Mesoporous Ni-N-C as an efficient electrocatalyst for reduction of CO2 into CO in a flow cell

Zhu, 2021, Carbon-supported single metal site catalysts for electrochemical CO2 reduction to CO and beyond, Small, 17 Daiyan, 2020, Tunable syngas production through CO2 electroreduction on cobalt-carbon composite electrocatalyst, ACS Appl. Mater. Interfaces, 12, 9307, 10.1021/acsami.9b21216 Huang, 2021, CO2 electrolysis to multicarbon products in strong acid, Science, 372, 1074, 10.1126/science.abg6582 Liu, 2021, CO2 reduction on pure Cu produces only H2 after subsurface O is depleted: theory and experiment, Proc. Natl. Acad. Sci. U.S.A., 118, 10.1073/pnas.2012649118 Navarro-Jaén, 2021, Highlights and challenges in the selective reduction of carbon dioxide to methanol, Nat. Rev. Chem., 5, 564, 10.1038/s41570-021-00289-y Niu, 2021, Rigorous assessment of CO2 electroreduction products in a flow cell, Energy Environ. Sci., 14, 4169, 10.1039/D1EE01664D Xie, 2021, Facet engineering to regulate surface states of topological crystalline insulator bismuth rhombic dodecahedrons for highly energy efficient electrochemical CO2 reduction, Adv. Mater., 33, 10.1002/adma.202008373 Costentin, 2013, Catalysis of the electrochemical reduction of carbon dioxide, Chem. Soc. Rev., 42, 2423, 10.1039/C2CS35360A Xie, 2018, Metal-free fluorine interlayer doped carbon electrocatalyst for CO2 reduction outcompeting hydrogen evolution, Angew. Chem. Int. Ed., 57, 9640, 10.1002/anie.201802055 Dostagir, 2021, Co single atoms in ZrO2 with inherent oxygen vacancies for selective hydrogenation of CO2 to CO, ACS Catal., 11, 9450, 10.1021/acscatal.1c02041 Fujinuma, 2020, Highly efficient electrochemical CO2 reduction reaction to CO with one-pot synthesized Co-pyridine-derived catalyst incorporated in a nafion-based membrane electrode assembly, Adv. Energy Mater., 10 Lee, 2018, Understanding the role of functional groups in polymeric binder for electrochemical carbon dioxide reduction on gold nanoparticles, Adv. Funct. Mater., 28, 10.1002/adfm.201804762 Liu, 2019, Simultaneous achieving of high faradaic efficiency and CO partial current density for CO2 reduction via robust, noble-metal-free Zn nanosheets with favorable adsorption energy, Adv. Energy Mater., 9, 10.1002/aenm.201900276 Liu, 2020, Unraveling structure sensitivity in CO2 electroreduction to near-unity CO on silver nanocubes, ACS Catal., 10, 3158, 10.1021/acscatal.9b03883 Zhang, 2021, Emerging dual-atomic-site catalysts for efficient energy catalysis, Adv. Mater., 33, 10.1002/adma.202102576 Zhu, 2020, Self-assembly induced metal ionic-polymer derived Fe-Nx /C nanowire as oxygen reduction reaction electrocatalyst, J. Catal., 391 Pan, 2018, Identification of champion transition metals centers in metal and nitrogen-codoped carbon catalysts for CO2 reduction, Appl. Catal. B Environ., 226, 463, 10.1016/j.apcatb.2018.01.001 Wang, 2021, Metal-nitrogen-carbon catalysts of specifically coordinated configurations toward typical electrochemical redox reactions, Adv. Mater., 33 Ma, 2019, Ultrasonic assisted synthesis of Zn-Ni bi-metal MOFs for interconnected Ni-N-C materials with enhanced electrochemical reduction of CO2, J. CO2 Util., 32, 251, 10.1016/j.jcou.2019.04.006 Varela, 2018, Molecular nitrogen-carbon catalysts, solid metal organic framework catalysts, and solid metal /nitrogen-doped carbon (MNC) catalysts for the electrochemical CO2 reduction, Adv. Energy Mater., 8, 10.1002/aenm.201802905 Wu, 2020, Boosting formate production at high current density from CO2 electroreduction on defect-rich hierarchical mesoporous