Microstructure and Mechanical Properties of the Extruded Al-Cu-Mn-Sc-Zr Alloy during Single-Stage and Two-Stage Aging

Journal of Materials Engineering and Performance - Tập 32 - Trang 185-198 - 2022
Zhiyong Cai1, Haijiang Liu1, Richu Wang1,2, Chaoqun Peng1, Yan Feng1, Xiaofeng Wang1
1School of Materials Science and Engineering, Central South University, Changsha, China
2National Key Laboratory of Science and Technology on High-strength Structural Materials, Central South University, Changsha, China

Tóm tắt

The evolution of microstructure and mechanical properties of hot extruded Al-5.5Cu-Mn-Sc-Zr and Al-6.5Cu-Mn-Sc-Zr alloys during solution and different aging treatments was investigated. The typical fibrous structure and elongated grains along the extrusion direction were observed in the two alloys. After solution and aging treatments, the proportion of large-size grains in the alloys increases slightly. The yield strength, ultimate tensile strength and elongation of the Al-5.5Cu-Mn-Sc-Zr alloy aged at 175 °C for 24 h are 400.8, 472.4 MPa and 13.9%, respectively. However, the growth and coarsening of the θ′ phase result in the decrease of strength of the Al-6.5Cu-Mn-Sc-Zr alloy. After 120 °C/6 h + 190 °C/3 h two-stage aging, the strength of the two alloys is equivalent to that of single-stage peak aging, while the time required is shortened. The two-stage aging has good application value in reducing aging time.

