Modelling the degradation of acidic and alkaline printing paper
Tóm tắt
There has always been an interest in the professional communities of libraries, archives and conservation science to find ways of estimating the rate of degradation of paper under archival conservation conditions. Previously we reported a number of considerations for developing a kinetic degradation model based on Whatman no.1 paper. In the present research, this model was extended to 10 different papers and validated. Various physical and chemical properties of acidic, neutral, and alkaline papers were measured, such as the degree of polymerization (DP), tensile strength, equilibrium moisture content, and pH, as well as alkaline fillers content when applicable. The activation energy (Ea) based on DP of cellulose and zero-span tensile strength were determined. Ea and pH had the most significant influence on the simulated decay of paper. Papers with a high Ea (> 120 kJ mol−1), alkaline such as those containing at least 2% CaCO3, and acidic—but good printing quality papers made of bleached chemical pulp– were found the most durable in ambient conditions. Papers with a lower Ea (< 110 kJ mol−1) such as lignocellulosic papers containing significant amount of mechanical pulp were much less stable over time. Whatman filter papers, used as models of pure cellulosic papers, were found to have low Ea despite the good quality cotton fibers. A generic isoperm equation based on Ea was developed to predict the changes in the state of papers under various climatic conditions, and was applicable independently of the pH of the paper. The model developed allows a better quantification of the deterioration rate of printing papers such as those that are currently, and will be in the future, found in our archival collections.
Tài liệu tham khảo
Barański A, Dziembaj R, Konieczna-Mlenda A et al (2004) On the applicability of Arrhenius equation to accelerated tests. The case of alum-impregnated cellulose. Pol J Chem Technol 6:1–8
Barrow WJ (1974) Permanence/durability of the book-VII. Physical and chemical properties of book papers, 1507–1949. Barrow Research Lab, Richmond
Barrow WJ, Sproull RC (1959) Permanence in book papers. Science 129:1075–1084
Bégin P, Deschâtelets S, Grattan D, Gurnagul N, Iraci J, Kaminska E, Zou X (1998) The impact of lignin on paper permanence. Restaurator 19:135–154. https://doi.org/10.1515/rest.1998.19.3.135
Bigourdan J-L, Adelstein PZ, Reilly JM (1996) Acetic acid and paper alkaline reserve: assessment of a practical situation in film preservation. In: Bridgland J (ed) ICOM committee for conservation 11th Triennial meeting Edinburgh 1–6 september 1996. James & James, London, pp 573–579
Bogaard J, Whitmore PM (2002) Explorations of the role of humidity fluctuations in the deterioration of paper. Stud Conserv 47(Suppl 3):11–15. https://doi.org/10.1179/sic.2002.47.s3.003
Bown R (1996) Physical and chemical aspects of the use of fillers in paper. In: Roberts JC (ed) Paper chemistry. Springer, Dordrecht, pp 195–230. https://doi.org/10.1007/978-94-011-0605-4_11
Calvini P (2005) The influence of levelling-off degree of polymerisation on the kinetics of cellulose degradation. Cellulose 12:445–447. https://doi.org/10.1007/s10570-005-2206-z
Calvini P, Gorassini A, Merlani AL (2008) On the kinetics of cellulose degradation: looking beyond the pseudo zero order rate equation. Cellulose 15:193–203
Clapp VW (1972) The story of permanent/durable book paper, 1115–1970. Restaurator 1(s3):1–51. https://doi.org/10.1515/rest.1972.1.s3.1
Ding HZ, Wang ZD (2008) On the degradation evolution equations of cellulose. Cellulose 15:205–224. https://doi.org/10.1007/s10570-007-9166-4
Du Plooy ABJ (1981) The influence of moisture content and temperature on the aging rate of paper. Appita J 34:287–292
Dupont A-L, Réau D, Bégin P, Paris-Lacombe S, Tétreault J, Mortha G (2018) Accurate molar masses of cellulose for the determination of degradation rates in complex paper samples. Carbohydr Polym 202:172–185. https://doi.org/10.1016/j.carbpol.2018.08.134
Ekenstam AA (1936) Über das verhalten der cellulose in mineralsäure-lösungen, II. mitteil: Kinetisches studium des abbaus der cellulose in säure-lösungen. Ber Dtsch Chem Ges 69:549–552
Erhardt D (1989) Relationship of reaction rates to temperature. Abbey Newsl 13:38–39
Forchheim D, Hornung U, Kruse A (2014) Sutter T (2014) Kinetic modelling of hydrothermal lignin depolymerisation. Waste Biomass Valor 5:985–994. https://doi.org/10.1007/s12649-014-9307-6
Gray GG (1978) Determination and significance of activation energy in permanence tests. In: Williams JC (ed) Preservation of paper and textiles of historic and artistic value, Advances in Chemistry 164, pp 286–313
Hansen BV, Vest M (2008) Lifetime of acid paper in the collection of the Royal library. In: Strlič M and Kolar J Durability of paper and writing 2: 2nd international symposium and workshops, Ljubljana, Slovenia. Faculty of Chemistry and Chemical Technology, Ljubljana, pp 38–39
