Metal-organic frameworks based on monodisperse palladium cobalt nanohybrids as highly active and reusable nanocatalysts for hydrogen generation

B. Şen, A. Aygün, Aysun Şavk, S. Akocak, F. Şen, Bimetallic palladium-iridium alloy nanoparticles as highly efficient and stable catalyst for the hydrogen evolution reaction, Int J Hydrogen Energy, DOI:10.1016/j.ijhydene.2018.07.081. Astruc, 2005, Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis, Angew Chem Int Ed, 44, 7852, 10.1002/anie.200500766 Sen, 2018, Highly efficient polymer supported monodisperse ruthenium-nickel nanocomposites for dehydrocoupling of dimethylamine borane, J Colloid Interface Sci, 526, 480, 10.1016/j.jcis.2018.05.021 Günbatar, 2018, Carbon-nanotube-based rhodium nanoparticles as highly-active catalyst for hydrolytic dehydrogenation of dimethylamineborane at room temperature, J Colloid Interface Sci, 530, 321, 10.1016/j.jcis.2018.06.100 Grunes, 2003, Catalysis and nanoscience, Chem Commun, 0, 2257, 10.1039/b305719b Li, 2015, Facile synthesis of AgAuPd/graphene with high performance for hydrogen generation from formic acid, J Mater Chem A, 3, 14535, 10.1039/C5TA03111G Yan, 2012, Rapid and energy-efficient synthesis of a graphene–CuCo hybrid as a high performance catalyst, J Mater Chem, 22, 10990, 10.1039/c2jm31042b Yan, 2018, Anchoring and upgrading ultrafine NiPd on room-temperature-synthesized bifunctional NH2-N-rGO toward low-cost and highly efficient catalysts for selective formic acid dehydrogenation, Adv Mater, 30, 1703038, 10.1002/adma.201703038 Yan, 2015, AuPd–MnOx/MOF–Graphene: an efficient catalyst for hydrogen production from formic acid at room temperature, Adv. Energy Mater, 5, 1500107, 10.1002/aenm.201500107 Lee, 2009, Metal-organic framework materials as catalysts, Chem Soc Rev, 38, 1450, 10.1039/b807080f Farrusseng, 2009, Metal-organic frameworks: opportunities for catalysis, Angew Chem Int Ed, 48, 7502, 10.1002/anie.200806063 Corma, 2010, Engineering metal-organic frameworks for heterogeneous catalysis, Chem Rev, 110, 4606, 10.1021/cr9003924 Dhakshinamoorthy, 2012, Catalysis by metal nanoparticles embedded on metal-organic frameworks, Chem Soc Rev, 41, 5262, 10.1039/c2cs35047e Alcaniz, 2012, Metal-organic frameworks as scaffolds for the encapsulation of active species: state of the art and future perspectives, J Mater Chem, 22, 10102, 10.1039/c2jm15563j Cevik, 2007, A novel three dimensional organic-inorganic hybrid BasedPorous phase: synthesis and characterization of reduced oxovanadium pyromellitate, [VIV2O2(H2O)2(C6H2(COO)4)], Chem Crystallogr, 37, 497, 10.1007/s10870-007-9203-z Staubitz, 2010, Ammonia-borane and related compounds as dihydrogen sources, Chem Rev, 110, 4079, 10.1021/cr100088b Staubitz, 2010, Amine- and phosphine-borane adducts: new interest in old molecules, Chem Rev, 110, 4023, 10.1021/cr100105a Pun, 2007, Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N2 complexes, Chem Commun, 0, 3297, 10.1039/b704941b Aijaz, 2012, Immobilizing highly catalytically active Pt nanoparticles inside the pores of the metal-organic framework: a double solvents approach, J Am Chem Soc, 134, 13926, 10.1021/ja3043905 Li, 2012, Hydrogen production from NaBH4 hydrolysis via Co-ZIF-9 catalyst, Fuel Process Technol, 100, 43, 10.1016/j.fuproc.2012.03.007 Srinivas, 2013, Nanoconfined ammonia borane in a flexible metal-organic framework Fe–MIL-53: clean hydrogen release with fast kinetics, Int J Mater Chem A, 1, 4167, 10.1039/c3ta00037k Srinivas, 2012, Zn-MOF assisted dehydrogenation of ammonia borane: enhanced kinetics and clean hydrogen generation, Int J Hydrogen Energy, 37, 3633, 10.1016/j.ijhydene.2011.04.008 Çelik, 2016, Monodisperse palladium-cobalt alloy nanoparticles assembled on poly (N-vinyl-pyrrolidone) (PVP) as highly effective catalyst for the dimethylamine borane (DMAB) dehydrocoupling, RSC Adv, 6, 24097, 10.1039/C6RA00536E Wang, 2013, Au@Pd core–shell nanoclusters growing on nitrogen-doped mildly reduced graphene oxide with enhanced catalytic performance for hydrogen generation from formic acid, J Mater Chem A, 1, 12721, 10.1039/c3ta12531a Wang, 2013, An efficient CoAuPd/C catalyst for hydrogen generation from formic acid at room temperature, Angew Chem Int Ed Engl, 52, 4406, 10.1002/anie.201301009 Hagen, 2005, Is it homogeneous or heterogeneous catalysis? Compelling evidence for both types of catalysts derived from [Rh(eta5-C5Me5)Cl2]2 as a function of temperature and hydrogen pressure, J Am Chem Soc, 127, 4423, 10.1021/ja044154g Watzky, 1997, Transition metal