Metallopolymers with transition metals in the side-chain by living and controlled polymerization techniques

Jäkle, 2010, Advances in the synthesis of organoborane polymers for optical, electronic, and sensory applications, Chem Rev, 110, 3985, 10.1021/cr100026f Abd-El-Aziz, 2007 Manners, 2004 2006 1985 Abd-El-Aziz, 2002, Organometallic polymers of the transition metals, Macromol Rapid Commun, 23, 995, 10.1002/marc.200290003 Beck, 2005, Metal/ligand-induced formation of metallo-supramolecular polymers, Macromolecules, 38, 5060, 10.1021/ma050369e Calzia, 2002, Methacrylate polymers containing metal binding ligands for use in supramolecular materials: random copolymers containing terpyridines, Macromolecules, 35, 6090, 10.1021/ma025551j Keng, 2009, Colloidal polymerization of polymer-coated ferromagnetic nanoparticles into cobalt oxide nanowires, ACS Nano, 3, 3143, 10.1021/nn900483w Korth, 2006, Polymer-coated ferromagnetic colloids from well-defined macromolecular surfactants and assembly into nanoparticle chains, J Am Chem Soc, 128, 6562, 10.1021/ja0609147 Yang, 2011, Main-chain supramolecular block copolymers, Chem Soc Rev, 40, 129, 10.1039/C0CS00073F Wang, 2010, Metal-containing polymers: building blocks for functional (nano)materials, Macromol Rapid Commun, 31, 331, 10.1002/marc.200900558 Wang, 2013, Migration insertion polymerization (MIP) of cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP): a new concept for main chain metal-containing polymers (MCPs), J Am Chem Soc, 135, 3399, 10.1021/ja400755e Szwarc, 1956, ‘Living’ polymers, Nature, 178, 1168, 10.1038/1781168a0 Hadjichristidis, 2001, Polymers with complex architecture by living anionic polymerization, Chem Rev, 101, 3747, 10.1021/cr9901337 Manners, 2001, Putting metals into polymers, Science, 294, 1664, 10.1126/science.1066321 Hudson, 2001, Ferrocene polymers: current architectures, syntheses and utility, J Organomet Chem, 637–639, 47, 10.1016/S0022-328X(01)01142-1 Abd-El-Aziz, 2012, Transition metal-containing macromolecules: en route to new functional materials, Polymer, 53, 4879, 10.1016/j.polymer.2012.08.024 Abd-El-Aziz, 2005, Neutral and cationic macromolecules based on iron sandwich complexes, J Inorg Organomet Polym, 15, 157, 10.1007/s10904-004-2384-4 Abd-El-Aziz, 2010, Synthetic methodologies and properties of organometallic and coordination macromolecules, Prog Polym Sci, 35, 714, 10.1016/j.progpolymsci.2010.01.004 Nguyen, 1999, Organometallic polymers with transition metals in the main chain, Chem Rev, 99, 1515, 10.1021/cr960113u Pittman, 1977, Anionic homopolymerization of ferrocenylmethyl methacrylate, J Polym Sci Polym Chem Ed, 15, 1677, 10.1002/pol.1977.170150716 Pittman, 1978, Synthesis of block copolymers containing poly(ferrocenylmethyl methacrylate) units, J Polym Sci Polym Chem Ed, 16, 1197, 10.1002/pol.1978.170160603 Pittman, 1979, Attempted anionic homo- and copolymerization of vinylcymantrene, ferrocenylmethyl acrylate, η6-(benzyl acrylate)-tricarbonylchromium, and η4-(2,4-hexadien-1-yl methacrylate)-tricarbonyliron, J Polym Sci Polym Chem Ed, 17, 271, 10.1002/pol.1979.170170127 Flanagan, 1978, Electron transfer to and from molecules containing multiple, noninteracting redox centers. Electrochemical oxidation of poly(vinylferrocene), J Am Chem Soc, 100, 4248, 10.1021/ja00481a040 Van de Mark, 1978, A poly-p-nitrostyrene electrode surface. Potential dependent conductivity and electrocatalytic properties, J Am Chem Soc, 100, 3223, 10.1021/ja00478a050 Daum, 1980, Diffusional charge transport through ultrathin films of radiofrequency plasma polymerized vinylferrocene at low temperature, J Am Chem Soc, 102, 4649, 10.1021/ja00534a014 Nowak, 1980, Chemically modified electrodes. Radiofrequency plasma polymerization of vinylferrocene on glassy carbon and platinum electrodes, Anal Chem, 52, 315, 10.1021/ac50052a024 Umana, 1981, Comparison of X-ray photoelectron spectroscopy and cyclic voltammetry for the determination of polymeric film thickness of ruthenium vinylbipyridine and vinylferrocene deposited on electrodes, Anal Chem, 53, 1170, 10.1021/ac00231a007 Abruña, 1988, Coordination chemistry in two dimensions: chemically modified electrodes, Coord Chem Rev, 86, 135, 10.1016/0010-8545(88)85013-6 Foucher, 1992, Ring-opening polymerization of strained, ring-tilted ferrocenophanes: a route to high-molecular-weight poly(ferrocenylsilanes), J Am Chem Soc, 114, 6246, 10.1021/ja00041a053 Matas, 2010, Synthesis, electronic structure, and reactivity of strained nickel-, palladium-, and platinum-bridged [1]ferrocenophanes, J Am Chem Soc, 132, 13279, 10.1021/ja103367e Baumgartner, 2002, Nucleophilically assisted and cationic ring-opening polymerization of tin-bridged [1]ferrocenophanes, J Am Chem Soc, 124, 10062, 10.1021/ja020206v Berenbaum, 2000, Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes, J Am Chem Soc, 122, 5765, 10.1021/ja000311+ Jäkle, 2000, Nucleophilically assisted ring-opening polymerization of group 14 element-bridged [1]ferrocenophanes, J Am Chem Soc, 122, 4231, 10.1021/ja9941227 Rulkens, 1997, Highly strained, ring-tilted [1]ferrocenophanes containing group 16 elements in the bridge: synthesis, structures, and ring-opening oligomerization and polymerization of [1]thia- and [1]selenaferrocenophanes, J Am Chem Soc, 119, 10976, 10.1021/ja972043u Rulkens, 1994, Anionic ring-opening oligomerization and polymerization of silicon-bridged [1]ferrocenophanes: characterization of short-chain models for poly(ferrocenylsilane) high polymers, J Am Chem Soc, 116, 797, 10.1021/ja00081a062 Rulkens, 1996, Linear oligo(ferrocenyldimethylsilanes) with between two and nine ferrocene units: electrochemical and structural models for poly(ferrocenylsilane) high polymers, J Am Chem Soc, 118, 12683, 10.1021/ja962470s Chuang, 2009, Templated self-assembly of square symmetry arrays from an ABC triblock terpolymer, Nano Lett, 9, 4364, 10.1021/nl902646e Eloi, 2011, Stimulus-responsive self-assembly: reversible, redox-controlled micellization of polyferrocenylsilane diblock copolymers, J Am Chem Soc, 133, 8903, 10.1021/ja1105656 Wang, 2003, Shell cross-linked cylinders of polyisoprene-b-ferrocenyldimethylsilane: formation of magnetic ceramic replicas and microfluidic channel alignment and patterning, J Am Chem Soc, 125, 12686, 10.1021/ja037521h MacLachlan, 2000, Superparamagnetic ceramic nanocomposites: synthesis and pyrolysis of ring-opened poly(ferrocenylsilanes) inside periodic mesoporous silica, J Am Chem Soc, 122, 3878, 10.1021/ja992006y Wang, 1995, Controlled/“living” radical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes, J Am Chem Soc, 117, 5614, 10.1021/ja00125a035 Percec, 1995, “Living” radical polymerization of styrene initiated by arenesulfonyl chlorides and CuI(bpy)nCl, Macromolecules, 28, 7970, 10.1021/ma00127a057 Kato, 1995, Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenylphosphine)ruthenium(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization, Macromolecules, 28, 1721, 10.1021/ma00109a056 Matyjaszewski, 2001, Atom transfer radical polymerization, Chem Rev, 101, 2921, 10.1021/cr940534g Tsarevsky, 2007, “Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials, Chem Rev, 107, 2270, 10.1021/cr050947p Matyjaszewski, 2012, Atom transfer radical polymerization (ATRP): current status and future perspectives, Macromolecules, 45, 4015, 10.1021/ma3001719 Matyjaszewski, 2009, Nanostructured functional materials prepared by atom transfer radical polymerization, Nat Chem, 1, 276, 10.1038/nchem.257 Chiefari, 1998, Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process, Macromolecules, 31, 5559, 10.1021/ma9804951 Moad, 2003, Synthesis of novel architectures by radical polymerization with reversible addition fragmentation chain transfer (RAFT polymerization), Macromol Symp, 192, 1, 10.1002/masy.200390029 Hawker, 2001, New polymer synthesis by nitroxide mediated living radical polymerizations, Chem Rev, 101, 3661, 10.1021/cr990119u Nicolas, 2013, Nitroxide-mediated polymerization, Prog Polym Sci, 38, 63, 10.1016/j.progpolymsci.2012.06.002 Hardy, 2012, Side-chain metallocene-containing polymers by living and controlled polymerizations, Isr J Chem, 52, 230, 10.1002/ijch.201100110 Weck, 2007, Side-chain functionalized supramolecular polymers, Polym Int, 56, 453, 10.1002/pi.2200 Shunmugam, 2008, Polymers that contain ligated metals in their side chain: building a foundation for functional materials in opto-electronic applications with an emphasis on lanthanide ions, Macromol Rapid Commun, 29, 1355, 10.1002/marc.200800083 Abd-El-Aziz, 2002, Monomers, oligomers and polymers containing arenes with pendent transition metal moieties, Coord Chem Rev, 233–234, 177, 10.1016/S0010-8545(02)00032-2 Dragutan, 2008, Synthesis of metal-containing polymers via ring opening metathesis polymerization (ROMP). Part II: Polymers containing transition metals, J Inorg Organomet Polym, 18, 311, 10.1007/s10904-008-9213-0 Amadoruge, 2008, Singly bonded catenated germanes: eighty years of progress, Chem Rev, 108, 4253, 10.1021/cr800197r Jäkle, 2006, Lewis acidic organoboron