Microstructures and microwave dielectric properties of (Ba1−xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 solid solutions

Journal of Advanced Ceramics - Tập 6 - Trang 50-58 - 2017
Xianpei Huang1, Xinyu Liu1, Fei Liu2, Changlai Yuan1,3, Jingjing Qu4, Jiwen Xu1, Changrong Zhou1, Guohua Chen1
1School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin, China
2School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin, China
3Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, China
4Department of Information Engineering, Guilin University of Aerospace Technology, Guilin, China

Tóm tắt

(Ba1−xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 (x = 0.02, 0.04, 0.06, 0.08, 0.1) solid solutions were prepared by the conventional solid-state reaction process. It was found that (Ba1−xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramics are fully composed of BaSm2Ti4O12 and BaNd2Ti5O14 phases for all the compositions. The increasing x value (0.02 ≤ x ≤ 0.1) in ((Ba1−xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramics can not only obtain high Q × f value but also effectively enhance the permittivity (εr). The (Ba1−xSrx)4(Sm0.4Nd0.6)28/3Ti18O54 ceramic with x = 0.08, sintered at 1440 °C for 4 h, shows excellent microwave dielectric properties of permittivity (εr) ≈ 93.19, quality factor (Q × f) ≈ 9770.14 GHz (at 3.415 GHz), and almost near-zero temperature coefficient of resonant frequency (τf) ≈ +4.56 ppm/°C.

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