Mechanism of corrosion protection in chloride solution by an apple-based green inhibitor: experimental and theoretical studies

Mehdi Honarvar Nazari1, Mehdi Salih Shihab2, Eden Adele Havens1, Xianming Shi1
1Department of Civil & Environmental Engineering, Laboratory of Corrosion Science and Electrochemical Engineering, National Center for Transportation Infrastructure & Life-Extension, Washington State University, P. O. Box 642910, Pullman, WA, 99164-2910, USA
2Department of Chemistry, College of Science, Al-Nahrain University, Baghdad 64021, Iraq

Tóm tắt

AbstractPreservation of metals in infrastructures and other assets requires cost-effective and sustainable solutions such as green corrosion inhibitors. This study assesses an apple pomace-derived green inhibitor synthesized by an innovative zero-waste method. Electrochemical measurements revealed the high performance of this liquid extract in reducing the corrosion of carbon steel in NaCl brine. The chemical composition of this inhibitor was characterized by liquid chromatography mass spectroscopy (LC-MS) to shed light on the corrosion inhibition mechanism. Based on LC-MS analysis, the results of surface analysis were interpreted. Specifically, the major corrosion inhibitor agent in the apple pomace extract was determined as C26H50NO7P (1-Linoleoyl-sn-glycero-3-phosphocholine), which can adsorb onto the steel surface to form a barrier layer and serve as a blocker of active anodic sites. Further study showed that the apple extract adsorption follows the Langmuir isotherm, and physical adsorption is dominant (vs. chemical adsorption). Theoretical calculations using quantum chemistry proposed a physisorption mechanism for the protection of steel by C26H50NO7P molecules.Graphical abstract

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