Micro/nano-structured SnS2 negative electrodes using chitosan derivatives as water-soluble binders for Li-ion batteries
Tóm tắt
Micro/nano-structured SnS2 was prepared by a hydrothermal method using biomolecular l-cysteine and SnCl4·5H2O as sulfur source and tin source, respectively. The electrochemical performances of SnS2 electrodes were investigated using water-soluble binders of carboxymethyl chitosan (C-chitosan) and chitosan lactate, and compared with the conventional water-soluble sodium carboxymethyl cellulose (CMC) and non-aqueous polyvinylidene difluoride (PVDF). SnS2 electrode using the water-soluble binders (C-chitosan, chitosan lactate, and CMC) showed higher initial coulombic efficiency, larger reversible capacity, and better rate capabilities than that of PVDF. In addition, SnS2 electrode using C-chitosan binder exhibited somewhat worse cycling stability, but better rate capability at a high rate of 5C than CMC.
Tài liệu tham khảo
Lou XW, Deng D, Lee JY, Feng J, Archer LA (2008) Self-supported formation of needlelike Co3O4 nanotubes and their application as lithium-ion battery electrode. Adv Mater 20:258–262
Wen SH, Hou ZF, Han KLA (2009) Promising anode material for lithium-ion batteries. J Phys Chem C 113:18436–18440
Martha SK, Nanda J, Veith GM, Dudney NJ (2012) Electrochemical and rate performance study of high-voltage lithium-rich composition: Li1.2Mn0.525Ni0.175Co0.1O2. J Power Sources 199:220–226
Sladkevich S, Gun J, Prikhodchenko PV, Gutkin V, Mikhaylov AA, Novotortsev VM, Zhu JX, Yang D, Hng HH, Tay YY, Tsakadze Z, Lev O (2012) Peroxide induced tin oxide coating of graphene oxide at room temperature and its application for lithium-ion batteries. Nanotechnology 23:485601
Martha SK, Grinblat J, Haik O, Zinigrad E, Drezen T, Miners JH, Exnar I, Kay A, Markovsky B, Aurbach D (2009) LiMn0.8Fe0.2PO4: an advanced cathode material for rechargeable lithium batteries. Angew Chem Int Ed 48:8559–8563
Tse KY, Zhang LZ, Baker SE, West R, Hamers RJ (2007) Vertically aligned carbon nanofibers coupled with organosilicon electrolytes: electrical properties of a high-stability nanostructured electrochemical interface. Chem Mater 19:5734–5741
Yoo M, Frank CW, Mori S, Yamaguchi S (2003) Effect of poly(vinylidene fluoride) binder crystallinity and graphite structure on the mechanical strength of the composite anode in lithium-ion battery. Polymer 44:4197–4204
Guy D, Lestriez B, Guyomard D (2004) New composite electrode architecture and improved battery performance from the smart use of polymers and their properties. Adv Mater 16:553–557
Huang H, Yin SC, Kerr T, Taylor N, Nazar LF (2002) Nanostructured composites: a high capacity, fast rate Li3V2(PO4)3/carbon cathode for rechargeable lithium batteries. Adv Mater 14:1525–1528
Chen ZH, Christensen L, Dahn JR (2003) Comparison of PVDF and PVDF-TFE-P as binders for electrode materials showing large volume changes in lithium-ion batteries. J Electrochem Soc 150:A1073–A1078
Liu WR, Yang MH, Wu HC, Chiao SM, Wu NL (2005) Enhanced cycle life of Si anode for Li-ion batteries by using modified elastomeric binder. Electrochem Solid State Lett 8:A100–A103
Li J, Lewis RB, Dahn JR (2007) Sodium carboxymethyl cellulose a potential binder for Si negative electrodes for Li-ion batteries. Electrochem Solid State Lett 10:A17–A20
Lee JH, Paik U, Hackney VA, Choi YM (2005) Effect of carboxymethyl cellulose on aqueous processing of natural graphite negative electrodes and their electrochemical performance for lithium batteries. J Electrochem Soc 152:A1763–A1769
Drofenik J, Gaberscek M, Dominko R, Poulsen FW, Morgensen M, Pejovnik S, Jamnik J (2003) Cellulose as a binding material in graphitic anodes for Li-ion batteries: a performance and degradation study. Electrochim Acta 48:883–889
Lee JH, Paik U, Hackley VA, Choi YM (2006) Effect of poly(acrylic acid) on adhesion strength and electrochemical performance of natural graphite negative electrode for lithium-ion batteries. J Power Sources 161:612–616