polymers, Coord Chem Rev, 250, 1107, 10.1016/j.ccr.2006.01.007 Abd-Ei-Aziz, 2007 Arimoto, 1955, Derivatives of dicyclopentadienyliron, J Am Chem Soc, 77, 6295, 10.1021/ja01628a068 Baldwin, 1967, Free radical polymerization of vinyl ferrocene, J Polym Sci A: Polym Chem, 5, 2091, 10.1002/pol.1967.150050825 Sasaki, 1973, Organometallic polymers. XXV. Preparation of polyvinylferrocene, J Polym Sci Polym Chem Ed, 11, 1213, 10.1002/pol.1973.170110609 George, 1975, Free-radical polymerization of vinylferrocene. I. Kinetics, J Polym Sci Polym Chem Ed, 13, 1049, 10.1002/pol.1975.170130503 George, 1976, Free-radical polymerization of vinylferrocene. II. Spectroscopic and physical properties, J Polym Sci Polym Chem Ed, 14, 475, 10.1002/pol.1976.170140218 George, 1974, Polymerization of vinylferrocene in chloroform, Polymer, 15, 397, 10.1016/0032-3861(74)90187-6 Pittman, 1971, Organometallic polymers. XIV. Copolymerization of vinylcyclopentadienyl manganese tricarbonyl and vinylferrocene with N-vinyl-2-pyrrolidone, J Polym Sci A: Polym Chem, 9, 3175, 10.1002/pol.1971.150091108 Pittman, 1974, Copolymerization of vinylferrocene and N-vinylcarbazole. Conductivity studies of the trinitrofluorenone and mixed-valence [Fe(II), Fe(III)] complexes of these copolymers, J Appl Polym Sci, 18, 2269, 10.1002/app.1974.070180806 Lai, 1971, Free-radical homopolymerization and copolymerization of vinylferrocene, J Polym Sci A: Polym Chem, 9, 651, 10.1002/pol.1971.150090307 Pittman, 2005, The discovery of metallocene- and metallocene-like addition polymers, J Inorg Organomet Polym, 15, 33, 10.1007/s10904-004-2374-6 Pittman, 1970, Kinetics of ferrocenylmethyl acrylate and ferrocenylmethyl methacrylate polymerization. Preparation of polymeric ferricinium salts, Macromolecules, 3, 105, 10.1021/ma60013a024 Pittman, 1970, Polymerization of ferrocenylmethyl acrylate and ferrocenylmethyl methacrylate. Characterization of their polymers and their polymeric ferricinium salts. Extention to poly(ferrocenylethylene), Macromolecules, 3, 746, 10.1021/ma60018a007 Pittman, 1971, Organometellic polymers. X. Solution polymerization of 2-ferrocenylethyl acrylate and 2-ferrocenylethyl methacrylate, Macromolecules, 4, 291, 10.1021/ma60021a006 Nuyken, 1997, Anionic homo- and block copolymerization of vinylferrocene, Macromol Chem Phys, 198, 3353, 10.1002/macp.1997.021981102 Durkee, 2005, Catalysts from self-assembled organometallic block copolymers, Adv Mater, 17, 2003, 10.1002/adma.200500352 Durkee, 2007, Microstructure and solvent distribution in cross-linked diblock copolymer gels, Macromolecules, 40, 5103, 10.1021/ma0629485 Higashihara, 2007, Synthesis of novel block copolymers comprised of polyisobutylene and poly(vinylferrocene) segments, Macromolecules, 40, 7453, 10.1021/ma070903d Yan, 2008, Self organization and redox behavior of poly(vinylferrocene)-block-poly(isobutylene)-block-poly(vinylferrocene) triblock copolymer, J Macromol Sci A, 45, 910, 10.1080/10601320802380075 Gallei, 2010, Silacyclobutane-mediated re-activation of “sleeping” polyvinylferrocene macro-anions: a powerful access to novel metalloblock copolymers, Macromolecules, 43, 1844, 10.1021/ma902092j Kloninger, 2007, Styrene–ferrocenyldimethylsilane–methyl methacrylate triblock copolymers: synthesis and phase morphology, Macromol Chem Phys, 208, 833, 10.1002/macp.200600564 Kloninger, 2004, Microphase behaviour of ferrocenyldimethylsilane-b-methylmethacrylate diblock copolymers, Polymer, 45, 8323, 10.1016/j.polymer.2004.09.075 Kloninger, 2004, Bicontinuous gyroidic morphologies in ferrocenyldimethylsilane-b-methyl methacrylate diblock copolymer blends, Macromolecules, 37, 8319, 10.1021/ma0489321 Datta, 2004, Synthesis and self-assembly of styrene–[1]dimethylsilaferrocenophane–methyl methacrylate pentablock copolymers, Macromol Rapid Commun, 25, 1615, 10.1002/marc.200400241 Kloninger, 2004, 1,1-Dimethylsilacyclobutane-mediated living anionic block copolymerization of [1]dimethylsilaferrocenophane and methyl methacrylate, Macromolecules, 37, 1720, 10.1021/ma034909o Staff, 2012, Patchy nanocapsules of poly(vinylferrocene)-based block copolymers for redox-responsive release, ACS Nano, 6, 9042, 10.1021/nn3031589 Tonhauser, 2012, Water-soluble poly(vinylferrocene)-b-poly(ethylene oxide) diblock and miktoarm star polymers, Macromolecules, 45, 3409, 10.1021/ma3000048 Elbert, 2013, Reversible activity modulation of surface-attached grubbs second generation type catalysts using redox-responsive polymers, Macromolecules, 46, 4255, 10.1021/ma4007126 Baumert, 