Hubbe MA, Smith RD, Zou X, Katuscak S, Potthast A, Ahn K (2017) Deacidification of acidic books and paper by means of non-aqueous dispersions of alkaline particles: a review focusing on completeness of the reaction. BioResources 12(2):4410–4477. https://doi.org/10.15376/biores.12.2.Hubbe
Jablonsky M, Šima J, Lelovsky M (2020) Considerations on factors influencing the degradation of cellulose in alum-rosin sized paper. Carbohyd Polym. https://doi.org/10.1016/j.carbpol.2020.116534
Jeong M-J, Potthast A (2021) Improving the accuracy of estimating paper permanence for accelerated degradation in closed vials. Cellulose 28:4053–4068. https://doi.org/10.1007/s10570-021-03804-y
Kaminska EM, Bégin P, Grattan DW et al (2001) ASTM/ISR research program on the effects of aging on printing and writing papers: accelerated aging test method development: final report. CCI report no.70664. Canadian Conservation Institute, Ottawa
Kuhn W (1930) Über die Kinetik des Abbaues hochmolekularer Ketten. Ber Dtsch Chem Ges 63:1503–1509
Liu Y, Cigić IK, Strlič M (2017) Kinetics of accelerated degradation of historic iron gall ink-containing paper. Polym Degrad Stab 142:255–262. https://doi.org/10.1016/j.polymdegradstab.2017.07.010
Menart E, De Bruin G, Strlič M (2011) Dose-response functions for historic paper. Polym Degrad Stab 96:2029–2039. https://doi.org/10.1016/j.polymdegradstab.2011.09.002
Mochizuki Y, Itsumura H, Enomae T (2020) Mechanism of acidification that progresses in library collections of books made of alkaline paper. Restaurator 41:153–172. https://doi.org/10.1515/res-2020-0008
Parker ME, Bronlund JE, Mawson AJ (2006) Moisture sorption isotherms for paper and paperboard in food chain conditions. Packag Technol Sci 19:193–209. https://doi.org/10.1002/pts.719
Parsa Sadr A, Bosco E, Suiker ASJ (2022) Multi-scale model for time-dependent degradation of historic paper artifacts. Int J Solids Struct. https://doi.org/10.1016/j.ijsolstr.2022.111609
Porck HJ (2000) Rate of paper degradation: the predictive value of artificial aging tests. European Commission on Preservation and Access, Amsterdam
Rouchon V, Belhadj O, Duranton M, Gimat A, Massiani P (2016) Application of Arrhenius law to DP and zero-span tensile strength measurements taken on iron gall ink impregnated papers: Relevance of artificial ageing protocols. Appl Phys A. https://doi.org/10.1007/s00339-016-0307-1
Sebera DK (1994) Isoperms: an environmental management tool. https://cool.culturalheritage.org/byauth/sebera/isoperm/ Accessed 11 Apr 2023
Shahani CJ, Hengemihle FH, Weberg N (1995) The effect of fluctuations in relative humidity on library and archival materials and their aging within contained microenvironments. In: Arnoult JM (ed) Proceedings of Pan-African conference on the preservation and conservation of library and archival materials. IFLA, The Hague, pp 61–70
Sharples A (1971) Acid hydrolysis and alcoholysis. In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives. Wiley-Interscience, New York, pp 991–1006
Strang T, Grattan D (2009) Temperature and humidity considerations for the preservation of organic collections—the isoperm revisited. E-Preserv Sci 6:122–128
Strlič M, Grossi CM, Dillon C et al (2015) Damage function for historic paper part III: isochrones and demography of collections. Herit Sci. https://doi.org/10.1186/s40494-015-0069-7
Tétreault J, Dupont A-L, Bégin P, Paris S (2013) The impact of carbonyl and hydrogen peroxide vapours on cellulose degradation under ambient hygrothermal conditions. Polym Degrad Stab 98:1827–1837. https://doi.org/10.1016/j.polymdegradstab.2013.05.017
Tétreault J, Bégin P, Paris S, Dupont A-L (2019) Modelling considerations for the degradation of cellulosic. Cellulose 26:2013–2033. https://doi.org/10.1007/s10570-018-2156-x
Timmermann EO (2003) Multilayer sorption parameters: BET or GAB values? Colloid Surf A 220(1):235–260. https://doi.org/10.1016/S0927-7757(03)00059-1
Vibert C, Fayolle B, Ricard D, Dupont A-L (2023) Decoupling hydrolysis and oxidation of cellulose in permanent paper aged under atmospheric conditions. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2023.120727
Wilson WK, Harvey JL, Mandel JM, Worksman T (1955) Accelerating aging of records papers compared with natural aging. Tappi J 38:543–547
Young RA (1994) Comparison of the properties of chemical cellulose pulps. Cellulose 1:107–130. https://doi.org/10.1007/BF00819662
Zervos S (2010) Natural and accelerated ageing of cellulose and paper: a literature review. In: Lejeune A, Deprez T (eds) Cellulose: structure and properties, derivatives and industrial uses. Nova Publishing, New York, pp 155–203
Zhang B, Huang H-J, Ramaswamy S (2008) Reaction kinetics of the hydrothermal treatment of lignin. Appl Biochem Biotechnol 147:119–131. https://doi.org/10.1007/s12010-007-8070-6
Zou X, Uesaka T, Gurnagul N (1996a) Prediction of paper permanence by accelerating aging part I. Kinetic analysis of the aging process. Cellulose 3:243–267. https://doi.org/10.1007/BF02228805
Zou X, Uesaka T, Gurnagul N (1996b) Prediction of paper permanence by accelerating aging part II. Comparison of the predictions with natural aging results. Cellulose 3:269–279. https://doi.org/10.1007/BF02228806