Tài liệu tham khảo

B. Grushko and S.B. Mi, Al-Rich Region of Al-Cu-Mn, J. Alloy. Compd., 2016, 688, p 957–963. D. Srinivasan and K. Chattopadhyay, Hardness of High Strength Nanocomposite Al-X-Zr (X=Si, Cu, Ni) Alloys, Mater. Sci. Eng. A, 2004, 375–377, p 1228–1234. H.S. Yoo, Y.H. Kim, S.H. Lee and H.T. Son, The Effect of Mn and Ca Addition on the Microstructure and Mechanical Properties of the Al-Cu-Fe-Si-Zn Based Alloys, J. Nanosci. Nanotechnol., 2020, 20(7), p 4307–4311. W.G. Wang, G. Wang, Y.S. Hu, G.N. Guo, T.T. Zhou and Y.M. Rong, Temperature-Dependent Constitutive Behavior with Consideration of Microstructure Evolution for as-Quenched Al-Cu-Mn alloy, Materi. Sci. Eng. a-Struct. Mater. Prop. Microstruct. Proc., 2016, 678, p 85–92. J. Feng, B. Ye, L.J. Zuo, R.J. Qi, Q.D. Wang, H.Y. Jiang, R. Huang, W.J. Ding, J. Yao and C.T. Wang, Effects of Zr, Ti and Sc Additions on the Microstructure and Mechanical Properties of Al-0.4Cu-0.14Si-0.05Mg-0.2Fe Alloys, J. Mater. Sci. Technol., 2018, 34(12), p 2316–2324. J.H. Ding, C.X. Cui, Y.J. Sun, L.C. Zhao and S. Cui, Effect of Mo, Zr, and Y on the High-Temperature Properties of Al-Cu-Mn Alloy, J. Mater. Res., 2019, 34(22), p 3853–3861. Z.W. Chen, P. Chen and C.Y. Ma, Microstructures and Mechanical Properties of Al-Cu-Mn Alloy with La and Sm Addition, Rare Met., 2012, 31(4), p 332–335. Z.W. Chen, M.J. Tang and K. Zhao, Effect of Rare Earth Samarium Addition on the Kinetics of Precipitation in Al-Cu-Mn Casting Alloy, Int. J. Miner. Metall. Mater., 2014, 21(2), p 155–161. Z. Chen, P. Chen and S. Li, Effect of Ce Addition on Microstructure of Al20Cu2Mn3 Twin Phase in an Al-Cu-Mn Casting Alloy, Mater. Sci. Eng. a-Struct. Mater. Prop. Microstruct. Proc., 2012, 532, p 606–609. J.D. Poplawsky, B.K. Milligan, L.F. Allard, D.W. Shin, P. Shower, M.F. Chisholm and A. Shyam, The Synergistic Role of Mn and Zr/Ti in Producing θ’/L1(2) Co-Precipitates in Al-Cu Alloys, Acta Mater., 2020, 194, p 577–586. F.S. Meng, Z. Wang, Y.L. Zhao, D.T. Zhang and W.W. Zhang, Microstructures and Properties Evolution of Al-Cu-Mn Alloy with Addition of Vanadium, Metals, 2017, 7(1), p 10. X.W. Yang, J.C. Zhu, Z.S. Nong, Y. Mao, Z.H. Lai and Y. Liu, Constitutive Behavior of as-Quenched Al-Cu-Mn alloy, Mod. Phys. Lett. B, 2013, 27(19), p 1341036. S. Bahl, X.H. Hu, E. Hoar, J.H. Cheng, J.A. Haynes and A. Shyam, Effect of Copper Content on the Tensile Elongation of Al-Cu-Mn-Zr alloys: Experiments and Finite Element Simulations, Mater. Sci. Eng., 2020, 772, p 138801. K. Ren, G. Wang, W.G. Wang, Y.S. Hu, H.D. Wang and Y.M. Rong, The Influence of Casting Microvoids on the Constitutive Behavior of As-Quenched Al-Cu-Mn Alloy, J. Mater. Eng. Perform., 2019, 28(11), p 6638–6648. K. Bharath, A.K. Khanra and M.J. Davidson, Hot Deformation Behavior and Dynamic Recrystallization Constitutive Modeling of Al-Cu-Mg Powder Compacts Processed by Extrusion at Elevated Temperatures, Proc. Inst. Mech. Eng. Part L J. Mater. Des. Appl., 2020, 235(3), p 581–596. R. Kaibyshev, I. Mazurina and O. Sitdikov, Geometric Dynamic Recrystallization in an AA2219 Alloy Deformed to Large Strains at an Elevated Temperature, Mater. Sci. Forum, 2004, 467–470, p 1199–1204. https://doi.org/10.4028/www.scientific.net/MSF.467-470.1199 R.M. Su, K.N. Wang, Y.P. Yang, Y.D. Qu and R.D. Li, Effect of Mg Content on the Microstructure and Corrosion Properties of Al-Cu-Mn Alloy, J. Mater. Eng. Perform., 2020, 29(3), p 1622–1629. J.M. Jang, D.G. Nam, Y.H. Park and I.M. Park, Effect of Solution Treatment and Artificial Aging on Microstructure and Mechanical Properties of Al-Cu Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23(3), p 631–635. M. Kamp, N. GAO, M.J. Starink and I. Sinclair, Influence of Grain Structure and Slip Planarity on Fatigue Crack Growth in Low Alloying Artificially Aged 2xxx Aluminium Alloys, Int. J. Fatigue, 2007, 29(5), p 869–878. G. Özer, A. Kisasöz and A. Karaaslan, Investigation of the Relationship Between Intergranular Corrosion and Retrogression and Reaging in the AA6063, Mater. Corros., 2019, 70(12), p 2256–2265. https://doi.org/10.1002/maco.201911100 D.J. Chakrabarti and D.E. Laughlin, Phase Relations and Precipitation in Al-Mg-Si Alloys with Cu Additions, Prog. Mater. Sci., 2004, 49(3–4), p 389–410. B.T. Sofyan, K. Raviprasad and S.P. Ringer, Effects of Microalloying with Cd and Ag on the Precipitation Process of Al-4Cu-0.3Mg (wt.%) Alloy at 200 °C, Micron, 2001, 32(8), p 851–856. https://doi.org/10.1016/S0968-4328(00)00093-7 Z.W. Chen, Q.Y. Fan and K. Zhao, Microstructure and Microhardness of Nanostructured Al−4.6Cu−Mn Alloy Ribbons, Int. J. Miner. Metall. Mater., 2015, 22(8), p 860–867. https://doi.org/10.1007/s12613-015-1143-6 S.M. Dar, H. Liao and A. Xu, Effect of Cu and Mn Content on Solidification Microstructure, T-Phase Formation and Mechanical Property of Al-Cu-Mn Alloys, J. Alloy. Compd., 2019, 774, p 758–767. J.L. Chen, H.C. Liao and H.T. Xu, Uneven Precipitation Behavior during the Solutionizing Course of Al-Cu-Mn Alloys and Their Contribution to High Temperature Strength, Adv. Mater. Sci. Eng., 2018, 2018, p 12. Z.J. Shen, Q.Q. Ding, C.H. Liu, J.W. Wang, H. Tian, J.X. Li and Z. Z, Atomic-Scale Mechanism of the θ″ → θ′ Phase Transformation in Al-Cu Alloys, J. Mater. Sci. Technol, 2017, 33(10), p 1159–1164. N.A. Belov, A.N. Alabin and I.A. Matveeva, Optimization of Phase Composition of Al-Cu-Mn-Zr-Sc Alloys for Rolled Products Without Requirement for Solution Treatment and Quenching, J. Alloy. Compd., 2014, 583, p 206–213. T. Dorin, M. Ramajayam, J. Lamb and T. Langan, Effect of Sc and Zr Additions on the Microstructure/Strength of Al-Cu Binary Alloys, Mater. Sci. Eng. A, 2017, 707, p 58–64. B. Rouxel, M. Ramajayam, T.J. Langan, J. Lamb, P.G. Sanders and T. Dorin, Effect of Dislocations, Al3(Sc, Zr) Distribution and Ageing Temperature on θ′ Precipitation in Al-Cu-(Sc)-(Zr) Alloys, Materialia, 2020, 9, p 100610. B. Noble, Theta-Prime Precipitation in Aluminium-Copper-Cadmium Alloys, Acta Metall., 1968, 16(3), p 394–401. Q.B. Kuang, R.C. Wang, C.Q. Pen and Z.Y. Cai, Microstructure and Mechanical Properties of Al-Mg-Li-Sc-Zr Alloy Processed by Spray Deposition and Thermo-Mechanical Processes, Mater. Charact., 2020, 169, p 110614.