1999, Styrene-vinylferrocene random and block copolymers by TEMPO-mediated radical polymerization, Macromol Rapid Commun, 20, 203, 10.1002/(SICI)1521-3927(19990401)20:4<203::AID-MARC203>3.0.CO;2-I Shi, 2007, Reversible addition-fragmentation transfer polymerization of a novel monomer containing both aldehyde and ferrocene functional groups, Macromolecules, 40, 1891, 10.1021/ma062577s Xiao, 2010, Amphiphilic block copolymers with aldehyde and ferrocene-functionalized hydrophobic block and their redox-responsive micelles, J Mater Chem, 20, 8375, 10.1039/c0jm01453b Sakakiyama, 2005, Fabrication and electrochemical properties of high-density graft films with ferrocene moieties on ITO substrates, Chem Lett, 34, 1366, 10.1246/cl.2005.1366 Kim, 2009, Ferrocene functional polymer brushes on indium tin oxide via surface-initiated atom transfer radical polymerization, Langmuir, 26, 2083, 10.1021/la902590u Feng, 2009, Synthesis of well-defined amphiphilic graft copolymer bearing poly(2-acryloyloxyethyl ferrocenecarboxylate) side chains via successive SET-LRP and ATRP, J Polym Sci A: Polym Chem, 47, 4346, 10.1002/pola.23487 Zhai, 2012, Successive SET-LRP and ATRP synthesis of ferrocene-based PPEGMEA-g-PAEFC well-defined amphiphilic graft copolymer, J Polym Sci A: Polym Chem, 50, 811, 10.1002/pola.25836 Mazurowski, 2012, Redox-responsive polymer brushes grafted from polystyrene nanoparticles by means of surface initiated atom transfer radical polymerization, Macromolecules, 45, 8970, 10.1021/ma3020195 Hardy, 2011, Side-chain ferrocene-containing (meth)acrylate polymers: synthesis and properties, J Polym Sci A: Polym Chem, 49, 1409, 10.1002/pola.24561 Hardy, 2013, Self-assembly of well-defined ferrocene triblock copolymers and their template synthesis of ordered iron oxide nanoparticles, Chem Commun, 49, 4373, 10.1039/C2CC36756D Kim, 2004, Highly oriented and ordered arrays from block copolymers via solvent evaporation, Adv Mater, 16, 226, 10.1002/adma.200304906 Kim, 2004, Solvent-induced ordering in thin film diblock copolymer/homopolymer mixtures, Adv Mater, 16, 2119, 10.1002/adma.200306577 Gallei, 2009, Defined poly[styrene-block-(ferrocenylmethyl methacrylate)] diblock copolymers via living anionic polymerization, Macromol Rapid Commun, 30, 1463, 10.1002/marc.200900177 Gallei, 2010, Silacyclobutane-based diblock copolymers with vinylferrocene. ferrocenylmethyl methacrylate, and [1]dimethylsilaferrocenophane, Macromol Rapid Commun, 31, 889, 10.1002/marc.200900897 Albagli, 1992, Well-defined redox-active polymers and block copolymers prepared by living ring-opening metathesis polymerization, J Am Chem Soc, 114, 4150, 10.1021/ja00037a017 Albagli, 1993, Surface attachment of well-defined redox-active polymers and block polymers via terminal functional groups, J Am Chem Soc, 115, 7328, 10.1021/ja00069a035 Watson, 1998, Hybrid nanoparticles with block copolymer shell structures, J Am Chem Soc, 121, 462, 10.1021/ja983173l Watson, 2000, The synthesis and ring-opening metathesis polymerization of an amphiphilic redox-active norbornene, J Organomet Chem, 606, 79, 10.1016/S0022-328X(00)00097-8 Abd-El-Aziz, 2003, Organoiron polymers, Coord Chem Rev, 246, 3, 10.1016/S0010-8545(03)00107-3 Abd-El-Aziz, 2005, Macromolecules containing redox-active neutral and cationic iron complexes, Macromolecules, 38, 9411, 10.1021/ma051645s Abd-El-Aziz, 1998, Synthesis and characterization of novel organoiron polymers, J Inorg Organomet Polym, 8, 127, 10.1023/A:1022506807678 Abd-El-Aziz, 2001, Design of polyethers, thioethers, and amines with pendent iron moieties, J Polym Sci A: Polym Chem, 39, 1216, 10.1002/pola.1099 Abd-El-Aziz, 1998, Synthesis and structural characterization of cyclic aryl ethers, Chem Commun, 265, 10.1039/a704333c Abd-El-Aziz, 2002, Novel approach to oligomers and polymers containing neutral and cationic iron moieties within and pendent to their backbones, Macromol Rapid Commun, 23, 743, 10.1002/1521-3927(20020901)23:13<743::AID-MARC743>3.0.CO;2-K Abd-Ei-Aziz, 1996, Effect of ligand structure, solvent, and temperature on the electrochemical behavior of polyarene–iron complexes, Can J Chem, 74, 650, 10.1139/v96-070 Abd-El-Aziz, 2001, First ring-opening metathesis polymerization of norbornenes containing cationic iron moieties, J Polym Sci A: Polym Chem, 39, 2716, 10.1002/pola.1249 Abd-El-Aziz, 2000, Synthesis of substituted norbornenes and their polymerization to polynorbornenes with flexible aliphatic side-chains, Macromol Rapid Commun, 21, 598, 10.1002/1521-3927(20000601)21:9<598::AID-MARC598>3.0.CO;2-0 