Metakaolin and calcined clays as pozzolans for concrete: a review

Cement and Concrete Composites - Tập 23 Số 6 - Trang 441-454 - 2001
B. B. Sabir1, S. Wild1, J. Bai1
1School of Technology, University of Glamorgan, Pontypridd, Mid. Glamorgan, Wales CF37 1DL, UK

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Mehta PK. Role of cementitious material in sustainable development of the concrete industry. In: Proceedings of the Sixth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, vol. 1, SP-178. Bangkok: V.M. Malhotra; May 1998. p. 1–20

Concrete Society. Changes in the properties of ordinary portland cement. Technical report 29; 1987. p. 1–30

Stanley CC. The history of concrete. Cement and Concrete Association. Wexham Springs, UK, ISBN 0 7210 1156 X; 1979. p. 3–9

Mehta PK. Supplementary cementing materials for concrete. V.M. Malhotra, CANMET (Sp-86-8E); 1987

Malinowski R. Concrete and mortar in ancient aqueducts. Concrete Int 1979:66–76

Mielenz RC. Mineral admixtures – history and background. Concrete Int 1983:34–42

Lea, 1970

Baronio G, Binda L. Study of the pozzolanicity of some bricks and clays. In: Proceedings of the 10th International Building Materials Conference. Calgary; July 1994. p. 1189–97

Teutonico JM, McCaig I, Burns C, Ashhurst J. Factors affecting the properties of lime-based mortars for use in the repair and conservation of historic buildings. English Heritage, The Smeaton Project, Research Project ACI: Phase I Report, Published by English Heritage, Architectural Conservation Branch, Science and Conservation Division, March 1994

Copernicus Research Project. Recycling of waste clay brick and tile material for the partial replacement of cement in concrete. Research contract No. CIPA-CT94-0211, First annual report, 1996, Second annual report, 1997 and Third annual report, 1998

Saad MNA, de Andrade WP, Paulton VA. Properties of mass concrete containing active pozzolan made from clay. Concrete Int July 1982:59–65

Brindley, 1959, The kaolinite-mullite reaction series: I, Survey of outstanding problems, J. Am. Ceram. Soc., 42, 311, 10.1111/j.1151-2916.1959.tb14314.x

Brindley, 1959, The kaolinite-mullite reaction series: II, Metakolin, J. Am. Ceram. Soc., 42, 314, 10.1111/j.1151-2916.1959.tb14315.x

Brindley, 1959, The kaolinite-mullite reaction series: III, High temperature phases, J. Am. Ceram. Soc., 42, 3319, 10.1111/j.1151-2916.1959.tb14316.x

Sayanam, 1989, Studies on thermal transformations and pozzolanic activities of clay from Jammu region (India), J. Thermal Analysis, 35, 9, 10.1007/BF01914268

Ambroise, 1986, Investigations on synthetic binders obtained by middle-temperature thermal dissociation of clay minerals, Silicates Industries, 7, 99

Pera, 1998, Pozzolanic activity of calcined laterite, Silicates Industries, Ceram. Sci. Technol., 63, 107

Malquori G, Portland-pozzolan cement. In: Proceedings of the Fourth International Symposium on Chemistry of Cement. Washington DC; 1960. p. 983–88

Turrizani R. The chemistry of cement, vol. 2. H.F.W. Taylor; 1964. p. 69–86

DeSilva, 1990, Hydration of cements based on metakaolin: thermochemistry, Adv. Cement Chem., 3, 167, 10.1680/adcr.1990.3.12.167

Dunster, 1993, The pozzolanic reaction of metakaolin and its effects on PC hydration, J. Mater. Sci., 28, 1345, 10.1007/BF01191976

Wild, 1998, Chemical and autogenous shrinkage of Portland cement-metakaolin pastes, Adv. Cement Res., 10, 109, 10.1680/adcr.1998.10.3.109

Murat, 1983, Hydration reaction and hardening of calcined clays and related minerals, Cement Concrete Res., 13, 259, 10.1016/0008-8846(83)90109-6

Kinuthia, 2000, Self-compensating autogenous shrinkage in Portland cement-metakaolin-fly ash pastes, Adv. Cement Res., 12, 35, 10.1680/adcr.2000.12.1.35

Khatib JM, Sabir BB, Wild S. Some properties of metakaolin paste and mortar. In: Dhir RK, Dyer TD, editors. International Congress, Concrete in the Service of Mankind – Concrete for Environmental Enhancement and Protection, Theme 6 Waste Materials and Alternative Product, University of Dundee, 1996. London: E & F N Spon; 1996. p. 637–44

Ambroise J, Martin–Calle S, Pera J. Pozzolanic behaviour of thermally activated kaolin. In: Malhotra VM, editor. Proceedings of the Fourth International Conference on Fly Ash, SF, Slag and Natural Pozzolans in Concrete, vol. 1. Turkey; 1992; p. 731–41

Ambroise, 1985, Hydration reaction and hardening of calcined clays and related minerals: V. Extension of the research and general conclusions, Cement Concrete Res., 15, 261, 10.1016/0008-8846(85)90037-7