Bi/Bi2O3 junction nanosheets, Appl. Catal. B Environ., 271, 10.1016/j.apcatb.2020.118957 Wang, 2020, Conversion of CO2 to chemical feedstocks over bismuth nanosheets in situ grown on nitrogen-doped carbon, J. Mater. Chem. A, 8, 19938, 10.1039/D0TA07411J Tang, 2014, Synthesis of nitrogen-doped mesoporous carbon spheres with extra-large pores through assembly of diblock copolymer micelles, Angew. Chem. Int. Ed., 127, 598, 10.1002/ange.201407629 Xiao, 2016, Nitrogen, iron-codoped mesoporous carbon with bimodal-pores as an efficient catalyst for the oxygen reduction reaction, Electrochim. Acta, 209, 551, 10.1016/j.electacta.2016.05.121 Byambasuren, 2016, The particle size effect of N-doped mesoporous carbons as oxygen reduction reaction catalysts for PEMFC, Korean J. Chem. Eng., 33, 1831, 10.1007/s11814-016-0030-9 Zhang, 2016, Mesoporous carbon materials with functional compositions, Chem. Eur. J., 23, 1986, 10.1002/chem.201602199 Wu, 2020, A CO2 adsorption dominated carbon defect-based electrocatalyst for efficient carbon dioxide reduction, J. Mater. Chem. A, 8, 1205, 10.1039/C9TA11473D Ju, 2017, Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2, Nat. Commun., 8, 944, 10.1038/s41467-017-01035-z Varela, 2019, Electrochemical reduction of CO2 on metal-nitrogen-doped carbon catalysts, ACS Catal., 9, 7270, 10.1021/acscatal.9b01405 Zeng, 2021, Orbital coupling of hetero-diatomic nickel-iron site for bifunctional electrocatalysis of CO2 reduction and oxygen evolution, Nat. Commun., 12, 4088, 10.1038/s41467-021-24052-5 Zhang, 2021, Quasi-double-star nickel and iron active sites for high-efficient carbon dioxide electroreduction, Energy Environ. Sci., 14, 4847, 10.1039/D1EE01592C Chen, 2019, Three-dimensional porous Ni, N-codoped C networks for highly sensitive and selective non-enzymatic glucose sensing, Sens. Actuators B Chem., 299, 10.1016/j.snb.2019.126945 Yuan, 2019, Powerful CO2 electroreduction performance with N-carbon doped by Ni single atoms, Catal. Sci. Technol., 9, 3669, 10.1039/C9CY00363K Leverett, 2021, Designing undercoordinated Ni-Nx and Fe-Nx on holey graphene for electrochemical CO2 conversion to syngas, ACS Nano, 15, 12006, 10.1021/acsnano.1c03293 Linares, 2014, Mesoporous materials for clean energy technologies, Chem. Soc. Rev., 43, 7681, 10.1039/C3CS60435G Zhang, 2019, Nitrogen-doped carbon-supported nickel nanoparticles: a robust catalyst to bridge the hydrogenation of nitriles and the reductive amination of carbonyl compounds for the synthesis of primary amines, ChemSusChem, 12, 1246, 10.1002/cssc.201802459 Yang, 2018, Controlled synthesis of nickel carbide nanoparticles and their application in lithium storage, Chem. Eng. J., 352, 940, 10.1016/j.cej.2018.06.066 Hou, 2020, Atomically dispersed Ni species on N-doped carbon nanotubes for electroreduction of CO2 with nearly 100% CO selectivity, Appl. Catal. B Environ., 271, 10.1016/j.apcatb.2020.118929 Daiyan, 2020, Transforming active sites in nickel-nitrogen-carbon catalysts for efficient electrochemical CO2 reduction to CO, Nano Energy, 78, 10.1016/j.nanoen.2020.105213 Sahin, 2020, CO2 electroreduction to fuels on mesoporous carbon-embedded copper nanoparticles, Sustain. Energy Fuels, 4, 6045, 10.1039/D0SE01025A Wang, 2021, Constructing ample active sites in nitrogen-doped carbon materials for efficient electrocatalytic carbon dioxide reduction, Nano Energy, 90, 10.1016/j.nanoen.2021.106541 Zhao, 2017, Ionic exchange of metal-organic frameworks to access single nickel sites for efficient electroreduction of CO2, J. Am. Chem. Soc., 139, 8078, 10.1021/jacs.7b02736