Li J, Leb DB, Fergusonc PP, Dahna JR (2010) Lithium polyacrylate as a binder for tin–cobalt–carbon negative electrodes in lithium-ion batteries. Electrochim Acta 55:2991–2995
Kovalenko I, Zdyrko B, Magasinski A, Hertzberg B, Milicev Z, Burtovyy R, Luzinov I, Yushin G (2011) A major constituent of brown algae for use in high-capacity Li-ion batteries. Science 7:75–79
Bridel JS, AzaÏs T, Morcrette M, Tarascon JM, Larcher D (2010) Toward efficient binders for Li-ion battery Si-based anodes: polyacrylic acid. Chem Mater 22:1229–1241
Zhai CX, Du N, Zhang H, Yang DR (2011) Large-scale synthesis of ultrathin hexagonal tin disulfide nanosheets with highly reversible lithium storage. Chem Commun 47:1270–1272
Luo B, Fang Y, Wang B, Zhou JS, Song HH, Zhi LJ (2012) Two dimensional graphene–SnS2 hybrids with superior rate capability for lithium ion storage. Energy Environ Sci 5:5226–5230
Seo JW, Jang JT, Park SW, Kim C, Park B, Cheon J (2008) Two-dimensional SnS2 nanoplates with extraordinary high discharge capacity for lithium-ion batteries. Adv Mater 20:4269–4273
Liu Y, Xie JY, Takeda Y, Yang J (2002) Advanced Sn/C composite anodes for lithium-ion batteries. J Appl Electrochem 32:687–692
Wang J, Liu J, Xu HB, Ji SM, Wang JB, Zhou YC, Hodgson P, Li YC (2013) Gram-scale and template-free synthesis of ultralong tin disulfide nanobelts and their lithium-ion storage performances. J Mater Chem 1:1117–1122
Liu SY, Lu X, Xie J, Cao GS, Zhu TJ, Zhao XB (2013) Preferential c-axis orientation of ultrathin SnS2 nanoplates on graphene as high-performance anode for Li-ion batteries. ACS Appl Mater Interfaces 5:1588–1595
Wang QF, Huang Y, Miao J, Zhao Y, Wang Y (2013) Synthesis and electrochemical characterizations of Ce doped SnS2 anode materials for rechargeable lithium-ion batteries. Electrochim Acta 93:120–130
Zhong HX, Wang CX (2011) Synthesis and field emission properties of SnS2 and In-doped SnS2 with hierarchical structure. NANO 6:5489–5496
Lei YQ, Song SY, Fan WQ, Xing Y, Zhang HJ (2009) Facile synthesis and assemblies of flowerlike SnS2 and In3+-doped SnS2: hierarchical structures and their enhanced photocatalytic property. J Phys Chem C 113:1280–1285
Zhong HX, Yang GZ, Song HW, Liao QY, Cui H, Shen PK, Wang CX (2012) Vertically aligned graphene-like SnS2 ultrathin nanosheet arrays: excellent energy storage, catalysis, photoconduction, and field-emitting performances. J Phys Chem C 116:9319–9326
Price LS, Parkin IP, Hardy AME, Clark RJH (1999) Atmospheric pressure chemical vapor deposition of tin sulfides (SnS, Sn2S3, and SnS2) on glass. Chem Mater 11:1792–1799
Kruk M, Jaroniec M (2001) Gas adsorption characterization of ordered organic–inorganic nanocomposite materials. Chem Mater 13:3169–3183
Chen LY, Zhang ZD, Wang WZ (2008) Self-assembled porous 3D flowerlike β-In2S3 Structures: synthesis, characterization and optical properties. J Phys Chem C 112:4117–4123
Hu YS, Adelhelm P, Smarsly BM, Hore S, Antonietti M, Maier J (2007) Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability. Adv Funct Mater 17:1873–1878
Kim TJ, Kim C, Son D, Choi M, Park B (2007) Novel SnS2-nanosheet anodes for lithium-ion batteries. J Power Sources 167:529–535
Liu S, Yin XM, Chen L, Li QH, Wang TH (2010) Synthesis of self-assembled 3D flowerlike SnS2 nanostructures with enhanced lithium ion storage property. Solid State Sci 12:712–718
Lefebvre-Devos I, Olivier-Fourcade J, Jumas JC, Lavela P (2000) Lithium insertion in SnS2. Phys Rev B 61:3110–3116
Zhang SS (2006) A review on electrolyte additives for lithium-ion batteries. J Power Sources 162:1379–1394
Lestriez B, Bahri S, Sandu I, Roué L, Guyomard D (2007) On the binding mechanism of CMC in Si negative electrodes for Li-ion batteries. Electrochem Commun 9:2801–2806
Wang ZL, Dupre N, Gaillot AC, Lestriez B, Martin JF, Daniel L, Patoux S, Guyomard D (2012) CMC as a binder in LiNi0.4Mn1.6O4 5 V cathodes and their electrochemical performance for Li-ion batteries. Electrochim Acta 62:77–83