Abd-El-Aziz, 2006, Synthesis of norbornenes containing cationic mono- and di(cyclopentadienyliron)arene complexes and their ring-opening metathesis polymerization, J Polym Sci A: Polym Chem, 44, 3053, 10.1002/pola.21412 Abd-El-Aziz, 2010, Polynorbornenes containing ferrocene derivatives and alkyne-bis(tricarbonylcobalt), Macromol Rapid Commun, 31, 1992, 10.1002/marc.201000395 Connelly, 1996, Chemical redox agents for organometallic chemistry, Chem Rev, 96, 877, 10.1021/cr940053x Casado, 2000, Mixed ferrocene–cobaltocenium dendrimers: the most stable organometallic redox systems combined in a dendritic molecule, Angew Chem Int Ed, 39, 2135, 10.1002/1521-3773(20000616)39:12<2135::AID-ANIE2135>3.0.CO;2-R Whittell, 2007, Metallopolymers: new multifunctional materials, Adv Mater, 19, 3439, 10.1002/adma.200702876 Sheats, 1970, Synthesis and properties of cobalticinium salts. I. Synthesis of monosubstituted cobalticinium salts, J Org Chem, 35, 3245, 10.1021/jo00835a014 Carraher, 1974, Production of organometallic polymers by interfacial technique, 33. Synthesis of oligomeric cobalticinium containing dialkylstannanediyl polyesters, Makromol Chem, 175, 3089, 10.1002/macp.1974.021751105 Pittman, 1971, Organometallic polymers. IX. Polyesters of 1,1′-bis(chlorocarbonyl)cobalticinium hexafluorophosphate, Macromolecules, 4, 360, 10.1021/ma60021a025 Pittman, 1974, Organometallic polymers, 28 Condensation polymerization of cobalticinium salts, Makromol Chem, 175, 1427, 10.1002/macp.1974.021750507 Mayer, 2009, Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight. Water-soluble polycobaltocenium polyelectrolytes, J Am Chem Soc, 131, 10382, 10.1021/ja903513e Gilroy, 2011, Main-chain heterobimetallic block copolymers: synthesis and self-assembly of polyferrocenylsilane-b-poly(cobaltoceniumethylene), Angew Chem Int Ed, 50, 5851, 10.1002/anie.201008184 Ren, 2010, Synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers, J Am Chem Soc, 132, 8874, 10.1021/ja1037726 Ren, 2010, Preparation of side-chain 18-e cobaltocenium-containing acrylate monomers and polymers, Macromolecules, 43, 9304, 10.1021/ma101935a Ren, 2012, Preparation of cobaltocenium-labeled polymers by atom transfer radical polymerization, Macromolecules, 45, 2267, 10.1021/ma202725c Zhang, 2012, Cobaltocenium-containing methacrylate homopolymers. Block copolymers, and heterobimetallic polymers via RAFT polymerization, Macromolecules, 45, 6857, 10.1021/ma3012784 Ren, 2012, Cobaltocenium-containing block copolymers: ring-opening metathesis polymerization. Self-assembly and precursors for template synthesis of inorganic nanoparticles, Macromol Rapid Commun, 33, 510, 10.1002/marc.201100732 Ren, 2012, Preparation of cationic cobaltocenium polymers and block copolymers by “living” ring-opening metathesis polymerization, Chem Sci, 3, 580, 10.1039/C1SC00783A Zhang, 2013, Quantitative and qualitative counterion exchange in cationic metallocene polyelectrolytes, Macromolecules, 46, 1618, 10.1021/ma4000013 Zhang, 2013, Charged metallopolymers as universal precursors for versatile cobalt materials, Angew Chem Int Ed, 52, 13387, 10.1002/anie.201306432 Yan, 2013, Facile preparation of cobaltocenium-containing polyelectrolyte via click chemistry and RAFT polymerization, Macromol Rapid Commun, 35, 254, 10.1002/marc.201300558 Rapakousiou, 2013, ‘Click’ synthesis and redox properties of triazolyl cobalticinium dendrimers, Inorg Chem, 52, 6685, 10.1021/ic400747y Neuse, 1966, Metallocene polymers: XV. Polymers containing the ruthenocene system, J Organomet Chem, 6, 92, 10.1016/S0022-328X(00)83354-9 Neuse, 1968, Polymeric ferrocene and ruthenocene compounds with boron in the main chain, J Macromol Sci Chem, 2, 751, 10.1080/10601326808051439 Willis, 1984, Synthesis and characterization of polymers and copolymers of vinylruthenocene, J Polym Sci Polym Chem Ed, 22, 1077, 10.1002/pol.1984.170220508 Allcock, 1985, Ring-opening polymerization of metallocene cyclophosphazene derivatives, Macromolecules, 18, 1340, 10.1021/ma00148a051 Allcock, 1987, Polymerization of new metallocenylphosphazenes, Macromolecules, 20, 6, 10.1021/ma00167a002 Buchmeiser, 1995, Synthesis of polyenes that contain metallocenes via the living polymerization of ethynylferrocene and ethynylruthenocene, Macromolecules, 28, 6642, 10.1021/ma00123a034 Yan, 2013, Ruthenocene-containing homopolymers and block copolymers via ATRP and RAFT Polymerization, Macromolecules, 46, 8816, 10.1021/ma402039u Sheats, 1985, Use of organometallic polymers for pre-heat shields for targets