Multi-jet electrospinning of polystyrene/polyamide 6 blend: thermal and mechanical properties

Fashion and Textiles - Tập 4 Số 1
Jae Won Yoon1, Yaewon Park2, Jooyoun Kim3, Chung Hee Park1
1Department of Textiles, Merchandising and Fashion Design, Seoul National University, Seoul, Republic of Korea
2Department of Textile Engineering, Chemistry and Science, North Carolina State University, Raleigh, USA
3Department of Apparel, Textiles, and Interior Design, Kansas State University, Manhattan, USA

Tóm tắt

AbstractPolystyrene (PS) has high thermal resistance thus can be applied as thermally comfortable textile. However, the application is limited due its low mechanical strength. In this study, polyamide 6 (PA6) was blended with PS to improve the mechanical strength of PS, by means of a multi-jet electrospinning. Content ratio of the blend web was measured by chemical immersion test and confocal microscopy analysis. Fiber content was in accordance with the number of syringes used for PS and PA6 respectively. The effects of content ratio on the web morphology, thermal resistance, tensile behavior, air and water vapor permeability, and surface hydrophilicity were investigated. The influence of environmental humidity during electrospinning process on three dimensional (3D) web structure was also reported. PS web produced from higher humidity had more pores and corrugations at the surface. The increased surface roughness and porosity led to the increased hydrophobicity and thermal resistance. Though the blending of PA6 with PS enhanced the mechanical strength, the added PA6 decreased air/water vapor permeability and thermal resistance. The lowered thermal resistance by the addition of PA6 was mainly attributed to higher thermal conductivity of PA6 material and lowered air content with PA6 fibers.

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Tài liệu tham khảo

Ahn, H. W., Park, C. H., & Chung, S. E. (2011). Waterproof and breathable properties of nanoweb applied clothing. Textile Research Journal, 81, 1438–1447.

Bonino, C. A., Efimenko, K., Jeong, S. I., Krebs, M. D., Alsberg, E., & Khan, S. A. (2012). Three-dimensional electrospun alginate nanofiber mats via tailored charge repulsions. Small (Weinheim an der Bergstrasse, Germany), 8, 1928–1936.

Carrizales, C., Pelfrey, S., Rincon, R., Eubanks, T. M., Kuang, A., McClure, M. J., et al. (2008). Thermal and mechanical properties of electrospun PMMA, PVC, Nylon 6, and Nylon 6,6. Polymers for Advanced Technology, 19, 124–130.

Casper, C. L., Stephens, J. S., Tassi, N. G., Chase, D. B., & Rabolt, J. F. (2004). Controlling surface morphology of electrospun polystyrene fibers: Effect of humidity and molecular weight in the electrospinning process. Macromolecules, 37, 573–578.

Cengiz, F., Dao, T. A., & Jirsak, O. (2010). Influence of solution properties on the roller electrospinning of poly(vinyl alcohol). Polymer Engineering & Science, 50, 936–943.

Ding, B., Kimura, E., Sato, T., Fujita, S., & Shiratori, S. (2004). Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning. Polymer, 45, 1895–1902.

Fashandi, H., & Karimi, M. (2012). Pore formation in polystyrene fiber by superimposing temperature and relative humidity of electrospinning atmosphere. Polymer, 53, 5832–5849.

Gibson, P. (1993). Influencing steady-state heat and water vapor transfer measurements for clothing materials hot plate and upright cup methods of. Textile Research Journal, 63, 749–764.

Gotoh, K. (2004). Wettability and surface free energies of polymeric materials exposed to excimer ultraviolet light and particle deposition onto their surfaces in water. In K. Mittal (Ed.), Polymer surface modification: relevance to adhesion (pp. 125–139). Utrecht: VSP.

Greiner, A., & Wendorff, J. H. (2007). Electrospinning: A fascinating method for the preparation of ultrathin fibers. Angewante Chemie-International Edition, 46, 5670–5703.

Han, Z., & Fina, A. (2011). Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review. Progress in Polymer Science, 36, 914–944.

Harris, M., Appel, G., & Ade, H. (2003). Surface morphology of annealed polystyrene and poly(methyl methacrylate) thin film blends and bilayers. Macromolecules, 36, 3307–3314.

Hu, C., Kiene, M., & Ho, P. S. (2001). Thermal conductivity and interfacial thermal resistance of polymeric low k films. Applied Physical Letter, 79, 4121–4123.

Kim, K. S., & Park, C. H. (2013). Thermal comfort and waterproof-breathable performance of aluminum-coated polyurethane nanowebs. Textile Research Journal, 83, 1808–1820.

Li, D., & Xia, Y. (2004). Electrospinning of nanofibers: Reinventing the wheel? Advanced Materials, 16, 1151–1170.

Lin, J., Ding, B., Jianyong, Y., & Hsieh, Y. (2010). Direct fabrication of highly nanoporous polystyrene fibers via electrospinning. ACS Applied Materials & Interfaces, 2, 521–528.

Marsano, E., Francis, L., & Giunco, F. (2010). Polyamide 6 nanofibrous nonwovens via electrospinning. Journal of Applied Polymer Science, 117, 1754–1765.

Miyauchi, Y., Ding, B., & Shiratori, S. (2006). Fabrication of a silver-ragwort-leaf-like super-hydrophobic micro/nanoporous fibrous mat surface by electrospinning. Nanotechnology, 17, 5151–5156.

Pai, C. L., Boyce, M. C., & Rutledge, G. C. (2009). Morphology of porous and wrinkled fibers of polystyrene electrospun from dimethylformamide. Macromolecules, 42, 2102–2114.

Park, C. H., Kim, C. H., Pant, H. R., Tijing, L. D., Yu, M. H., Kim, Y., et al. (2013). An angled robotic dual-nozzle electrospinning set-up for preparing PU/PA6 nanofiber composites. Textile Research Journal, 83, 311–320.

Park, D.-K., Park, S.-J., Baek, W.-I., Kanjwal, M. A., & Kim, H.-Y. (2011). Point-bonded electrospun polystyrene fibrous mats fabricated via the addition of poly(butylacrylate) adhesive. Polymer Engineering & Science, 51, 894–901.

Park, Y., Park, C. H., & Kim, J. (2014). A quantitative analysis on the surface roughness and the level of hydrophobicity for superhydrophobic ZnO nanorods grown textiles. Textile Research Journal, 84, 1776–1788.

Pham, Q. P., Sharma, U., & Mikos, A. G. (2006). Electrospinning of polymeric nanofibers for tissue engineering applications: A review. Tissue Engineering, 12, 1197–1211.

Reneker, D. H., & Chun, I. (1996). Nanometre diameter fibres of polymer, produced by electrospinning. Nanotechnology, 7, 216–223.

Sun, B., Long, Y.-Z., Yu, F., Li, M.-M., Zhang, H.-D., Li, W.-J., et al. (2012). Self-assembly of a three-dimensional fibrous polymer sponge by electrospinning. Nanoscale, 4, 2134–2137.

Teo, W. E., & Ramakrishna, S. (2006). A review on electrospinning design and nanofibre assemblies. Nanotechnology, 17, 89–106.

Wehner, J. A., Miller, B., & Rebenfeld, L. (1988). Dynamics of water vapor transmission through fabric barriers. Textile Research Journal, 58, 581–592.

Yener, F., & Jirsak, O. (2012). Comparison between the needle and roller electrospinning of polyvinylbutyral. Journal of Nanomaterials, 2012, 1–6.