Metal (Co, Mn)-amine-functionalized mesoporous silica SBA-15: synthesis, characterization and catalytic properties in hydroxylation of benzene

Springer Science and Business Media LLC - Tập 18 - Trang 475-482 - 2010
Roozbeh Javad Kalbasi1, Ahmad Reza Massah1, Farzad Zamani1, Alex D. Bain2, Bob Berno2
1Department of Chemistry, Islamic Azad University, Shahreza, Iran
2Department of Chemistry, McMaster University, Hamilton, Canada

Tóm tắt

Mesoporous silica SBA-15 was synthesized using H3PO4 and functionalized with ethylendiaminopropyltrimethoxysilane (H2N–(CH2)2–NH–(CH2)3–) by grafting method. A variety of transition metals such as Co and Mn have been coordinated with amine-functionalized silica SBA-15. The materials have been characterized by XRD, FT-IR, BET, TGA, 13C-NMR, DR UV–Vis, atomic absorption spectroscopy (AAS) and back titration using NaOH (0.1 N). The catalytic performance of obtained catalyst was determined for hydroxylation of benzene using H2O2 as oxidant in the presence of O2 atmosphere. At optimized conditions, the Mn-amine-functionlized mesoporous silica SBA-15 exhibited high catalytic activity at room temperature in the absence of solvent.

Tài liệu tham khảo

C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Nature. 359, 710 (1992)

P.T. Tanev, T.J. Pinnavaia, Science. 267, 865 (1995)

S.A. Bagshaw, E. Prouzet, T.J. Pinnavaia, Science. 269, 1242 (1995)

D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredickson, B.F. Chmelka, G.D. Stucky, Science. 279, 548 (1998)

A. Stein, B.J. Melde, R.C. Schroden, Adv. Mater. 12, 1403 (2000)

A. Vinu, K.Z. Hossain, K. Ariga, J. Nanosci. Nanotechnol. 5, 347 (2005)

D. Zhao, Q. Huo, J. Feng, B.F. Chmelka, G.D. Stucky, J. Am. Chem. Soc. 120, 6024 (1998)

M. Colilla, F. Balas, M. Manzano, M. Vallet-Regí. Chem. Mater. 19, 3099 (2007)

T. Mizuno, H. Yamada, T. Tagawa, S. Goto, J. Chem. Eng. Jpn 38, 849 (2005)

A. Germain, M. Allian, F. Figueras, Catal. Today 32, 145 (1996)

B. Chou, J.L. Tsai, S. Cheng, Micropor. Mesopor. Mater. 48, 309 (2001)

Y.K. Masumoto, R. Hamada, K. Yokota, S. Nishiyama, S. Tsuruya, J. Mol. Catal. A: 184, 215 (2002)

T. Miyahara, H. Kanzaki, R. Hamada, S. Kuroiwa, S. Nishiyama, S. Tsuruya, J. Mol. Catal. A: 176, 141 (2001)

H. Kanzaki, T. Kitamura, R. Hamada, S. Nishiyama, S. Tsuruya, J. Mol. Catal. A: 208, 203 (2004)

J.S. Choi, T.H. Kim, M.B. Saidutta, J.S. Sung, K.I. Kim, R.V. Jasra, S.D. Song, Y.W. Rhee, J. Ind. Eng. Chem. 10, 445 (2004)

V. Parvulescu, B.L. Su, Catal. Today. 69, 315 (2001)

R. Dimitrova, M. Spassova, Catal. Commun. 8, 693 (2007)

Z. Mua, J.J. Li, H. Tian, Z.P. Hao, S.Z. Qiao, Mater. Res. Bull. 43, 2599 (2008)

M. Stockmann, F. Konietzni, J.U. Notheis, Appl. Catal. A: 208, 343 (2001)

D. Andreeva, T. Tabakova, L. Ilieva, A. Naydenov, D. Mehanjiev, M.V. Abrashev, Appl. Catal. A: Gen. 209, 291 (2001)

J.S. Choi, T.H. Kim, M.B. Saidutta, J.S. Sung, K.I. Kim, R.V. Jasra, S.D. Song, Y.W. Rhee, J. Ind. Eng. Chem. 10, 445 (2004)

J.S. Choi, T.H. Kim, K.Y. Choo, J.S. Sung, M.B. Saidutta, S.O. Ryu, S.D. Song, B. Ramachandra, Y.W. Rhee, Appl. Catal. A: 290, 1 (2005)

J. Zhang, Y. Tang, G. Li, C. Hu, Appl. Catal. A: 278, 251 (2005)

Y.J. Seo, Y. Mukai, T. Tagawa, S. Goto, J. Mol. Catal. A: 120, 149 (1997)

J. Aguado, J.M. Arsuaga, A. Arencibia, M. Lindo, V. Gascόn, J. Hazard. Mater. 163, 213 (2009)

G.H. Hu, W.J. Ruan, Y.L. Zhang, H. Han, Z.A. Zhu, Acta Phys. Chin. Sin. 19, 320 (2003)

A.G.S. Prado, C. Airoldi, J. Coll. Inter. Science 236, 161 (2001)

R.B. Hernández, O.R. Yolac, A.L.R. Mercê, J. Braz. Chem. Soc. 18, 1388 (2007)

K.M. Parida, D. Rath, Appl. Catal. A: 321, 101 (2007)

L.N. Franco, I.H. Perez, J.A. Pliego, A.M. Franco, Catal. Today 75, 189 (2002)

G. Goor, J. Edwards, R. Curu, in Catalytic Oxidations with Hydrogen Peroxide as Oxidant, 50, ed. by G. Strukul (Kluwer Academic Publishers, Dordrecht, 1993), p. 423

Thông tin
Thông tin xuất bản

Springer Science and Business Media LLC

Tập 18

475-482

Thông tin tác giả