Mixed Salt Cs2[I(OH)3O3] · CsSO4(H)H5IO6: Synthesis, Crystal Structure, and Properties
Tóm tắt
The mixed salt Cs2[I(OH)3O3] · CsSO4(H)H5IO6 (I) was synthesized for the first time, and its structure and properties were studied by X-ray diffraction, IR and Raman spectroscopies, impedance measurements and DTA method. It crystallizes in trigonal system: a = 7.503(2) Å, c = 16.631(3) Å, space group P3, Z = 2. The crystal structure consists of octahedral IO6 and tetrahedral SO4 fragments, linked by a three-dimensional network of hydrogen bonds, and of the Cs+ ions.
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