in inertial-confinement nuclear fusion, 83 Chan, 2003, Toward highly metallized polymers: synthesis and characterization of silicon-bridged [1]ferrocenophanes with pendent cluster substituents, Organometallics, 22, 3796, 10.1021/om030352p Berenbaum, 2003, Ceramics containing magnetic Co–Fe alloy nanoparticles from the pyrolysis of a highly metallized organometallic polymer precursor, Adv Mater, 15, 51, 10.1002/adma.200390009 Berenbaum, 2002, Synthesis, characterization, and the platinum-catalyzed ring-opening polymerization and stereoselective dimerization of silicon-bridged [1]ferrocenophanes with acetylenic substituents, Organometallics, 21, 4415, 10.1021/om0204078 Liu, 2006, Pyrolysis of highly metallized polymers: ceramic thin films containing magnetic CoFe alloy nanoparticles from a polyferrocenylsilane with pendant cobalt clusters, Chem Mater, 18, 2591, 10.1021/cm052339w Clendenning, 2004, Magnetic ceramic films from a metallopolymer resist using reactive ion etching in a secondary magnetic field, Adv Mater, 16, 291, 10.1002/adma.200306262 Cheng, 2004, UV photopatterning of a highly metallized, cluster-containing poly(ferrocenylsilane), Chem Commun, 780, 10.1039/b316656b Chan, 2005, Highly metallized polymers: synthesis, characterization, and lithographic patterning of polyferrocenylsilanes with pendant cobalt, molybdenum, and nickel cluster substituents, J Am Chem Soc, 127, 1765, 10.1021/ja045386i Chan, 2007, Synthesis, characterization, and photocontrolled ring-opening polymerization of Sila[1]ferrocenophanes with multiple alkyne substituents, Organometallics, 26, 1217, 10.1021/om060767l Tanabe, 2006, Photocontrolled living polymerizations, Nat Mater, 5, 467, 10.1038/nmat1649 Chabanne, 2011, Organic-metalloblock copolymers via photocontrolled living anionic ring-opening polymerization, Polym Chem, 2, 2651, 10.1039/c1py00298h Friebe, 2007, Pyrolysis of polycarbosilanes with pendant nickel clusters: synthesis and characterization of magnetic ceramics containing nickel and nickel silicide nanoparticles, Chem Mater, 19, 2630, 10.1021/cm062470j Greenberg, 2005, Synthesis and lithographic patterning of polycarbosilanes with pendant cobalt carbonyl clusters, Macromolecules, 38, 2023, 10.1021/ma048368u Pittman, 1973, Organometallic polymers. XXIV. Synthesis and copolymerization behavior of H6-(2-phenylethyl acrylate) tricarbonylchromium, J Polym Sci Polym Chem Ed, 11, 2753, 10.1002/pol.1973.170111104 Macomber, 1982, A new, general route to.eta.5-vinylcyclopentadienyl organometallic monomers, J Am Chem Soc, 104, 884, 10.1021/ja00367a055 Pittman, 1973, Organometallic polymers. XXVII. Radical-initiated polymerization and copolymerization of π-(2,4-hexadien-1-yl acrylate) tricarbonyliron, J Macromol Sci Chem, 7, 1563, 10.1080/00222337308066374 Pittman, 1974, Functionalization of polymers via π-allyliron tetracarbonyl cations, Macromolecules, 7, 396, 10.1021/ma60039a025 Mîinea, 2004, Phenylethynylstyrene–cobalt carbonyl block copolymer composites, Macromolecules, 37, 8967, 10.1021/ma0490092 Sessions, 2005, Alkyne-functional homopolymers and block copolymers through nitroxide-mediated free radical polymerization of 4-(phenylethynyl)styrene, Macromolecules, 38, 2116, 10.1021/ma048793n Al-Badri, 2008, Well-defined acetylene-functionalized oxanorbornene polymers and block copolymers, Macromolecules, 41, 4173, 10.1021/ma8004179 Al-Badri, 2011, Room temperature magnetic materials from nanostructured diblock copolymers, Nat Commun, 2, 482, 10.1038/ncomms1485 Zha, 2013, Magnetic properties of cobalt-containing diblock copolymers with cylindrical morphology of different domain sizes, J Inorg Organomet Polym, 23, 89, 10.1007/s10904-012-9744-2 Zha, 2012, Nanostructured block-random copolymers with tunable magnetic properties, J Am Chem Soc, 134, 14534, 10.1021/ja305249b Happ, 2012, Photogenerated avenues in macromolecules containing Re(I), Ru(II), Os(II), and Ir(III) metal complexes of pyridine-based ligands, Chem Soc Rev, 41, 2222, 10.1039/C1CS15154A Marin, 2007, Functional ruthenium(II)- and iridium(III)-containing polymers for potential electro-optical applications, Chem Soc Rev, 36, 618, 10.1039/B610016C Schubert, 2002, Macromolecules containing bipyridine and terpyridine metal complexes: towards metallosupramolecular polymers, Angew Chem Int Ed, 41, 2892, 10.1002/1521-3773(20020816)41:16<2892::AID-ANIE2892>3.0.CO;2-6 Chan, 2007, Metal containing polymers with heterocyclic rigid main chains, Coord Chem Rev, 251, 2104, 10.1016/j.ccr.2007.03.002 Ho, 2011, Metal-containing polymers: facile tuning of photophysical traits and emerging applications in organic electronics and photonics, Coord Chem Rev, 255, 2469, 10.1016/j.ccr.2011.01.052 Shunmugam, 2010, Metal–ligand-containing polymers: terpyridine as the supramolecular unit, Macromol Rapid Commun, 31, 784, 10.1002/marc.200900869 Juris, 1988, Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence, Coord Chem Rev, 84, 85, 10.1016/0010-8545(88)80032-8 Wu, 2001, Ruthenium tris(bipyridine)-centered linear and star-shaped polystyrenes: making atom transfer radical polymerization and metal complex initiators compatible, Macromolecules, 34, 2812, 10.1021/ma001745s Fleming, 2001, Ultrafast excited-state energy migration dynamics in an efficient light-harvesting antenna polymer based on Ru(II) and Os(II) polypyridyl complexes, J Am Chem Soc, 123, 10336, 10.1021/ja016304i Strouse, 1989, Long-range energy transfer in a soluble polymer by an energy-transfer cascade, J Am Chem Soc, 111, 9101, 10.1021/ja00207a017 Marin, 2004, Polymeric ruthenium bipyridine complexes: new potential materials for polymer solar cells, J Polym Sci A: Polym Chem, 42, 374, 10.1002/pola.11024 Aamer, 2004, Synthesis of terpyridine-containing polymers with blocky architectures, Macromolecules, 37, 1990, 10.1021/ma0352375 Aamer, 2007, Supramolecular polymers containing terpyridine–metal complexes in the side chain, Macromolecules, 40, 2737, 10.1021/ma062765i Aamer, 2008, Diblock copolymers containing metal complexes in the side chain of one block, Macromolecules, 41, 2022, 10.1021/ma071531b Qin, 2008, Tris(1-pyrazolyl)borate (scorpionate) functionalized polymers as scaffolds for metallopolymers, Macromolecules, 41, 2972, 10.1021/ma800310v Tzanetos, 2005, Side-chain terpyridine polymers through atom transfer radical polymerization and their ruthenium complexes, J Polym Sci A: Polym Chem, 43, 4838, 10.1002/pola.20950 Stefopoulos, 2009, Carbon nanotubes decorated with terpyridine-ruthenium complexes, J Polym Sci A: Polym Chem, 47, 2551, 10.1002/pola.23339 Sun, 2012, Light harvesting arrays of polypyridine ruthenium(II) chromophores prepared by reversible addition-fragmentation chain transfer polymerization, Macromolecules, 45, 2632, 10.1021/ma202804u Holder, 2003, New soluble functional polymers by free-radical copolymerization of methacrylates and bipyridine ruthenium complexes, J Polym Sci A: Polym Chem, 41, 3954, 10.1002/pola.10959 Serin, 2002, Synthesis and study of the absorption and luminescence properties of polymers containing Ru(BpyMe2)32+ chromophores and coumarin laser dyes, Macromolecules, 35, 5396, 10.1021/ma020265t Schultze, 2001, Light harvesting and energy transfer in a ruthenium-coumarin-2 copolymer, Chem Commun, 1160, 10.1039/b103792g Carlise, 2004, Side-chain functionalized polymers containing bipyridine coordination sites: polymerization and metal-coordination studies, J Polym Sci A: Polym Chem, 42, 2973, 10.1002/pola.20134 Chen, 2004, Ruthenium bipyridine-containing polymers and block copolymers via ring-opening metathesis polymerization, Macromolecules, 37, 5866, 10.1021/ma049450s Metera, 2007, Luminescent vesicles, tubules, bowls, and star micelles from ruthenium–bipyridine block copolymers, Macromolecules, 40, 3733, 10.1021/ma0623789 Chen, 2005, Biotin-terminated ruthenium bipyridine ring-opening metathesis polymerization copolymers: synthesis and self-assembly with streptavidin, Macromolecules, 38, 1084, 10.1021/ma0478714 Sankaran, 2010, Ring-opening metathesis polymers for biodetection and signal amplification: synthesis and self-assembly, Macromolecules, 43, 5530, 10.1021/ma100234j Happ, 2009, Click chemistry meets polymerization: controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization, Eur Polym J, 45, 3433, 10.1016/j.eurpolymj.2009.09.010 Happ, 2011, Synthesis and resonance energy transfer study on a random terpolymer containing a 2-(pyridine-2-yl)thiazole donor-type ligand and a luminescent [Ru(bpy)2(2-(triazol-4-yl)pyridine)]2+ chromophore, Macromolecules, 44, 6277, 10.1021/ma201193e Zha, 2012, Metal-cation-based anion exchange membranes, J Am Chem Soc, 134, 4493, 10.1021/ja211365r Baranoff, 2004, From ruthenium(II) to iridium(III): 15 years of triads based on bis-terpyridine complexes, Chem Soc Rev, 33, 147, 10.1039/b308983e Collin, 1999, Synthesis and photophysical properties of iridium(III) bisterpyridine and its homologues: a family of complexes with a long-lived excited state, J Am Chem Soc, 121, 5009, 10.1021/ja9833669 Adachi, 2000, High-efficiency organic electrophosphorescent devices with