Walters GV, Jones TR. Effect of metakaolin on alkali-silica-reactions in concrete manufactured with reactive aggregates. In: Malhotra VM, editor. Proceedings of the Second International Conference on the Durability of Concrete, vol. II. Montreal; 1991. p. 941–47

Kostuch JA, Walters GV, Jones TR. High performance concrete incorporating metakaolin – a review, Concrete 2000. University of Dundee; September 1993. p. 1799–1811

Asbridge AH, Walters GV, Jones TR. Ternary blended concretes-OPC/ggbfs/metakaolin. Denmark: Concrete Across Borders; June 1994. p. 547–557

Frias, 2000, Pore size distribution and degree of hydration of metakaolin-cement pastes, Cement Concrete Res., 30, 561, 10.1016/S0008-8846(00)00203-9

Li, 1985, Quantitative determination of pozzolans in hydrated systems of cement or Ca(OH)2 with fly ash or silica fume, Cement Concrete Res., 15, 1074, 10.1016/0008-8846(85)90100-0

Frias, 2000, The effect that the pozzolanic reaction of metakaolin has on the heat evolution in metakaolin-cement mortars, Cement Concrete Res., 30, 209, 10.1016/S0008-8846(99)00231-8

Oriol, 1995, Pozzolanic activity of metakaolin under microwave treatment, Cement Concrete Res., 25, 265, 10.1016/0008-8846(95)00007-0

Marwan T, Pera J, Ambroise J. The action of some aggressive solutions on Portland and calcined laterite blended cement concretes. In: Malhotra VM, editor. Proceedings of the Fourth International Conference on Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, vol. I. Istanbul, Turkey; May 1992. p. 763–79

Salvador, 1994, Modelling of combined heating and dehydroxylation of kaolinite particles during flash calcination; production of metakolin, Processing Adv. Mater., 9, 128

Salvador, 1995, Pozzolanic properties of flash-calcined kaolinite: a comparative study with soak-calcined products, Cement Concrete Res., 25, 102, 10.1016/0008-8846(94)00118-I

Wild, 1997, Portlandite consumption in metakaolin cement pastes and mortars, Cement Concrete Res., 27, 137, 10.1016/S0008-8846(96)00187-1

Wild S, Khatib JM, Craythorne MJ. Strength development of mortar containing metakaolin. In: Proceedings of the Fifth International Conference on Modern Building Materials, Structures and Techniques. Lithuania: Vilnius Gediminas Technical University; May 1997. p. 58–63

Curcio, 1998, Metakaolin as a pozzolanic microfiller for high-performance mortars, Cement Concrete Res., 28, 803, 10.1016/S0008-8846(98)00045-3

Bredy, 1989, Microstructure and porosity of metakaolin blended cements, Proc. Mater. Res. Soc. Symp., 137, 431, 10.1557/PROC-137-431

Khatib, 1996, Pore size distribution of metakaolin paste, Cement Concrete Res., 26, 1545, 10.1016/0008-8846(96)00147-0

Cabrera JG, Nwaubani SO. The microstructure and chloride ion diffusion characteristics of cements containing metakaolin and fly ash. In: Proceedings of the Sixth CANMET/ACI International Conference on Fly ash, Silica Fume, Slag and Natural Pozzolans in Concrete, vol. I. Bangkok, Thailand; 1998. p. 493–506

Rols S, Mbessa M, Ambroise J, Pera J. Influence of ultra-fine particle type on properties of very-high-strength concrete. In: Malhotra VM, Helene P, Prudencio LR, Dal Molin DCC, editors. Proceedings of the Second CANMET/ACI International Conference on High Performance Concrete and Performance and Quality of Concrete Structures. Gramado, RS, Brazil; 1999. p. 671–86

Caldarone MA, Gruber KA, Burg RG. High reactivity metakaolin: a new generation mineral admixture. Concrete Int November 1994:37–40

Wild, 1996, Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete, Cement Concrete Res., 26, 1537, 10.1016/0008-8846(96)00148-2

Sabir BB. The effects of curing temperature and water/binder ratio on the strength of metakaolin concrete. In: Sixth CANMET/ACI International Conference on Fly ash, Silica Fume, Slag and Natural Pozzolans in Concrete, Supplementary volume. Bangkok, Thailand; 1998. p. 493–506

Brooks, 2000, Effect of admixtures on the setting times of high-strength concrete, Cement Concrete Compos., 22, 293, 10.1016/S0958-9465(00)00025-1

ECC International product document. A new pozzolanic material for the cement and concrete industry, use of metastar for the production of highly durable concretes and mortars. 3rd ed. England: St Austell; 1996

Coleman, 1997, Aspects of the pore solution chemistry of hydrated cement pastes containing metakaolin, Cement Concrete Res., 27, 147, 10.1016/S0008-8846(96)00184-6

Jones TR, Walters GV, Kostuch JA. Role of metakaolin in suppressing ASR in concrete containing reactive aggregate and exposed to NaCl solution. In: Proceedings of the Ninth International Conference on Alkali-Aggregate Reaction in Concrete, vol. 1. 1992. p. 485–96

