Method for Measuring the Combustion Heat of Natural Gas with Isothermal Calorimeter

Pleiades Publishing Ltd - Tập 74 - Trang 1539-1545 - 2001
Yu. I. Aleksandrov1,2, V. I. Belyakov1,2, V. P. Varganov1,2, S. Sarge1,2
1Mendeleev Russian Research Institute of Metrology, State Unitary Enterprise, St. Petersburg, Russia
2Physicotechnical Institute, Braunschweig, Germany

Tóm tắt

Factors that are to be taken into account in developing a calorimetric technique are considered. The possible deviations of temperatures at the inlet and outlet of gases in the calorimeter from the nominal values are evaluated and an example of such estimate is given for the case of methane burning in batch and continuous operation modes. The necessity for taking into account the humidity of gases fed into the calorimeter burner is demonstrated. The proposed method was used to perform absolute measurements of the combustion heat of methane.

Từ khóa


Tài liệu tham khảo

Aleksandrov, Yu.I. and Varganov, V.P., Zh. Prikl. Khim., 2001, vol. 74, no. 9, pp. 1484-1488.

Aleksandrov, Yu.I., Varganov, V.P., and Sarge, S., Zh. Prikl. Khim., 2001, vol. 74, no. 9, pp. 1488-1493.

ISO/DIS 6976:1996: Natural Gas-Calculation of Calorific Value, Density, Relative Density and Wobbe Index from Composition, Geneve (Switzerland): Int. Organisation for Standardization, 1996.

GOST (State Standard) 30 319.0-96: Natural Gas. Methods for Property Calculations, Moscow: Izd. Standartov, 1997.

ISO/CD 13443:1993: Natural Gas-Standard Reference Conditions, Geneve (Switzerland): Int. Organisation for Standardization, 1993.

GOST (State Standard) 21 261-75: Petroleum Products. Methods for Determining Specific Heat of Combustion, Moscow: Izd. Standartov, 1985.

GOST (State Standard) 147-95 (ISO 1928-76): Solid Mineral Fuel. Determining the Highest and Calculating the Lowest Heat of Combustion, Minsk: Izd. Standartov, 1995.

GOST (State Standard) 22 667-95: Natural Combustible Gases. Method for Calculation of Combustion Heat, Density, Relative Density, and Wobbe Index from Gas Composition, Moscow: Izd. Standartov, 1995.

GOST (State Standard) 27 193-86: Natural Combustible Gases. Method for Determining Combustion Heat with Water Calorimeter, Moscow: Izd. Standartov, 1987.

GOST (State Standard) 30 319.1-96: Natural Gas. Methods for Calculation of Physical Properties. Determining the Physical Properties of Natural Gas, Its Components, and Products of Its Processing,Moscow: Izd. Standartov, 1997.

DIN 51857-1994: Gasförmige Brennstoffe und sonstige Gase, Berechnung von Brennwert, Heizwert, Dichte, relative Dichte und Wobbeindex von Gasen und Gasgemischen, 1994.

Cerbe, G., Grundlagen der Gastechnik, München: Carl Hauser, 1992, 4th ed.

Pittam, D.A. and Pilcher, G., J. Chem. Soc., Faraday Trans. 1, 1972, vol. 68, pp. 2224-2226.

Physical Properties of Natural Gases, Geerssen, T.M., Ed., Groningen (Netherlands): N.V. Nederlandse Gasunie, 1988.

MI (Methodical Instructions) 2552-99: Recommendations of the State Measurement Service. Use of the “Guide to Expression of Uncertainty in Measurements” St. Petersburg: Vseross. Nauchno-Issled. Inst. Metrologii im. D.I. Mendeleeva, 1999.