Linear Diamides Derivative-Nucleated Biodegradable Poly(ethylene succinate) Polyester: Crystallization Kinetics and Aggregated Structure Manipulated by Hydrogen Bond Interaction

Journal of Polymers and the Environment - Tập 29 - Trang 3605-3617 - 2021
Shanshan Zhou1, Yongyan Sun1,2, Huimin Ma1, Chunfeng Jia1, Xiaoyu Sun1, Yubin Yang1, Juan Liu1, Jinjun Yang1
1Tianjin Key Laboratory of Hazardous Waste Safety Disposal and Recycling Technology, School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin, China
2Shanghai Institute of Nutrition and Health, Shanghai Institutes for Biological Sciences, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai, China

Tóm tắt

A linear diamides derivative (TMC300) as a nucleating agent (NA) was incorporated into biodegradable poly(ethylene succinate) (PES) to investigate effect of TMC300 on nucleation, crystallizability, crystallization kinetics, aggregated structure of PES. TMC300 enhanced significantly crystallizability and crystallization temperature of PES in cooling process at a rate of 10 ℃/min from molten state, indicating that TMC300 exhibits an excellent nucleation effect on PES. IR measurement suggested that TMC300 interacts with amorphous carbonyl and ester segment, and crystalline CH2 segment of PES via hydrogen bond. Change rate of carbonyl group is comparable to that of C‒C backbone of PES, regardless of the presence or absence of TMC300. Small difference of diffraction peak in WAXD measurement between neat PES and PES/TMC300 is probably attributed to spherulitic orientation on film surface of neat PES, and different spatial arrangements in the same crystal lattice. TMC300 enhanced carbon residue yield of PES/TMC300 composite, probably related to slight flame retardance effect.

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