Localized Surface Plasmon Resonance Spectroscopy and Sensing

Annual Review of Physical Chemistry - Tập 58 Số 1 - Trang 267-297 - 2007
Katherine A. Willets1, Richard P. Van Duyne2
1Department of Chemistry, Northwestern University, Evanston, IL 60208-3113, USA. [email protected]
2Department of Chemistry, Northwestern University, Evanston, Illinois, 60208-3113

Tóm tắt

Localized surface plasmon resonance (LSPR) spectroscopy of metallic nanoparticles is a powerful technique for chemical and biological sensing experiments. Moreover, the LSPR is responsible for the electromagnetic-field enhancement that leads to surface-enhanced Raman scattering (SERS) and other surface-enhanced spectroscopic processes. This review describes recent fundamental spectroscopic studies that reveal key relationships governing the LSPR spectral location and its sensitivity to the local environment, including nanoparticle shape and size. We also describe studies on the distance dependence of the enhanced electromagnetic field and the relationship between the plasmon resonance and the Raman excitation energy. Lastly, we introduce a new form of LSPR spectroscopy, involving the coupling between nanoparticle plasmon resonances and adsorbate molecular resonances. The results from these fundamental studies guide the design of new sensing experiments, illustrated through applications in which researchers use both LSPR wavelength-shift sensing and SERS to detect molecules of chemical and biological relevance.

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Tài liệu tham khảo

10.1016/S0022-0728(77)80224-6

10.1002/jrs.1376

10.1007/3-540-33567-6_2

10.1021/ac035134k

10.1021/j100287a028

10.1126/science.275.5303.1102

10.1103/PhysRevLett.78.1667

10.1063/1.456129

10.1103/PhysRevB.49.8320

10.1103/PhysRevB.53.4162

10.1063/1.471241

Geddes CD, 2004, Rev. Fluoresc., 1, 365

10.1007/0-387-27617-3_7

10.1063/1.454251

10.1366/0003702001949654

10.1103/PhysRevLett.89.117401

10.1021/ja044087q

10.1021/nl049670j

10.1023/B:JOFL.0000031817.35049.1f

10.1021/nl034372s

10.1021/ja047118q

10.1016/j.talanta.2005.06.039

10.1117/12.508611

10.1021/ja003312a

10.1021/la971228b

10.1366/000370203322554446

10.1146/annurev.physchem.51.1.41

10.1016/S0006-3495(99)77219-X

10.1021/ac970929a

10.1021/ac0513459

10.1016/j.stam.2005.03.019

10.1039/a804010i

10.1021/nl034223+

10.1021/nl049573q

10.1117/12.532613

10.1021/nl052322c

10.1038/361186a0

10.1126/science.1104976

10.1146/annurev.physchem.49.1.569

10.1007/s00216-004-2708-9

10.1557/mrs2005.100

10.1021/ja043623b

10.1021/jp026731y

10.1063/1.464398

10.1021/jp054227y

10.1021/jp9926802

10.1088/1464-4258/8/3/007

10.1021/ja00457a071

10.1088/0953-8984/4/5/001

10.1063/1.437095

10.1063/1.440560

10.1146/annurev.pc.35.100184.002451

10.1021/ar00106a005

10.1080/00268978500102131

10.1016/S0081-1947(08)60314-8

10.1021/jp010657m

10.1021/nl0515753

10.1063/1.1462610

10.1021/jp013570+

Haynes CL, 2005, Chem., 77, A338

10.1021/jp0467604

10.1021/jp0540656

10.1021/jp0361327

10.1021/nl052409y

10.1557/mrs2005.96

10.1002/chem.200400927

10.1126/science.1077229

10.1021/nl050873x

10.1038/nature02020

10.1126/science.1066541

10.1021/jp034234r

10.1166/jnn.2005.118

Bohren CF, Huffman DR. 1983. Absorption and Scattering of Light by Small Particles. New York: Wiley. 530 pp.

10.1002/andp.19083300302

10.1021/jp9917648

10.1364/JOSAA.11.001491

10.1023/A:1021977613319

10.1063/1.469787

10.1103/PhysRevLett.79.645

10.1103/PhysRevLett.75.4772

Taflove A, 1995, Computational Electrodynamics: The Finite-Difference Time Domain Method.

10.1021/ja020393x

10.1016/B978-0-12-505404-1.50009-X

10.1021/jp050508u

10.1557/PROC-635-C6.3

10.1116/1.579726

10.1021/ac0501238

10.1021/jp0545400

10.1021/nl0505492

10.1103/PhysRevLett.84.4721

10.1021/nl049951r

10.1021/la050887i

10.1002/anie.200462208

10.1002/anie.200503821

10.1002/anie.200600394

10.1021/jp051178g

10.1021/jp002435e

10.1021/nl0340475

10.1021/ja992128q

Sherry LJ, Jin R, Mirkin CA, Schatz GC, Van Duyne RP. 2006. Localized surface plasmon resonance spectroscopy of single silver triangular nanoprisms. Nano Lett. In press

10.1021/jp036261n

10.1016/S0040-6090(02)00438-8

10.1016/B978-012512908-4/50005-9

10.1016/S0040-6090(96)08934-1

10.1039/b513431p

10.1021/jp984454i

10.1021/jp027749b

10.1016/j.cplett.2004.12.107

10.1021/ja063575q

10.1021/nl051592s

10.1038/nbt1100

10.1021/jp022130v

10.1073/pnas.1834302100

10.1073/pnas.95.11.6448

10.1046/j.1471-4159.2001.00592.x

10.1016/B978-012444562-8/50017-3

Zhao J, Das A, Zhang X, Schatz GC, Sligar SG, Van Duyne RP. 2006. Resonance surface plasmon spectroscopy: low molecular weight substrate binding to cytochrome P450. 128:11004–5

10.1021/ja0638760

10.1021/ja028255v

10.1021/ac051357u

10.1021/jp010333y

10.1039/b513326b