tris(2-phenylpyridine)iridium doped into electron-transporting materials, Appl Phys Lett, 77, 904, 10.1063/1.1306639 Adachi, 2001, Nearly 100% internal phosphorescence efficiency in an organic light-emitting device, J Appl Phys, 90, 5048, 10.1063/1.1409582 Aamer, 2007, Synthesis, dynamic light scattering, and luminescence properties of copolymers containing iridium(III) bisterpyridine in the side chain, J Polym Sci A: Polym Chem, 45, 1109, 10.1002/pola.21875 Ott, 2012, Metallo-supramolecular materials based on amine-grafting onto polypentafluorostyrene, Macromol Rapid Commun, 33, 556, 10.1002/marc.201100769 Ulbricht, 2008, Copolymers containing phosphorescent iridium(III) complexes obtained by free and controlled radical polymerization techniques, Macromol Rapid Commun, 29, 1919, 10.1002/marc.200800561 Carlise, 2005, Phosphorescent side-chain functionalized poly(norbornene)s containing iridium complexes, Macromolecules, 38, 9000, 10.1021/ma0512298 Metera, 2012, Luminescent iridium(III)-containing block copolymers: self-assembly into biotin-labeled micelles for biodetection assays, ACS Macro Lett, 1, 954, 10.1021/mz3001644 Poulsen, 2010, Site isolation in phosphorescent bichromophoric block copolymers designed for white electroluminescence, Adv Mater, 22, 77, 10.1002/adma.200901453 Kido, 2002, Organo lanthanide metal complexes for electroluminescent materials, Chem Rev, 102, 2357, 10.1021/cr010448y Tsukube, 2002, Lanthanide complexes in molecular recognition and chirality sensing of biological substrates, Chem Rev, 102, 2389, 10.1021/cr010450p Binnemans, 2009, Lanthanide-based luminescent hybrid materials, Chem Rev, 109, 4283, 10.1021/cr8003983 Shunmugam, 2005, Efficient route to well-characterized homo, block, and statistical polymers containing terpyridine in the side chain, J Polym Sci A: Polym Chem, 43, 5831, 10.1002/pola.21102 Shunmugam, 2005, Unique emission from polymer based lanthanide alloys, J Am Chem Soc, 127, 13567, 10.1021/ja053048r Li, 2012, Macromolecular ligands for gadolinium MRI contrast agents, Macromolecules, 45, 4196, 10.1021/ma300521c Breul, 2013, Incorporation of polymerizable osmium(II) bis-terpyridine complexes into PMMA backbones, J Inorg Organomet Polym, 23, 74, 10.1007/s10904-012-9709-5 Tse, 2005, Synthesis and characterization of random and block copolymers with pendant rhenium diimine complexes by controlled radical polymerization, J Polym Sci A: Polym Chem, 43, 1292, 10.1002/pola.20587 Tam, 2009, Multifunctional poly(N-vinylcarbazole)-based block copolymers and their nanofabrication and photosensitizing properties, Macromol Rapid Commun, 30, 622, 10.1002/marc.200800714 Furuta, 2004, Platinum-functionalized random copolymers for use in solution-processible, efficient, near-white organic light-emitting diodes, J Am Chem Soc, 126, 15388, 10.1021/ja0446247 Pollino, 2003, Living ROMP of exo-norbornene esters possessing PdII SCS pincer complexes or diaminopyridines, Macromolecules, 36, 2230, 10.1021/ma025873n Nair, 2006, Noncovalently functionalized block copolymers possessing both hydrogen bonding and metal coordination centers, Macromolecules, 39, 931, 10.1021/ma052222t Pollino, 2003, One-step multifunctionalization of random copolymers via self-assembly, J Am Chem Soc, 126, 563, 10.1021/ja0372715 Meyers, 2004, Design, synthesis, characterization, and fluorescent studies of the first zinc-quinolate polymer, Chem Commun, 1176, 10.1039/b402289k Kaminsky, 1998, Highly active metallocene catalysts for olefin polymerization, J Chem Soc Dalton Trans, 1413, 10.1039/a800056e Brintzinger, 1995, Stereospecific olefin polymerization with chiral metallocene catalysts, Angew Chem Int Ed, 34, 1143, 10.1002/anie.199511431 Heurtefeu, 2011, Polymer support of “single-site” catalysts for heterogeneous olefin polymerization, Prog Polym Sci, 36, 89, 10.1016/j.progpolymsci.2010.09.002 Britovsek, 1999, The search for new-generation olefin polymerization catalysts: life beyond metallocenes, Angew Chem Int Ed, 38, 428, 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO;2-3 Stanley, 2012, Luminescent lanthanide-containing metallopolymers, Coord Chem Rev, 256, 1520, 10.1016/j.ccr.2012.03.046 Neuse, 2005, Macromolecular ferrocene compounds as cancer drug models, J Inorg Organomet Polym, 15, 3, 10.1007/s10904-004-2371-9 Gasser, 2010, Organometallic anticancer compounds, J Med Chem, 54, 3, 10.1021/jm100020w Zhang, 2014, Antimicrobial metallopolymers and their bioconjugates with antibiotics against multidrug resistant bacteria, J Am Chem Soc, 136, 4873, 10.1021/ja5011338