nanocluster formation kinetic and mechanistic studies. A new mechanism when hydrogen is the Reductant:  slow, continuous nucleation and fast autocatalytic surface growth, J Am Chem Soc, 119, 10382, 10.1021/ja9705102 Zahmakiran, 2009, Dimethylammonium hexanoate stabilized rhodium(0) nanoclusters identified as true heterogeneous catalysts with the highest observed activity in the dehydrogenation of Dimethylamine−Borane, Inorg Chem, 48, 8955, 10.1021/ic9014306 Jaska, 2004, Heterogeneous or homogeneous catalysis? Mechanistic studies of the rhodium-catalyzed dehydrocoupling of amine-borane and phosphine-borane adducts, J Am Chem Soc, 126, 9776, 10.1021/ja0478431 Sloan, 2009, Homogeneous catalytic dehydrogenation/dehydrocoupling of amine-borane adducts by the Rh(I) Wilkinson's complex analogue RhCl(PHCy2)3 (cy = cyclohexyl), Inorg Chem, 48, 2429, 10.1021/ic801752k Friedrich, 2009, Ruthenium-catalyzed dimethylamineborane dehydrogenation: stepwise metal-centered dehydrocyclization, Chem Eur J, 15, 10339, 10.1002/chem.200901372 Keaton, 2007, Base metal catalyzed dehydrogenation of Ammonia−Borane for chemical hydrogen storage, J Am Chem Soc, 129, 1184, 10.1021/ja066860i Kawano, 2009, Dehydrocoupling reactions of Borane−Secondary and −Primary amine adducts catalyzed by group-6 carbonyl complexes: formation of aminoboranes and borazines, J Am Chem Soc, 131, 14946, 10.1021/ja904918u Chandra, 2006, A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia-borane, J Power Sources, 156, 190, 10.1016/j.jpowsour.2005.05.043 Sloan, 2010, Homogeneous catalytic dehydrocoupling/dehydrogenation of amine-borane adducts by an early transition metal, group 4 metallocene complexes, J Am Chem Soc, 132, 3831, 10.1021/ja909535a Sen, 2014, Amylamine stabilized platinum (0) nanoparticles: active and reusable nanocatalyst in the room temperature dehydrogenation of dimethylamine-borane, RSC Adv, 4, 1526, 10.1039/C3RA43701A Robertson, 2011, Heterogeneous dehydrocoupling of amine-borane adducts by skeletal nickel catalysts, Inorg Chem, 50, 12680, 10.1021/ic201809g Jaska, 2003, Transition metal-catalyzed formation of boron-nitrogen bonds: catalytic dehydrocoupling of amine-borane adducts to form amino boranes and borazines, J Am Chem Soc, 125, 9424, 10.1021/ja030160l Li, 2015, Polymeric micelle assembly for the smart synthesis of mesoporous platinum nanospheres with tunable pore sizes, Angew Chem Int Ed, 54, 11073, 10.1002/anie.201505232 Erken, 2016, New Pt(0) nanoparticles as highly active and reusable catalysts in the C1–C3 alcohol oxidation and the room temperature dehydrocoupling of dimethylamine-borane (DMAB), J Cluster Sci, 27, 9, 10.1007/s10876-015-0892-8 Li, 2013, Electrochemical synthesis of one-dimensional mesoporous Pt nanorods using the assembly of surfactant micelles in confined space, Angew Chem, 31, 8050, 10.1002/anie.201303035 Sen, 2017, Hydrogen liberation from the dehydrocoupling of dimethylamine-borane at room temperature by using novel and highly monodispersed RuPtNi nanocatalysts decorated with graphene oxide, Int J Hydrogen Energy, 42, 23299, 10.1016/j.ijhydene.2017.04.213 Sen, 2017, Highly monodisperse RuCo nanoparticles decorated on functionalized multiwalled carbon nanotube with the highest observed catalytic activity in the dehydrogenation of dimethylamine borane, Int J Hydrogen Energy, 42, 23292, 10.1016/j.ijhydene.2017.06.032 Sen, 2017, Highly efficient catalytic dehydrogenation of dimethyl ammonia borane via monodisperse palladium-nickel alloy nanoparticles assembled on PEDOT, Int J Hydrogen Energy, 42, 23307, 10.1016/j.ijhydene.2017.05.115 Sen, 2017, Polymer-Graphene hybrid decorated Pt Nanoparticles as highly efficient and reusable catalyst for the Dehydrogenation of Dimethylamine-borane at room temperature, Int J Hydrogen Energy, 42, 23284, 10.1016/j.ijhydene.2017.05.112 Sen, 2017, Monodisperse palladium-nickel alloy nanoparticles assembled on graphene oxide with the high catalytic activity and reusability in the dehydrogenation of dimethylamine-borane, Int J Hydrogen Energy, 42, 23276, 10.1016/j.ijhydene.2017.05.113 B. Sen, A. Aygun, T.O. Okyay, A. Savk, R. Kartop, F. Sen, A Monodisperse palladium nanoparticles assembled on graphene oxide with the high catalytic activity and reusability in the dehydrogenation of dimethylamine-borane, Int J Hydrogen Energy, DOI:10.1016/j.ijhydene.2018.03.175 Sen, 2018, Highly efficient monodisperse nanoparticles confined in the carbon black hybrid material for hydrogen liberation, J Colloid Interface Sci, 520, 112, 10.1016/j.jcis.2018.03.004