Mechanism of methoxycarbonylation of 1,5-naphthalene diamino with dimethyl carbonate to 1,5-naphthalene dicarbamate over anhydrous zinc acetate

Reaction Kinetics, Mechanisms and Catalysis - Tập 89 - Trang 131-138 - 2006
Fu-kui Xiao1, De-sheng Zhang2, Qing-nian Dong3, Wei Wei4, and Yu-han Suna3
1State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Research Institute of Jilin Petrochemical Company, Petrochina
2Research Institute of Jilin Petrochemical Company, Petrochina
3State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,
4State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,

Tóm tắt

The FT-IR characterization showed that anhydrous zinc acetate hardly interacted with dimethyl carbonate, but it could coordinate with 1,5-naphthalene diamino to form a new complex. As a result, a new mechanism on 1,5-naphthalene diamino activation was proposed for the methoxycarbonylation of 1,5-naphthalene diamino with dimethyl carbonate over anhydrous zinc acetate.

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Thông tin xuất bản

Reaction Kinetics, Mechanisms and Catalysis

Tập 89

131-138

Thông tin tác giả