Mixed-ligand complexes of paddlewheel dinuclear molybdenum as hydrodehalogenation catalysts for polyhaloalkanes

Chemical Science - Tập 6 Số 6 - Trang 3434-3439
Hayato Tsurugi1,2,3,4,5, Akio Hayakawa1,2,3,4,5, Shun Kando1,2,3,4,5, Yoshitaka Sugino1,2,3,4,5, Kazushi Mashima1,2,3,4,5
1CREST
2Department of Chemistry, Graduate School of Engineering Science, Osaka University, CREST, Toyonaka, Osaka 560-8531, Japan
3Graduate School of Engineering Science
4Osaka University
5Toyonaka

Tóm tắt

A mixed-ligated dimolybdenum complex Mo2(OAc)2[CH(NAr)2]2 in combination with 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene and nBu4NCl exhibited high catalytic activity for hydrodehalogenation reactions.

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