiCo2O4 #mật độ năng lượng #mật độ công suất #lý thuyết mật độ chức năng

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