Can Wu1,2, Dan Liú1, Hui Li1, Jinghong Li1
1Department of Chemistry, Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Tsinghua University, Beijing 100084, China
2Faculty of Materials Science & Engineering Hubei University Wuhan 430062 China
Tóm tắt
AbstractElectrocatalytic hydrogen evolution reaction (HER) based on water splitting holds great promise for clean energy technologies, in which the key issue is exploring cost‐effective materials to replace noble metal catalysts. Here, a sequential chemical etching and pyrolysis strategy are developed to prepare molybdenum carbide‐decorated metallic cobalt@nitrogen‐doped porous carbon polyhedrons (denoted as Mo/Co@N–C) hybrids for enhanced electrocatalytic hydrogen evolution. The obtained metallic Co nanoparticles are coated by N‐doped carbon thin layers while the formed molybdenum carbide nanoparticles are well‐dispersed in the whole Co@N–C frames. Benefiting from the additionally implanted molybdenum carbide active sites, the HER performance of Mo/Co@N–C hybrids is significantly promoted compared with the single Co@N–C that is derived from the pristine ZIF‐67 both in alkaline and acidic media. As a result, the as‐synthesized Mo/Co@N–C hybrids exhibit superior HER electrocatalytic activity, and only very low overpotentials of 157 and 187 mV are needed at 10 mA cm−2 in 1 m KOH and 0.5 m H2SO4, respectively, opening a door for rational design and fabrication of novel low‐cost electrocatalysts with hierarchical structures toward electrochemical energy storage and conversion.