Bosc JL, Kouame K, Pera J. Improvement of concrete durability in tropical marine environment by adding metakaolin and superplasticisers. In: Proceedings of the Sixth International Conference on Durability of Building Materials and Components, vol. 1. Omiya, Japan; 1993. p. 448–57

Khatib, 1998, Sulphate resistance of metakaolin mortar, Cement Concrete Res., 28, 83, 10.1016/S0008-8846(97)00210-X

Martin S. Metakaolin and its contribution to the acid resistance of concrete. In: International Symposium on Concrete for a Sustainable Agriculture. Stavanger, Norway; 1997. p. 21–9

Pera J, Rols S, Chabannet M, Ambroise J. Influence of the cement type on the resistance of concrete to an agricultural environment. In: Cohen M, Mindess S, Skalny J, editors. Materials Science of Concrete: The Sidney Diamond Symposium. The American Concrete Society; 1998. p. 419–30

Pera, J, Bonnin, E, Inertization of toxic metals in metakaolin-blended cements. In: Jain V, Peeler D, editors. Environmental issues and waste management technologies in the ceramic and nuclear industries II, Ceramic Transactions, vol. 72. The American Ceramic Society; 1996. p. 365–74

Pera J, Bonnin E, Chabannet. Immobilisation of wastes by metakaolin-blended cements. In: Proceedings, Sixth Int Conf on Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, vol. 2. V. Malhotra; 1998. p. 997–1006

Barger GS, Lukkarila MR, Martin DL, Lane SB, Hansen ER, Ross MW, Thomson JL. Evaluation of a blended cement and a mineral admixture containing calcined clay natural pozzolan for high-performance concrete. In: Proceedings of the Sixth International Purdue Conference on Concrete Pavement Design and Materials for High Performance. Purdue; 1997. p. 21–40

Girodet C, Chabannet M, Bosc JL, Pera J. Influence of the type of cement on the freeze-thaw resistance of the nortar phase of concrete. In: Setzer MJ, Auberg R. editor. Proceedings of the International RILEM Workshop on the Frost Resistance of Concrete. London: E & FN Spon; 1997. p. 31–40

Sabir BB, Wild S, Khatib, JM. On the workability and strength development of metakaolin concrete. In: Proceedings of the International Conference Concrete in the Service of Mankind, Environmental Enhancement and Protection. Dundee; 1996. p. 651–62

Tattersall, 1991

Faroug, 1999, Influence of superplasticisers on the workability of concrete, J. Mater. Civil Eng. ASCE, 11, 151, 10.1061/(ASCE)0899-1561(1999)11:2(151)

Bai, 1999, Workability of concrete incorporating PFA and metakaolin, Mag. Concrete Res., 51, 207, 10.1680/macr.1999.51.3.207

Lota, 2000, Mechanism for the modification of portland cement hydration using polyacrylic acid, Adv. Cement Res., 12, 45, 10.1680/adcr.2000.12.2.45

Caldarone MA, Gruber KA. High reactivity metakaolin-A mineral admixture for high performance concrete. In: Sakai K, Banthia N, Gjorv OE, editors. Concrete under service conditions: environment and loading, vol. 2. London: E & FN Spon; 1995. ISBN 0 419 19860 1

Sabir BB, Wild S, Khatib JM Strength development and workability of concrete blended with metakaolin and fly ash. In: Second International Conference on High Performance Concrete and Performance and Quality of Concrete Structures, Supplementary papers, CD ROM, SP144doc. Brazil; June 1999. p. 1–13

Bai, 2000, Strength development in concrete incorporating PFA and MK, Mag. Concrete Res., 52, 153, 10.1680/macr.2000.52.3.153

Kinuthia JM, Wild S, Sabir BB, Bai J. Influence of metakaolin-PFA blends on the chemical shrinkage of cement pastes. In: Proceedings, Concrete Communication Conference, 99, Ninth BCA Annual Conference on Higher Education and the Concrete Industry. Cardiff University; July 1999. p. 91–102

Pera J, Ambroise J. Cementitious matrices using indigenous materials for ferrocement applications. In: Naaman A, editor. Proceedings of the Sixth International Symposium on Ferrocement. University of Michigan; June 1988. p. 417–29

Pera J, Ambroise J. Calcined paper sludge: an interesting admixture for the cement industry. In: Cohen M, Mindess S, Skalny J, editors. Materials Science of Concrete – The Sidney Diamond Symposium, Special volume. The American Ceramic Society; 1998. p. 467–79

Pera J, Ambroise J, Pozzolanic properties of metakaolin obtained from paper sludge. In: Malhotra VM, editor. Proceedings of the Sixth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, vol. II. Bangkok, Thailand; 1998. p. 1007–20

Pera, 1998, Development of highly reactive metakaolin from paper sludge, Adv. Cement Based Mater., 7, 49, 10.1016/S1065-7355(97)00016-3

Joshi RC, Lohta RP. Fly ash in concrete. In: Advances in concrete technology, vol. 2. Amsterdam: Gordon and Breach; 1997

Malhotra VM, Mehta PK. Pozzolanic and cementitious materials. In: Advances in concrete technology, vol. 1. Amsterdam: Gordon and Breach; 1996